MSDS PAGE: CAS 78-93-3 MSDS celanese

產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006

材料安全康傀�?
1. 產品與公司識縠資�?

Product:甲基乙基�?
MSDS 炭碼: 61
材料炭碼:80061

Celanese Pte Ltd
111 Somerset Road
Singapore Power Building #02-02/03
Singapore 238164
Tel No: (65) 6733 1767

運菘緊�?�情縭肟钥炭碼﹕
+ (65) 66639259 (Operations Room direct dial)
+ (65) 62656917 (Operations Room direct dial)
+ (65) 62650177(Switchboard, ask for Operations Room)

or fax request to
+(65) 62644190 (Facsimile to Operations Room)
+(65) 62664696 (Facsimile to Operations Room)

or email to
opsroom@semco.psa.com.sg

or Call CHEMTREC 703 527 3887 (USA), collect calls accepted
"+" = International Dialing Access Code

產品使用:油漆和縏坑�?�黏合咯、磁咖生產�?�靠滑油每臘、印刷等的溶液；雜砜使用�?

2. 成分/成分資料

成分及化縒文摘服空炭炭碼重量% OSHA 铱定�?�?:
成分及化縒文摘服空炭
炭碼
丁酮 78-93-3 99.5 危險

3. 危險識縠

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1 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
緊�?�情�?:
危險!
縊其易燃之液體和蒸库。蒸库可引起暴燃�?
造成眼睛刺激�?
可�?�成呼吸道刺�?�?
可�?�成皮膚刺激�?
蒸库重於空库縆可遠距離運移到火源及回燃�??

產品說明

外貌: 透明、縪色�?�油性液體�??
味道: 靠烈、有“酮”特色的库味�?

靠在健康影砜
暴露途拷: 皮膚、眼睛�?�吸入�?�坎下�??

即縭影砜
皮膚: 可能�?引起皮膚發炎�? 暴露的徵�?可能包括�? 皮膚乾燥、乾裂或發炎�?

眼睛: 暴露於库體和液體 �?刺激眼睛�? 暴露的徵�?可能包括�?
眼睛刺激、灼魁的感覺、痛、流眼縄�?/或铱力改卓�??

吸入: 可能�?引起呼吸道刺�?�? 暴露的徵�?可能包括�?
中央神娇系統亢抑�?引起的縄心�?�頭靠�?�頭痛�?�木僵�?�不縡調或奇怪的舉止或昏迷�??
流鼻水�?�嘶俊�?�咳嗽�?�胸痛和呼吸困難�?

坎下: 基本上縘有毒性�?? 暴露的徵�?可能包括�?
縄心、縄吐�?�失去食欲�?�刺�?腸胃�?/或腹縜�??
中啃神娇系統亢抑，伴有縡心�?�頭痛和精神不振�?

生殖: 縪不良生殖影砜的證明�?

致癌�?: 縪致癌證明�??

突卓�?: 在Ames 縴蚩中縆未顯示突卓可能�?��?? 在大部分钥管縴蚩中縆未顯示突卓可能�?��??

致畸�?: 縘有先天缺陷的證明�??

�?特定器官的影�?: 過度（長期或反客）接觸可咖致�?
中啃神娇系統亢抑
眼睛受葵
刺激呼吸�?
皮膚縫葵�?

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2 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
大量接觸钥化縒品可能�?�?患有下列急�?�和慢�?�器官疾病的病人有不利影砜：
�?般認块在暴露後傀使病情亢化的呼吸�?
病縭: 皮膚
眼睛
中啃神娇系統

有關钥情，竣�?: �?5部分 �? 跨火措施
�?4部分 �? 急救措施 �?6部分 �? 意外峥放措施
�?8部分 �? 暴露控制/靠人保護
�?9部分 �? 物理與化縒特�?
�?10部分 �? 房定性與反开�?

4. 急救措施

皮膚: 立即用大量清水縚洗皮膚�?�每下污染的衣服和鞋子�?�如果產生持續的過敏反开，开�?
醫生驴絡。衣服开洗乾縌後才能再穿。鞋子开控底清靠後才再穿�?

眼睛: 立即用大量清水縚洗眼睛至�?15分缈。如果有戴隱形眼鏡縆可以輕易取下縭，�?竣之
取下。立即郡求治 �?

吸入: 移往空库清新炭�?�如果停止呼吸，�?施人工呼吸�?�如果呼吸困難，�?給氧库�?�郡求治
�?

坎下: 如果坎下大量本物質，立即驴絡醫生。除非娇�? 人縏的指示，否縯切勿引起縄吐�?
切勿餵昏迷的人任何縷西�??

5. 跨火措施

NFPA: Health: 1 Flammability: 3 Reactivity: 0

易燃特�??

閃點（縴钥方法）�? -9 C (16 F) (Closed Cup)

易燃限度，在空库，容�?%
上限: 10 %
下限: 1.8 %

自坑點燃控度: 404 C (759 F)

燃魁產品�? �?氧化碳�??

跨火媒介: 大火使用酒精羁的水溶成膜泡沫�? 小火使用二氧化碳或乾化縒品�??

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3 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
消防說明水可能不起作用，但开使用宽冷縮暴露在火中的建築和槽�?�大火开用水靠竣。竣水可
用於降低火枯，縆竣溢出物�?峥成不易燃的混合物�??
竣人縏撤離火源至迎風地點。如果有可能暴露在蒸库下或有可燃魁的產品存在，开�?
全套消防裝夸和NIOSH核准�? 立呼吸裝夸�?�氧化化縒品在著火的情縭下可能傀加�?�燃
魁的速度�? 蒸库比空库重，縆可以移坑�? 遠的距離至點火源和引起火舌回閃�??

消防環保靠題可使用水霧流控制蒸库和燃魁库體�??
再用�?藏快設夸和其它跨火設夸前�?完全清除污染�?

6. 意外峥放措施

溢出或开漏說�? 排除點火源�??
竣铱�?8部分有關�? 的人縏保護設夸�?�用土堤或非易燃的吸收咯隔離溢出物，使污�?
保持在最小的範窥咳�?? 水霧流可以縫少蒸库�??
如果有起火的可能，开使用酒精羁的水溶成膜泡沫宽覆蓋溢出物，或用水霧流分散�?
库�??
�?避免流入下水道及通往水道的肯渠�?�若州及地方有铱定，�?通知地方 �?。竣�?�?
的容器置於�?�風良好炭�??
使用非燃魁的吸收咯清除或用少許水縚洗小铱模的溢出物�?�用真空吸除或窟除乾縌�??

在美盔境咳，如果�?24小縭咳峥放出的分量相等於或超於下列开矿告的分量縭，开�?
肟�?�全盔回�?中心�?(National Response Center) (800-424-
8802)和適的州�? 地緾關﹕ par 5,000 lbs. of the material as is, based on
a Reportable Quantity of 5,000 lbs. for methyl ethyl ketone.

蚩散不必要在况的人；隔離危險地縙縆拒絕任何人進入。保持在迎風的位置；避開�?
的地縙�?? 如果火磕涉及到運菘罐、火芸罐芸或卡芸罐芸，开在各靠方向上隔離800�?
�?0.5哩）�?
如果情縭有必要开撤離砜風地縙以預防暴露，縆卓蒸库或靠消散。某些情縭的溢出�?
可能使相遠距離的砜風地縙暴露於有毒或可燃魁的库度�?

7. 炭理與喀�?

炭理: 在�?�風足框的環境下使用�?
不使用縭�?竣容器關緊�?�打開容器縭，开小心挚慎卓累積的亢力透出。避免吸入蒸�?
。避免與眼睛、皮膚或衣服接觸。炭理後�?用肥皂和水控底洗乾縌。沾污的衣服�?�?
底清除污染後才再使用。污染的皮革衣物�?咖跨�?

本產品可能傀產生靜肟。在運菘材料縭，�?竣設夸接�?/約束以預防靜肟的累積。在�?
盔，�?有喀藏和炭理用的肟子設夸都必砜符合�?�全盔肟库铱程�??(�?500�?501�?)�?�?
險地點的要求�?

�?�?: 不使用縭，竣�?有容器關緊�?�喀存在縘有昕光照射和不可緽透的地板上�??
湛勿與不兼容的材料喀存�?�竣铱�?�第10部分，房定�?�與反开性�?��??

8. 暴露控制/靠人保護

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
4 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
工程控制 �?般或�?峥�?�風作块雇縏暴露的唯�?控制方法通常是不足框的�?��?�常靠先選狂的是�?
部�?�風。緾坑�?�風系統�?使用防爆炸裝�?(例如，風扇�?�開關和接地管等)�?

�?隨縭渴夸好安全淋浴和洗眼設夸�?
靠人保護設夸
皮膚保護: 穿�?�不過的衣服和手套以便預防接觸�?�建議使用丁基橡膠�?�铱情縭，如果有足框的降
解和緽�?�資料，可使用其它保護材料�?�如果在使用本化縒品的同縭使用其它化縒品�?
選狂的材料开能保護所有使用的化縒品�??

眼睛/目部保護: 如有可能接觸眼睛縭开戴化縒護目鏡�?

呼吸道保�?: 根傀工作况所的污染程度及防毒面罩的工作限度，使用娇�?�全盔驴縄安全與保健縒傀
�?(NIOSH)
核准使用的防毒面罩�?�以下是建議驴縄暴露水平至少�?有的裝夸。竣铱第3�?8�?11�?
分以便估涌驴縄暴露水平�??
库度高於驴縄暴露水平1倍，但低�?10倍﹕使用罩蓋整靠目的空库縌化防毒面罩及有�?
蒸库筒或使用含有緾蒸库過縑毒罐�?�罩蓋整靠目的空库縌化防毒面罩或裝上有緾蒸库
筒�?�罩蓋整靠目的肟坑空库縌化防毒面罩�?�空库縌化部件必砜有結束服空扣命的顯�?
器，或必砜有�?靠更縌縭間表的文件�?�否縯使用菘送的空库�?
库度高於驴縄暴露水平10倍，但低於驴縄暴露水平的100倍或IDLH﹕使用C型罩蓋整�?
目�?�在亢力要求或不苦菘送空库的防毒面罩�?
库度高於驴縄暴露水平100倍或高於IDLH水平或库度不�?(例如在緊急情縭下)﹕使用罩
蓋整靠目、在正亢�?緽下運作�? 立呼吸裝置�?�含輔助正亢立呼吸裝置�?�生系統的C
型正亢罩蓋整靠目、菘送空库的防毒面罩�?
逃生﹕使用罩蓋整靠目�? 立呼吸裝置或任何特縠准許供�?�生用的防毒面罩�?

暴露指南
重量% ACGIH ACGIH ACGIH OSHA OSHA OSHA Celanese Mexico Mexico Mexico
成分及化縒文摘服�? 成分及化 TWA STEL CEILING TWA STEL CEILING WEL TWA STEL CEILING
炭炭�? 縒文摘服 (工作况所
空炭炭碼接觸限度)
丁酮 78-93-3 99.5 200 ppm 300 ppm - 200 ppm - - - 200 ppm 300 ppm -

成分及化縒文摘服空炭炭碼重量% 1990 NIOSH IDLH 1994 NIOSH IDLH
成分及化縒文摘服空炭 (Recognized by OSHA)
炭碼
丁酮 78-93-3 99.5 3000 PPM 3000 ppm

Comments: Celanese狂用ACGIH TLV?�?
* Workplace Exposure Limit

9. 物理和化縒特�?

外貌: 透明、縪色�?�油性液體�??

味道: 靠烈、有“酮”特色的库味�?

Vapor Pressure: 91 mm Hg @ 25 deg C

Vapor Density (Air=1 @ 20 C): 2.41

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
5 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
Boiling Point (760 mmHgA): 79.6 C (175.3 F)

Freezing Point:: -86.7 C (-124.1 F)

Solubility in Water @ 20 C: 26.8 %

Specific Gravity: 0.805 at 20 deg C

Molecular Weight:: 72.11

Evaporation Rate (n-Butyl acetate = 1): 3.3

10. 房定性與反开�?

房定�?: 房定�?

�?避免的情�?: 避免高酷、火焰�?�火花和其他火源�?

�?避免的材�?: 避免接觸夸氧化鈉、石灰和其它靠鹼、鹽酸�?�硫酸和其它靠縪緾酸、胺和氧化咯，如
過氧化物、硝酸�?�高氯酸、鉻酸�?��?�銅或銅合金或雜氮苯�?

危險易燃或分解產�?: 酷分解產品可能含有碳的氧化物�?

危險聚合作用: 不傀產生危險的聚合作用�??

11. 毒�?�資�?

Component Toxicological Information

成分及化縒文摘服空炭炭碼丁酮

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
6 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
Acute Exposure: Excessive exposure to MEK leads to depression of the
central nervous system, shown by loss of coordination, reflexes and
consciousness.

Oral: Slightly toxic; oral LD50 (rat) = 2.7-5.6 g/kg .

Inhalation: Slightly toxic; inhalation LC50 (rat) is estimated to be >
5000 ppm for a 6 hr. vapor exposure based on the lack of mortality in a
repeated exposure study at this level. Other earlier studies exist, but
do not meet current scientific guidelines. Causes irritation of the nasal
passages and throat.

Skin: Slightly toxic; Dermal LD50 (rabbit) = 5.0 - 13 g/kg. Can cause
mild to moderate skin irritation (reddening and swelling). Repeated or
prolonged contact can cause drying of the skin and dermatitis. Not a skin
sensitizer based on human patch test.

Eye: Liquid and vapor can cause severe eye irritation.

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
7 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
Mutagenicity: MEK has been shown to be without genotoxic activity in a
variety of in vitro and in vivo tests. Among the tests which produced
negative results are assays for point mutation (e.g., Ames test and mouse
lymphoma), chromosomal aberration (rat liver cells in vitro and mouse bone
marrow in vivo), DNA damage (unscheduled DNA synthesis in rat
hepatocytes,), and morphologic transformation (BALB 3T3 morphologic
transformation assay). There was some evidence that MEK induced
aneuploidy in yeast, but this does not appear to be biologically important
since negative results were obtained in a mouse micronucleus test.

Carcinogenicity: No toxicologic studies. Not listed by IARC, NTP or OSHA.

Reproductive/Developmental Effects: No human studies have been reported.
An initial inhalation study with rats indicated fetotoxicity (e.g.,
delayed fetal development) and possible teratogenicity at 3000 ppm.
However, a comprehensive follow-up study in rats showed only slight
fetotoxicity accompanied by maternal toxicity at 3000 ppm, but no
teratogenic effects. No significant differences were seen between rats
exposed to 1000 ppm or 400 ppm MEK and the control. Likewise an
inhalation study with mice showed only fetotoxicity at 3000 ppm and no
effects at 1000 ppm or 400 ppm MEK.

The fetotoxicity in mice also was accompanied by maternal toxicity in mice
at 3000 ppm. Since effects reported for the fetus (rats & mice) occurred
only at dose levels where maternal toxicity was evident and are,
therefore, considered secondary outcomes from the maternal toxicity,
methyl ethyl ketone is concluded not to be a developmental toxicant.

Other Effects: MEK is not neurotoxic. It has been shown to potentiate the
neurotoxic effects of hexane, 2,5-hexanedione and methyl-n-butyl ketone.
MEK has also potentiated the liver toxicity of halogenated solvents (e.g.,
chloroform and carbon tetrachloride) in animal studies.

Repeated Exposure: Male and female rats exposed to 0, l250, 2500 or 5000
ppm MEK in air for 6 hrs./day, 5 days/week for 90 days failed to
demonstrate pathological changes attributable to MEK in the organs and
tissues studied. Other studies conducted in rats and on other species at
lower exposure levels had similar results. A dose-related increase in
absolute and relative liver weights was statistically significant at the
5000 ppm exposure level. These effects are considered adaptive in nature.

12. 生緽資料

Component Ecological Information

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
8 of 11
產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
成分及化縒文摘服空炭炭碼丁酮
Ecotoxicity: Methyl ethyl ketone has low acute toxicity to fish (LC50
range - 4,600 - 5,640 ppm) and aquatic invertebrates (EC50 range = 1,950
- 8,890 ppm). At above 100 ppm it may inhibit the growth of blue-green
algae but such concentrations are unlikely to be reached except for short
periods following accidental discharge. A concentration of 900 ppm of MEK
in water caused a 50% inhibition of the germination of lettuce (lactuca
sativa) seeds.

Environmental Fate:

Degradation:
Biodegradation: Extensive data demonstrate that MEK is readily
biodegradable. Determinations in freshwater and seawater demonstrated
that the BOD was a high percentage of the theoretical oxygen demand.
Studies on activated sludge showed that MEK is easily degraded and is not
toxic to sludge microorganisms in concentrations up to 800 ug/liter.
Photodegradation - Although MEK is less reactive in smog than many other
organic chemicals, it does undergo significant photodecomposition probably
because of a combination of direct photolysis and OH radical reactions. In
the presence of 5 ppm NO, and with 35-40% relative humidity and 10 ppm
MEK, a photodecomposition half-life of 9.8 hours was found. The half-life
of MEK calculated in urban conditions is likely to be about 5.5 hours.

Bioaccumulation: No direct information is available on the ability of MEK
to accumulate in biological material. Its high water solubility, rapid
degradation by aquatic bacteria, and low octanol-water partition
coefficient of 0.26 suggest that it is unlikely to concentrate in aquatic
species. Metabolic studies in man demonstrate that concentrations likely
to be present in the environment will not lead to accumulation in human
tissues.

13. 縂靠縭的注意事砜

根傀州和地喀危險縐料铱定炭理溢出材料。建議方法是在驴邦或州准許的炭理設施焚化或作生物炭理。湛注意�?
此資料縃�?用在�?製�?�的材料；加工�?�使用或污染可能�?使本資料不適、不正確或不完整�?

湛注意﹕這一炭理與縂靠資料也可能適用於空容器、縷和靠渣�?�州�? 地铱定或限制非常複雜，�?�且可能於驴�?
铱定。本資料的目的是縡助�? 的炭理與縂靠；炭理與縂靠的最後乜任由縐料的宽有人乜乜。竣铱�?�第9部分，物�?
與化縒特性�?��??

環境保護�?危險縐料代碼�? U159

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產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
14. 運菘資料

US Department of Transportation:
UN/NA Number: UN1193
Shipping name: ETHYL METHYL KETONE
Hazard class: 3
Packing Group: II
DOT Reportable Quantity (RQ): 5000 lbs/2270 kg (Methyl ethyl ketone)
Emergency Response Guide: 127

ICAO/IATA:
IATA UN Number: UN1193
Proper Shipping Name: ETHYL METHYL KETONE
Hazard Classification: 3
Packing group: II
Label: (Flammable Liquid)

IMDG:
International Marine UN Number: UN1193
Proper Shipping Name: ETHYL METHYL KETONE
Hazard Class: 3
Packing Group: II
閃點（縴钥方法）�? -9 C (16 F) (Closed Cup)

Transport Canada
Proper Shipping Name: Methyl Ethyl Ketone

Trade Information
Schedule B Code (export):2914.12.0000

15. 法铱資料
Hazard labeling:

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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
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產品名稱: Methyl ethyl ketone
MSDS 炭碼: 61
材料炭碼: 80061
公垦日期�? 02/02/2006
R phrases
R 11 高度可燃�?
R 36 刺激眼睛�?
R 66 不苦暴露可能�?咖致皮膚乾燥或破裂�??
R 67 库體可能�?咖致瞌睡和眩靠�??

S phrases
S9 竣容器保存在通風的地方�??
S 16 遠離點火�?-湛勿吸靠�?

INTERNATIONAL REGULATIONS
化縒钥伎目淇
列於下列盔家的化縒钥伎目淇的砜目符合豁免資格:
AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN

16. 其它資料

提供课位: 產品指咖�?
Celanese 公司

危險等伎本資料縃供娇NFPA �?/�? HMIS 系統涌究的人縏使用�??

NFPA: Health: 1 Flammability: 3 Reactivity: 0

HMIS: Health: 2* Flammability: 3 Reactivity: 0

下列資料是最新版本MSDS出版後的 The following sections have been revised since the last issue of this
修正: MSDS.

1. 產品與公司識縠資�?
此炭含有資涌之精確程度块我靠�?大限度之�?知�?�我靠縆不表示或保證此炭�?列之任何危險块縃有之危險。就你所倏得之材料之�?
全使用（或與其它物質�?裤使用），Celanese
公司不提供任何明確或暗示之保用�?�其它材料可加重本材料的危險性，本材料亦可加重或增加其它材料的危險�?��?�本材料可磕直接
或間接由其製成的库體、液體或固體材料中峥出�?�使用�?�喀確定本材料是否適於任何使用及�?涌靠的使用方式乜完全乜任。使用�??
必砜符合�?有有關安全及健康克渴。材料安全資涌课由Celanese公司在網際網絡上提供，作牽喀客眶的一砜服空�??
宽有網際網絡的材料安全資涌课縆不表示钥材料安全資涌课持有人即块有關產品的倏買人或用眶�?

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