MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: WS-36 Emulsi炉er
Product Code: F302
Product Name: WS-36 Emulsi炉er
Chemical Family: Emulsifying Agent
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Composition (trade secret)
COMMENTS:
This product contains no ingredients that meet the de炉nition of a hazardous chemical as de炉ned
in 29 CFR 1910.1200. However, good industrial hygiene practices should still be used with this
product.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
May be harmful by
Skin Contact
Ingestion
Eye contact
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
SKIN:
Immediately wash with soap and water for 30 minutes. See a doctor if irritation occurs. Launder
contaminated shoes and clothing before reuse.
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DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: >200卤 F 93卤 C Cleveland Closed Cup
Flammable Limits: Not Determined
Autoignition Temperature: Not Determined
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
Oxides of carbon and phosphorous and harmful organic chemical fumes.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Put in plastic or steel drum.
Soak up residual with inert absorbant (sand).
Wash spill site after material pickup is complete.
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
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DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
STORAGE:
Keep container tightly closed.
Isolate from incompatible materials.
Do not store near oxidizing materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
None normally needed. Use NIOSH approved respirator with organic vapor/acid gas protection
(color coded yellow) if vapors are generated and for emergencies.
PROTECTIVE CLOTHING:
Clean body covering and chemical resistant gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Amber
pH: 4 to 5
Percent Volatile: Not Determined
Vapor Pressure: Not Determined
Vapor Density: >1 (Air = 1)
Boiling Point: Not Determined
Freezing Point: 15卤 F -9卤 C
Solubility in Water: Disperses
Speci炉c Gravity: 1.016 (water=1)
COMMENTS:
pH: pH listed above is for a 5% solution
10. STABILITY AND REACTIVITY
STABLE: Yes
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DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
HAZARDOUS POLYMERIZATION: No
HAZARDOUS DECOMPOSITION:
Oxides of carbon and phosphorous and harmful organic chemical fumes.
INCOMPATIBLE MATERIALS:
Oxidizing materials
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Irritant. May cause pain, redness, discomfort.
Skin: Irritant. May cause pain, redness, dermatitis. Not likely to be absorbed in toxic amounts.
Ingestion: Irritant. May cause pain or discomfort to mouth, throat and stomach. Harmful if
swallowed. Large amounts may cause illness or death.
Inhalation: High concentrations cause narcosis. Harmful if inhaled repeatedly or for long periods.
May cause dizziness or headache.
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
No environmental data for this material are currently available.
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Dispose of in accordance with ALL applicable federal, state and local regulations.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
This material is not a RCRA regulated material.
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
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DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: F302 Emulsi炉er { Not Regulated
Reportable Quantity (RQ) Under CERCLA: None
Placards: None
Label: None
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: No Pressure Generating: No Reactivity: No Acute: Yes Chronic: No
Title III Notes: This product contains no substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: Not Established
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
REASON FOR ISSUE:
Biannual review
Approved by: Charles M Maddin, PhD, FAIC
Approval date: 10/08/1999
Page: 6
DATE PREPARED: 10/08/1999
MSDS No: F302
WS-36 Emulsi炉er
REVISION SUMMARY
Revision #: 2
This MSDS replaces the August 17, 1998 MSDS. Any changes in information are as follows:
In Section 16
Reason for Issue Date Prepared
In Section 3
Emergency Overview - Immediate Concerns
In Section 4
Firstaid - Skin
In Section 8
Clothing Protection
In Section 9
(Group Field) for (pH) (pH) (from) (pH) (to) (pH) Comments (Group Field) for Vapor Pressure
Density Vapor Density # Vapor Density REF Speci炉c Gravity (from) Vapor Density (oper)
In Section 11
Acute Eye Target Organ
In Section 15
SARA Title III Notes
NFPA CODES
Fire: 1 Health: 1 Reactivity: 0
HMIS CODES
Fire: 1 Health: 1 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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