MSDS PAGE: CAS 50-00-0 67-56-1 7732-18-5 MSDS celanese

產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006

材料安全康傀�?
1. 產品與公司識縠資�?

Product:37% 甲醛/7%甲醇, 溶液
MSDS 炭碼: 45
材料炭碼:80045

Celanese Pte Ltd
111 Somerset Road
Singapore Power Building #02-02/03
Singapore 238164
Tel No: (65) 6733 1767

運菘緊�?�情縭肟钥炭碼﹕
+ (65) 66639259 (Operations Room direct dial)
+ (65) 62656917 (Operations Room direct dial)
+ (65) 62650177(Switchboard, ask for Operations Room)

or fax request to
+(65) 62644190 (Facsimile to Operations Room)
+(65) 62664696 (Facsimile to Operations Room)

or email to
opsroom@semco.psa.com.sg

or Call CHEMTREC 703 527 3887 (USA), collect calls accepted
"+" = International Dialing Access Code

產品使用:尿素和三聚氰胺甲醛夸脂中間物；酚醛夸脂；乙炔化縒品；聚醛夸脂�?

2. 成分/成分資料

成分及化縒文摘服空炭炭碼重量% OSHA 铱定�?�?:
成分及化縒文摘服空炭
炭碼
甲醛 50-00-0 37 - 37.5 危險
甲醇 67-56-1 6.5 - 7.5 危險

Water (CAS 7732-18-5), wt. %: 55 - 56.5

An equilibrium mixture of formaldehyde, methanol, and water with the nominal composition listed above.

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
3. 危險識縠

緊�?�情�?:
危險!
造成皮膚、眼睛及消化道灼葵�??
長期及反客皮膚接觸可造成死亡或失明�??
吞入可能致命或咖致失明�??
造成呼吸道�?�喉康�?�皮膚和眼睛刺激�?
吸入有害�?
可能咖致過敏性呼吸及皮膚反开�?
可燃液體與蒸库�??
致癌危險。含有可能致癌材料�?�致癌風險縌定於接觸縭間長短及程度�??

產品說明

外貌: 透明、縪色液體�??
味道: 靠烈、刺鼻�?? 特的库味�?

靠在健康影砜
暴露途拷: 皮膚、眼睛�?�吸入�?�坎下�??

即縭影砜
皮膚: �?引起皮膚灼葵�? 可能�?引起皮膚過敏反开�? 如果磕皮膚吸收傀有害�?
暴露的徵�?可能包括�?
中央神娇系統亢抑�?引起的頭痛�?�木僵�?�不縡調或奇怪的舉止或昏迷�??
皮膚發紅或卓色�?�腫、癢、魁痛或起泡�?
皮膚長期�?/或重複與浸甲醇的材料接觸�?產生中毒效果、包括铱力受縫和死亡�?

眼睛: 暴露於液�? �?引起坷重眼睛灼葵、縫葵不可�?�轉�? 暴露於库�? �?刺激眼睛�?
暴露的徵�?可能包括�? 眼睛刺激、灼魁的感覺、痛、流眼縄�?/或铱力改卓�??

吸入: �?引起呼吸道刺�?�? 如果吸入�?縫葵�? 可能�?引起過敏呼吸反开�?
暴露的徵�?可能包括�?
中央神娇系統亢抑�?引起的縄心�?�頭靠�?�頭痛�?�木僵�?�不縡調或奇怪的舉止或昏迷�??
流鼻水�?�嘶俊�?�咳嗽�?�胸痛和呼吸困難�? 肺積�?(肺水�?)—徵�?可能延遲康小縭�??
�?铱力有不良影砜�??

坎下: �?引起消化道魁葵�?? 如果坎下�?有害�? 暴露的徵�?可能包括�?
中央神娇系統亢抑�?引起的縄心�?�頭靠�?�頭痛�?�木僵�?�不縡調或奇怪的舉止或昏迷�??
縄心、縄吐�?�失去食欲�?�刺�?腸胃�?/或腹縜�?? 坷重縫葵口�?�喉、食管和/或胃�?

延究/長期影砜 See "Section 11 - Toxicological Information" for studies with experimental
animals.

生殖: 根傀坑物康傀，可能傀引起不良的生殖影砜�??

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2 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
致癌�?: 根傀靠蚩室寇齒坑物研究及有限的人羁康�?，長期或重複呼吸、過分受甲醛暴露可能
�?咖致鼻腫瘤�?�人羁受甲醛暴露的研究顯示混合的結果，指出白�?病及以下�?縭與�?
醛暴露有關﹕
甲醛是﹕
列块OSHA致癌物﹕ 被NTP列块預期的致癌物
listed as carcinogenic to humans, IARC Group I, based on sufficient human
evidence for nasopharyngeal cancer and sufficient evidence in experimental
animals

�?特定器官的影�?: 過度（長期或反客）接觸可咖致�?
中啃神娇系統亢抑
眼睛受葵
消化道縫�?
呼吸道縫�?
過敏反开及皮膚局部刺�?
皮膚縫葵�?
生殖系統受縫
過敏性呼吸反�?
Nasal tract

大量接觸钥化縒品可能�?�?患有下列急�?�和慢�?�器官疾病的病人有不利影砜：
�?般認块在暴露後傀使病情亢化的呼吸�?
病縭: 皮膚
眼睛
中啃神娇系統
Reproductive System

有關钥情，竣�?: �?5部分 �? 跨火措施
�?4部分 �? 急救措施 �?6部分 �? 意外峥放措施
�?8部分 �? 暴露控制/靠人保護
�?9部分 �? 物理與化縒特�?
�?10部分 �? 房定性與反开�?

4. 急救措施

皮膚: 立即用大量清水縚洗皮膚至�?15分缈，縆同縭每下污染的衣服和鞋子。立即郡求治
。衣服开洗乾縌後才能再穿。房向的鞋子�?咖跨�?

眼睛: 立即用大量清水縚洗眼睛至�?15分缈。如果有戴隱形眼鏡縆可以輕易取下縭，�?竣之
取下。立即郡求治 �?

吸入: 移往空库清新炭�?�如果停止呼吸，�?施人工呼吸�?�如果呼吸困難，�?給氧库�?�驴絡醫
生�??

坎下: 切勿引起縄吐。立即郡求治。如果受害�?�完全清醒，給他喝一杯水。切勿餵昏迷�?
人任何縷西�??

醫生注意: �?察延究肺水腫�? 呼吸道暴露後可能�?咖致化縒肺炎�?

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
5. 跨火措施

NFPA: Health: 3 Flammability: 2 Reactivity: 0

易燃特�??

閃點（縴钥方法）�? 69 C (156 F)

易燃限度，在空库，容�?%
上限: 73% (Formaldehyde)
36.5% (Methanol at 25 deg C)
Not Applicable (Water)
下限: 7% (Formaldehyde)
5.5% (Methanol at 25 deg C)
Not Applicable (Water)

自坑點燃控度: 300 C (572 F) (Formaldehyde )
385 C (725 F) (Methanol)

燃魁產品�? �?氧化碳�??

跨火媒介: 大火使用酒精羁的水溶成膜泡沫�? 小火使用二氧化碳或乾化縒品�??

消防說明 �?用水冷縮暴露在火中的建築和槽。竣水可用於降低火枯，縆竣溢出物�?峥成不易�?
的混合物�?
竣人縏撤離火源至迎風地點。如果有可能暴露在蒸库下或有可燃魁的產品存在，开�?
全套消防裝夸和NIOSH核准�? 立呼吸裝夸�?�氧化化縒品在著火的情縭下可能傀加�?�燃
魁的速度�?

消防環保靠題溢出的水和蒸库肟可能有腐蝕�?��?�用堤縆收集用於跨火的水，中和後才峥放�??
可使用水霧流控制蒸库和燃魁库體�??
再用�?藏快設夸和其它跨火設夸前�?完全清除污染�?

6. 意外峥放措施

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
溢出或开漏說�? 排除點火源�??
竣铱�?8部分有關�? 的人縏保護設夸�?�用土堤或非易燃的吸收咯隔離溢出物，使污�?
保持在最小的範窥咳�?? 水霧流可以縫少蒸库�??
如果有起火的可能，开使用酒精羁的水溶成膜泡沫宽覆蓋溢出物，或用水霧流分散�?
库�??
�?避免流入下水道及通往水道的肯渠�?�若州及地方有铱定，�?通知地方 �?。竣�?�?
的容器置於�?�風良好炭�?? 使用氨基磺酸或重靠硫酸鈉中和�?
使用非燃魁的吸收咯清除或用少許水縚洗小铱模的溢出物�?�用真空吸除或窟除乾縌�??

在美盔境咳，如果�?24小縭咳峥放出的分量相等於或超於下列开矿告的分量縭，开�?
肟�?�全盔回�?中心�?(National Response Center) (800-424-
8802)和適的州�? 地緾關﹕
270 lbs. of the material as is; based on a Reportable Quantity of 100 lbs.
for formaldehyde.

蚩散不必要在况的人；隔離危險地縙縆拒絕任何人進入。保持在迎風的位置；避開�?
的地縙�?? 如果火磕涉及到運菘罐、火芸罐芸或卡芸罐芸，开在各靠方向上隔離800�?
�?0.5哩）�?
如果情縭有必要开撤離砜風地縙以預防暴露，縆卓蒸库或靠消散。某些情縭的溢出�?
可能使相遠距離的砜風地縙暴露於有毒或可燃魁的库度�?

7. 炭理與喀�?

炭理: 在�?�風足框的環境下使用�?
不使用縭�?竣容器關緊�?�打開容器縭，开小心挚慎卓累積的亢力透出。避免吸入蒸�?
。避免與眼睛、皮膚或衣服接觸。炭理後�?用肥皂和水控底洗乾縌。沾污的衣服�?�?
底清除污染後才再使用。污染的皮革衣物�?咖跨�?

本產品可能傀產生靜肟。在運菘材料縭，�?竣設夸接�?/約束以預防靜肟的累積。在�?
盔，�?有喀藏和炭理用的肟子設夸都必砜符合�?�全盔肟库铱程�??(�?500�?501�?)�?�?
險地點的要求�?

�?�?: 不使用縭，竣�?有容器關緊�?�喀存在縘有昕光照射和不可緽透的地板上�??
湛勿與不兼容的材料喀存�?�竣铱�?�第10部分，房定�?�與反开性�?��??

8. 暴露控制/靠人保護

工程控制 �?般或�?峥�?�風作块雇縏暴露的唯�?控制方法通常是不足框的�?��?�常靠先選狂的是�?
部�?�風�?

�?隨縭渴夸好安全淋浴和洗眼設夸�?
靠人保護設夸
皮膚保護: 穿�?�不過的衣服和手套以便預防接觸�?�建議使用丁基橡膠�?�铱情縭，如果有足框的降
解和緽�?�資料，可使用其它保護材料�?�如果在使用本化縒品的同縭使用其它化縒品�?
選狂的材料开能保護所有使用的化縒品�??

眼睛/目部保護: 如有可能接觸眼睛縭开戴化縒護目鏡�?
如果可能靠竣到目上縭，除了戴護目鏡外呖开戴面罩�??
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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
5 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006

呼吸道保�?: 根傀工作况所的污染程度及防毒面罩的工作限度，使用娇�?�全盔驴縄安全與保健縒傀
�?(NIOSH)
核准使用的防毒面罩�?�以下是建議驴縄暴露水平至少�?有的裝夸。竣铱第3�?8�?11�?
分以便估涌驴縄暴露水平�??
甲醛库度高於驴縄暴露水平1倍，但低�?10倍﹕使用罩蓋整靠目的空库縌化防毒面罩�?
HEPA粒子過縑器，縆加特縠核准用於預防甲醛的筒或縑毒罐，或罩蓋整靠目的肟坑�?
库縌化防毒面罩及HEPA粒子過縑器，縆加特縠核准用於預防甲醛的筒或縑毒罐。空�?
縌化部件必砜有結束服空扣命的顯示器，或必砜有�?靠更縌縭間表的文件�?�否縯使�?
菘�?�的空库�?
库度高於驴縄暴露水平10倍，但低於驴縄暴露水平的100倍或IDLH﹕使用C型罩蓋整�?
目�?�在亢力要求或不苦菘送空库的防毒面罩�?
库度高於IDLH水平或库度不�?(例如在緊急情縭下)﹕使用罩蓋整靠目、在正亢�?緽下
運作�? 立呼吸裝置�?�含輔助正亢立呼吸裝置�?�生系統的C型正亢罩蓋整靠目、菘�?
空库的防毒面罩�??
逃生﹕使用正亢罩蓋整靠目�? 立呼吸裝置或罩蓋整靠目�?�在下巴或前或後安裝工縄
尺寸、特縠核准用於預防甲醛特縠核准用於預防甲醛的縑毒罐�??

暴露指南
重量% ACGIH ACGIH ACGIH OSHA OSHA OSHA Celanese Mexico Mexico Mexico
成分及化縒文摘服�? 成分及化 TWA STEL CEILING TWA STEL CEILING WEL TWA STEL CEILING
炭炭�? 縒文摘服 (工作况所
空炭炭碼接觸限度)
甲醛 50-00-0 37 - 37.5 - - 0.3 ppm 0.75 ppm 2 ppm - 0.75 ppm - - 2 ppm
(TWA); 2
ppm (STEL)
甲醇 67-56-1 6.5 - 7.5 200 ppm 250 ppm - 200 ppm - - - 200 ppm 250 ppm -

成分及化縒文摘服空炭炭碼重量% 1990 NIOSH IDLH 1994 NIOSH IDLH
成分及化縒文摘服空炭 (Recognized by OSHA)
炭碼
甲醛 50-00-0 37 - 37.5 30 ppm 20 ppm
甲醇 67-56-1 6.5 - 7.5 25,000 PPM 6000 ppm

Comments: Celanese公司根傀�?�?有現有資料的科縒評估，縌定喀甲醛不狂�? ACGIH 上限值�??
Celanese 公司�?甲醇狂用 ACGIH TLV �?

9. 物理和化縒特�?

外貌: 透明、縪色液體�??

味道: 靠烈、刺鼻�?? 特的库味�?
o
pH (1% soln in water @ 25 C): 3-6

Vapor Pressure: 23 mmHg @ 25 deg C (calculated)

Vapor Density (Air=1 @ 20 C): Formaldehyde: 1.04 (calculated)
Water: 0.62 (calculated)
Methanol: 1.11 (calculated)

Boiling Point (760 mmHgA): 97 C (207 F)
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運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
6 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006

Freezing Point: �? 16 C (61 F)以下，固緽甲醛聚合物逐縰形成。冰�? �? 0
C (32 F)以下出現�?

Solubility in Water @ 20 C: complete

Specific Gravity: 1.092 @ 25 deg C

Molecular Weight:: Formaldehyde: 30.0
Water: 18
Methanol: 32.0

10. 房定性與反开�?

房定�?: 房定�?

�?避免的情�?: 避免高酷、火焰�?�火花和其他火源�?

�?避免的材�?: 避免接觸夸氧化鈉、石灰和其它靠鹼、鈉、饪和其它靠鹼金抠�?�鹽酸�?�硫酸和其它�?
縪緾酸�?�氮氧化物�?�胺和氧化咯如過氧化物�?�硝酸�?�高氯酸、三氧化鉻�?�苯酚或尿素
�?

危險易燃或分解產�?: 酷分解產品可能含有碳的氧化物�?

危險聚合作用: 不傀產生危險的聚合作用�??

11. 毒�?�資�?

Component Toxicological Information

成分及化縒文摘服空炭炭碼甲醛

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
Acute Exposure: Toxicity information on the solution is generally not
available. Information on the solution components is listed next.

Oral LD50: 800mg/kg (rats); slightly toxic to animals.

Inhalation LC50: 474ppm (rats,4 hrs.); moderately toxic to animals.

Skin: Severely irritating/corrosive to rabbit skin depending on exposure
duration and concentration; moderately toxic to animals (LD50, rabbits:
270mg/kg); causes skin sensitization in humans and guinea pigs.

Eye: Severely irritating to rabbit eyes.

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8 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
Mutagenicity: Genotoxic potential was noted in a variety of in vitro
systems. Results in vivo have been mixed probably due to the presence of
metabolic processes for detoxifying.

Carcinogenicity: Oral-Formaldehyde was not carcinogenic in several well-
conducted rodent lifetime drinking water studies. Repeated dermal-topical
application on mice has not indicated carcinogenic potential. Inhalation-
Rats and mice were exposed to 2.0, 5.6, or 14.3 ppm formaldehyde for
6hrs/day, 5 days/week for 24 months. In rats no treatment-related tumors
were seen at 2 ppm while at 5.6 ppm 1% had nasal tumors and at 14.3 ppm
43% had nasal tumors. In mice no treatment-related tumors were observed
at 2 ppm or 5.6 ppm while 1% had nasal tumors at 14.3 ppm. IARC: Group I,
Carcinogenic to Humans, based on sufficient human (nasopharyngeal cancer)
and experimental animal data. Formaldehyde is listed as an OSHA
carcinogen. Formaldehyde is listed as an anticipated carcinogen by the
NTP.

Hauptmann, et. al. (2004) have reported a statistically significant dose-
related increase in the incidence of nasopharyngeal tumors in a large
cohort of formaldehyde exposed workers. In another study by Hauptmann,
et. al. (2003) based upon the same cohort, a statistically significant
dose-related increase of leukemia mortality was observed. However, this
increase was seen only for a peak exposure metric and the rate of leukemia
mortality was less than that of the unexposed general population. In
addition, the Hauptmann et. al. (2003) results are not consistent with the
findings of Coggon et. al. (2003). Coggon et. al. found no association
between formaldehyde exposure and leukemia incidence in a large cohort of
U.K. workers with estimated formaldehyde exposures higher than the
Hauptmann et. al. (2003) study. A recent NIOSH study (Pinkerton, et. al.
2004) based on a cohort of formaldehyde exposed garment workers reported
only a marginal association with leukemia incidence. Experimental data
linking formaldehyde exposure with toxicity in organs, including the bone
marrow, remote from the portal of entry is lacking. Also, an established
mechanism for induction of leukemia by formaldehyde is not available.
Furthermore, formaldehyde inhalation by rats in several well-conducted
cancer bioassays did not induce leukemia.

Reproductive/Developmental Effects: In a developmental toxicity study with
mice dosed orally by gavage at 74, 148 or 185 mg/kg/day, no fetotoxic or
teratogenic effects were seen. In a developmental toxicity study with
rats exposed via inhalation to 2, 5 or 10ppm formaldehyde, treat-related
developmental effects were not observed. In a reproduction study, dogs
received the equivalent of 9.4 mg/kg/day of formaldehyde in feed during
days 4-56 after mating without adverse reproductive effects.

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
Repeated Exposure: Inhalation exposure (6hrs./day;5 days/week;13 weeks)
of rats resulted in nasal tissue irritation at 10 or 20ppm, but not at
2ppm. Monkeys exposed for 26 weeks (22hrs./day;7 days/week) had nasal
irritation at 3ppm but not at 1ppm. Oral exposure of rats to formaldehyde
in the drinking water at a dose equivalent to 82-109 mg/kg/day over a
lifetime resulted in stomach tissue irritation while a dose of 15-21
mg/kg/day was without effect.
成分及化縒文摘服空炭炭碼甲醇
Acute Exposure: Toxicity information on the solution is generally not
available. Information on the solution components is listed next.

Oral LD50: 6.2-12.9g/kg (rats); practically nontoxic to animals. However,
based on human exposure reports, a small amount (usually two or more
ounces) can cause mental sluggishness, nausea and vomiting leading to
severe illness, and may produce adverse effects on vision with possible
blindness or death if treatment is not received.

Inhalation LC50: 64000ppm (rats,4 hrs.); practically nontoxic to animals.
Based on human exposure reports, levels substantially above the TLV cause
stupor, headache, nausea, dizziness, unconsciousness and may produce
adverse effects on vision.

Skin: Irritating to rabbit skin. Severity depends on the quantity
administered and exposure period and is related to the defatting
properties of methanol; slightly toxic to animals (minimum lethal dose,
monkeys: 1.6g/kg; LD50, rabbits:16g/kg). Based on human exposure reports,
prolonged and repeated skin contact with methanol-soaked material has
produced toxic effects including vision effects and death.

Eye: Severely irritating to rabbit eyes.

----------------------------------------------------------------------------------------------------------------------------

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
Mutagenicity: Methanol - Not genotoxic in most in vitro assays. Not
genotoxic in vivo in mice exposed via inhalation up to 4000ppm (6hrs./day
for 5 days) and subsequently examined for cytogenetic effects.

Carcinogenicity: Methanol - Inhalation-Not carcinogenic in lifetime
inhalation studies (reported in limited detail) in rats and mice at
concentrations of 10-1000ppm. Dermal-Not carcinogenic in mice exposed
dermally to 0.02ml/day, 2 days/week over a lifetime in a study of limited
quality.

Reproductive/Developmental Effects: Methanol - In an inhalation
developmental toxicity study, rats were exposed 6hrs./day to 5000, 10000
or 20000ppm vapors. A significant teratogenic response was seen at
20000ppm. Fetotoxicity was noted at 10000ppm, but not at 5000ppm. In an
inhalation developmental toxicity study, mice were exposed 7hrs./day to
2000, 5000 or 10000ppm vapors. Methanol caused developmental toxicity at
all levels. Oral administration of methanol via gavage at 1.3, 2.6 or 5.2
ml/kg to rats resulted in developmental toxicity at all levels.

Repeated Exposure: Methanol - Inhalation exposure (6hrs./day; 5days/week)
of monkeys to vapor concentrations of 500, 2000 or 5000ppm for 4 weeks did
not result in any treatment-related effects. Monkeys exposed to methanol
vapors of 10, 100 or 1000ppm for 22hrs./day for up to 2.5yrs. showed
changes in the liver, kidney and nervous system at 1000ppm (limited
details reported). Rats exposed by oral gavage to 100, 500 or
2500mg/kg/day methanol for 90days exhibited only effects on organ weight
(brain) and serum enzymes (SGPT,AP) at the high dose.

12. 生緽資料

Component Ecological Information

成分及化縒文摘服空炭炭碼甲醛
Ecotoxicity: Formaldehyde exhibits slight acute toxicity to various fish
species. The 24-, 48- and 96-hr. LC50 values (bluegill sunfish, trout,
bass, salmon, catfish, carp, golden orfe) are in the range 10-1000ppm.
Algae and some invertebrates appear more susceptible e.g., acute toxicity
occurs in green algae at 0.3-0.5ppm and in the water flea (daphnids) at 2-
52ppm (24/48-hr. EC50). Formaldehyde has bactericidal properties at low
levels (EC50, E. coli=1ppm).

----------------------------------------------------------------------------------------------------------------------------

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產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
Environmental Fate: The short atmospheric half-life, the low n-
octanol/water partition coefficient and the ability of animals &
microorganisms to rapidly biodegrade formaldehyde are expected to lead to
its ready removal if released into the environment.
Degradation: Formaldehyde in aqueous effluent is degraded by activated
sludge and sewage in 48-72 hr. In a die-away test with lake water,
degradation was complete in 30 hrs. under aerobic conditions and 48 hrs.
under anaerobic conditions. Atmospheric photochemical degradation is
rapid with estimated half-lives of 19hrs. or less.

Bioaccumulation: The log n-octanol/water partition coefficient is 0.35.
This suggests that formaldehyde has relatively low potential to
bioaccumulate.

成分及化縒文摘服空炭炭碼甲醇
Ecotoxicity: Toxicity information on the solution is generally not
available. Information on solution components is listed next.

Methanol exhibits low acute toxicity to aquatic species. The 24-, 48- and
96-hr. LC50 values for various fish species (bluegill sunfish, fathead
minnows, rainbow trout, goldfish, carp, bleak, creek chub) are in the
range 1700-28100ppm. The 18-, 24- and 48-hr. EC50 values for the water
flea (daphnids) are in the range 10000-24500ppm. The 18-hr. LC50 for
grass shrimp is 21900ppm and the 24-hr. LC50 for brine shrimp is
>10000ppm. Cell multiplication was inhibited after 8 days exposure to
8000ppm and 530ppm in the green algae (Scenedesmus quadricauda) and blue-
green algae (Anacystis aeruginosa), respectively.

Environmental Fate: The ability of animals and microorganisms to rapidly
biodegrade methanol coupled with its low n-octanol/water partition
coefficient is expected to lead to its rapid removal if released into the
environment.

Degradation: Under aerobic conditions methanol is readily biodegradable.
The 5-Day BOD values are 48-83% of COD. Biodegradation also occurs under
anaerobic conditions, e.g. 83-91% degradation in a marine water/sediment
system after 3 days. Atmospheric photochemical degradation (half-life) is
estimated to be be 17.8days. Volatilization half-lives of 4.8days and
51.7days have been estimated for a model river and a model pond,
respectively.

Bioaccumulation: The log n-octanol/water partition coefficient for
methanol is -0.77. This suggests that methanol has low potential to
bioaccumulate.

----------------------------------------------------------------------------------------------------------------------------

運菘緊�?�情�?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
12 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
13. 縂靠縭的注意事砜

根傀州和地喀危險縐料铱定炭理溢出材料。建議方法是在驴邦或州准許的炭理設施焚化或作生物炭理。湛注意�?
此資料縃�?用在�?製�?�的材料；加工�?�使用或污染可能�?使本資料不適、不正確或不完整�?

湛注意﹕這一炭理與縂靠資料也可能適用於空容器、縷和靠渣�?�州�? 地铱定或限制非常複雜，�?�且可能於驴�?
铱定。本資料的目的是縡助�? 的炭理與縂靠；炭理與縂靠的最後乜任由縐料的宽有人乜乜。竣铱�?�第9部分，物�?
與化縒特性�?��??

14. 運菘資料

US Department of Transportation:
UN/NA Number: UN 2209
Shipping name: FORMALDEHYDE SOLUTIONS
Hazard class: 8
Packing Group: PG III
DOT Reportable Quantity (RQ): 100 lb/45.4 kg (FORMALDEHYDE)
Emergency Response Guide: 132

ICAO/IATA:
IATA UN Number: UN 2209
Proper Shipping Name: FORMALDEHYDE SOLUTIONS
Hazard Classification: 8
Packing group: III
Label: Corrosive

IMDG:
International Marine UN Number: UN 2209
Proper Shipping Name: FORMALDEHYDE SOLUTIONS
Hazard Class: 8
Packing Group: III
閃點（縴钥方法）�? 69 C (156 F)

Transport Canada

Trade Information
Schedule B Code (export):2912.11.0000
Harmonization Code (import): 29121100

----------------------------------------------------------------------------------------------------------------------------

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13 of 14
產品名稱: Formaldehyde 37%/Methanol 7%, solution
MSDS 炭碼: 45
材料炭碼: 80045
公垦日期�? 02/02/2006
15. 法铱資料

INTERNATIONAL REGULATIONS
化縒钥伎目淇
列於下列盔家的化縒钥伎目淇的砜目符合豁免資格:
AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN

16. 其它資料

提供课位: 產品指咖�?
Celanese 公司

危險等伎本資料縃供娇NFPA �?/�? HMIS 系統涌究的人縏使用�??

NFPA: Health: 3 Flammability: 2 Reactivity: 0

HMIS: Health: 3* Flammability: 2 Reactivity: 0

下列資料是最新版本MSDS出版後的 The following sections have been revised since the last issue of this
修正: MSDS.

1. 產品與公司識縠資�?
此炭含有資涌之精確程度块我靠�?大限度之�?知�?�我靠縆不表示或保證此炭�?列之任何危險块縃有之危險。就你所倏得之材料之�?
全使用（或與其它物質�?裤使用），Celanese
公司不提供任何明確或暗示之保用�?�其它材料可加重本材料的危險性，本材料亦可加重或增加其它材料的危險�?��?�本材料可磕直接
或間接由其製成的库體、液體或固體材料中峥出�?�使用�?�喀確定本材料是否適於任何使用及�?涌靠的使用方式乜完全乜任。使用�??
必砜符合�?有有關安全及健康克渴。材料安全資涌课由Celanese公司在網際網絡上提供，作牽喀客眶的一砜服空�??
宽有網際網絡的材料安全資涌课縆不表示钥材料安全資涌课持有人即块有關產品的倏買人或用眶�?

----------------------------------------------------------------------------------------------------------------------------

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