MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Corrosion Inhibitor A406
Product Description: Rodine 103
Product Code: A406
Product Name: Corrosion Inhibitor A406
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Blend of Chemicals (trade secret) Containing:
Surfactants 1 { 10
Ethylenediamine Dihydroiodide 1 { 10 5700-49-2
Iodine Complex 1 { 10 11096-42-7
Phosphoric acid 1 { 10 7664-38-2
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Iodine Complex 1 mg/m3 (ceiling) 1 mg/m3 for
iodine
Phosphoric acid 1 mg/m3 1 mg/m3
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Irritating to eyes, respiratory system and skin.
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
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DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
SKIN:
Wash thoroughly with soap and water. See a doctor if irritation occurs. Wash clothes thoroughly
before reusing.
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: Not Applicable
Flammable Limits: Not Applicable
Autoignition Temperature: None
GENERAL HAZARD:
Material will not burn.
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
If heated strongly or burned, oxides of carbon and nitrogen, phosphoric acid, hydrogen iodode,
cyanides, ammonia, and iodine fumes and harmful organic fumes may be released.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Ventilate area.
Put in appropriate container.
Soak up residual on inert absorbant (sand).
Wash spill site after material pickup is complete.
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DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
STORAGE:
No special precautions required.
Store away from oxidizers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
None normally needed. For protection from dust, use NIOSH approved respirator with dust
protection.
PROTECTIVE CLOTHING:
Face shield, boots, protective suit and impervious (neoprene) gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Bland
Color: Brown
pH: 2 to 3
Percent Volatile: Not Determined
Vapor Pressure: Not Determined
Vapor Density: Not Determined
Boiling Point: >210卤 F
Freezing Point: Not Determined
Solubility in Water: Soluble
Evaporation Rate: Not Determined
Speci炉c Gravity: 1.05 to 1.15 (water=1)
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DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
HAZARDOUS DECOMPOSITION:
Thermal decomposition may produce oxides of carbon and nitrogen, phosphoric acid, hydrogen
iodode, cyanides, ammonia, and iodine fumes and harmful organic fumes may be released.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Severe irritant. Causes pain and redness. Prolonged or repeated contact may cause mild
burn.
Skin: Severe irritant. Causes pain, redness, dermatitis or mild burn. Not likely to be absorbed in
toxic amounts.
Ingestion: Irritant. May cause pain or discomfort to mouth, throat and stomach.
Inhalation: Irritant. May cause pain and coughing.
TARGET ORGANS:
None known.
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
COMMENTS:
Only selected Registry of Toxic E庐ects of Chemical Substances (RTECS) data is presented in this
document. See the actual entry in RTECS for complete information.
RTECS Number:
KL9625000 (iodine complex)
TB6300000 (phosphoric acid)
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
No environmental data for this material are currently available.
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DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Dispose of in accordance with ALL applicable federal, state and local regulations.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
RCRA Status - Not Determined
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Corrosion Inhibitor A406, Rodine 103 { Not Regulated
Reportable Quantity (RQ) Under CERCLA: 6000 gal
SPECIAL SHIPPING NOTES:
Not regulated unless RQ exceeded in a single container.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: No Pressure Generating: No Reactivity: No Acute: Yes Chronic: No
313 Reportable Ingredients: Phosphoric acid
Title III Notes: This product contains substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: 6000 gal
EPA
EPA RQ Ingredient: Phosphoric Acid
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
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DATE PREPARED: 10/07/1999
MSDS No: A406
Corrosion Inhibitor A406
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
Approval date: 10/07/1999
REVISION SUMMARY
Revision #: 5
This MSDS replaces the September 01, 1999 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared
NFPA CODES
Fire: 0 Health: 1 Reactivity: 0
HMIS CODES
Fire: 0 Health: 1 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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