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MSDS Material Safety Data Sheet
CAS

111-76-2

File Name: hydrochem_com---b211.asp
              MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Sharp 104-B
Product Code: B211
Product Name: Sharp 104-B
Generic Name: Flash rust inhibitor
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376




2. COMPOSITION/INFORMATION ON INGREDIENTS

wt.% CAS Registry #
Proprietary Blend of Chemicals (trade secret) Containing:
2-Butoxyethanol 0.18 111-76-2


OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)

EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
2-Butoxyethanol 50 ppm 25 ppm



3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Contains an oxidizing agent.



4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.

SKIN:
Wash thoroughly with soap and water. See a doctor if irritation occurs. Wash clothes thoroughly
before reusing.
Page: 2
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B



INGESTION:
If swallowed, induce vomiting with ipecac (preferred), or by giving water and sticking 炉nger down
throat. After vomiting give milk (preferred) or water and consult physician.

INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.



5. FIRE FIGHTING MEASURES
Flashpoint and Method: Not Applicable
Flammable Limits: Not Applicable
Autoignition Temperature: None

GENERAL HAZARD:
Material contains an oxidizer that may pose a hazard after evaporation of volatile components.

EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.

HAZARDOUS COMBUSTION PRODUCTS:
None reported

FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.

FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.



6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Ventilate area.
Put in appropriate container.
Soak up residual on inert absorbant (sand).
Wash spill site after material pickup is complete.



7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
Page: 3
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B



STORAGE:
Keep container tightly closed.
Store in corrosion proof area.
Isolate from incompatible materials.

Oxidizing agents can be hazardous in concentrated form and must not be stored with organic
materials or acids. Poisonous gases or explosive mixtures could result from accidental mixing
with other chemicals.



8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.

PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.

RESPIRATORY:
None normally needed. For protection from dust, use NIOSH approved respirator with dust
protection.

PROTECTIVE CLOTHING:
Clean body covering and chemical resistant gloves.

OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.



9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Red
pH: 8.3 to 8.5
Percent Volatile: Not Determined
Vapor Pressure: Not Determined
Vapor Density: Not Determined
Boiling Point: 218卤 F
Freezing Point: Not Determined
Solubility in Water: Soluble
Evaporation Rate: Not Determined
Speci炉c Gravity: 1.28
Page: 4
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B



10. STABILITY AND REACTIVITY
STABLE: Yes

HAZARDOUS POLYMERIZATION: No

HAZARDOUS DECOMPOSITION:
Nitrogen oxides

INCOMPATIBLE MATERIALS:
Acids, Ammonia, Ammonium Hydroxide



11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Irritant. May cause pain, redness, discomfort.
Skin: Irritant. May cause pain, redness, dermatitis. Not likely to be absorbed in toxic amounts.
Ingestion: Harmful if swallowed. Large amounts may cause illness or death.
Inhalation: No e庐ect expected. Prolonged or repeated exposure may cause mild irritation. Mist
is irritating.

TARGET ORGANS:
Not Determined

TERATOGENICITY:
2-Butoxyethanol has shown teratogenic efects in laboratory animals.

GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.



12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
No environmental data for this material are currently available.



13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Dispose of in accordance with ALL applicable federal, state and local regulations.

EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
Page: 5
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B



RCRA/USEPA WASTE INFORMATION:
This material is not a RCRA regulated material.

COMMENTS:
Always follow ALL applicable federal, state and local regulations.



14. TRANSPORT INFORMATION

DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Flash Rust Inhibitor 104B { Not Regulated
Reportable Quantity (RQ) Under CERCLA: None
Placards: None
Label: None



15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Title III Notes: This product contains no substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).

CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: Not established

TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.

STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.



16. OTHER INFORMATION
REASON FOR ISSUE:
Biannual review

Approved by: Charles M Maddin, PhD, FAIC
Approval date: 10/08/1999
Page: 6
DATE PREPARED: 10/08/1999
MSDS No: B211
Sharp 104-B



REVISION SUMMARY
Revision #: 4

This MSDS replaces the August 19, 1998 MSDS. Any changes in information are as follows:
In Section 16
Reason for Issue

In Section 11
Teratology


NFPA CODES
Fire: 0 Health: 1 Reactivity: 0

HMIS CODES
Fire: 0 Health: 1 Reactivity: 0

MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.

The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.

HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.

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