MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MANGANESE SULFATE
SYNONYMS
MnSO4, O4S.Mn, "manganous sulphate", "manganese (II) sulphate", "manganese (II) sulphate"
, "sulphuric acid, manganese (II) salt", "sulphuric acid, manganese (II) salt",
"manganese (2+) sulphate", "manganese (II) sulfate", "manganese (II) sulfate", "manganous
sulfate", 0783.25, 0783.50
PROPER SHIPPING NAME
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains manganese sulfate)
PRODUCT USE
Used as a nutrient and/or dietary supply food additive and as a tracer mineral added to
animal feeds; for dyeing; for red glazes on porcelain; boiling oils for varnishes; in
fertilizers for vines and in tobacco.
SUPPLIER
Company: Quantum Chemicals Pty Ltd
Address:
70 Quantum Close
Dandenong South
Victoria 3175
Telephone: 03 8795 8000
Emergency Tel: 1300 131 001
Fax: 03 8795 8099
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Harmful: danger of serious damage to health by Do not breathe dust.
prolonged exposure through inhalation and if
swallowed.
Toxic to aquatic organisms may cause long- term Wear suitable protective clothing.
adverse effects in the aquatic environment.
Inhalation and/or ingestion may produce health Use only in well ventilated areas.
damage*.
Cumulative effects may result following Keep container in a well ventilated place.
exposure*.
* (limited evidence). To clean the floor and all objects contaminated
by this material use water.
This material and its container must be disposed
of in a safe way.
Keep away from food drink and animal feeding
stuffs.
Take off immediately all contaminated clothing.
If swallowed IMMEDIATELY contact Doctor or
Poisons Information Centre (show this container
or label).
Use appropriate container to avoid environment
contamination.
Avoid release to the environment. Refer to
special instructions/ safety data sheets.
This material and its container must be disposed
of as hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
manganese sulfate 7785-87-7 > 98
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 3 of 12
Section 4 - FIRST AID MEASURES
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin or hair contact occurs:
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Both dermal and oral toxicity of manganese salts is low because of limited solubility of
manganese. No known permanent pulmonary sequelae develop after acute manganese exposure.
Treatment is supportive.
[Ellenhorn and Barceloux: Medical Toxicology]
In clinical trials with miners exposed to manganese-containing dusts, L-dopa relieved
extrapyramidal symptoms of both hypo kinetic and dystonic patients. For short periods of
time symptoms could also be controlled with scopolamine and amphetamine. BAL and calcium
EDTA prove ineffective.
[Gosselin et al: Clinical Toxicology of Commercial Products.].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water courses.
路 Use fire fighting procedures suitable for surrounding area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES
FIRE/EXPLOSION HAZARD
路 Non combustible.
路 Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: sulfur oxides (SOx), metal oxides.
FIRE INCOMPATIBILITY
None known.
HAZCHEM: 2X
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Environmental hazard - contain spillage.
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Use dry clean up procedures and avoid generating dust.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Environmental hazard - contain spillage.
Moderate hazard.
路 CAUTION: Advise personnel in area.
路 Alert Emergency Services and tell them location and nature of hazard.
路 Control personal contact by wearing protective clothing.
路 Prevent, by any means available, spillage from entering drains or water courses.
路 Recover product wherever possible.
路 IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and
place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up
and place in labelled containers for disposal.
路 ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise Emergency Services.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 10 metres
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 5 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES
IERG Number 47
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 171 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
manganese sulfate 500 mg/m鲁
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
manganese sulfate 12.5 mg/m鲁
other than mild, transient adverse effects without perceiving a clearly defined odour is:
manganese sulfate 7.5 mg/m鲁
The threshold concentration below which most people will experience no appreciable risk of health effects:
manganese sulfate 0.5 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 6 of 12
Section 7 - HANDLING AND STORAGE
路 DO NOT allow material to contact humans, exposed food or food utensils.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately. Launder contaminated clothing before re
-use.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
Glass container.
路 Polyethylene or polypropylene container.
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Metals and their oxides or salts may react violently with chlorine trifluoride. Chlorine
trifluoride is a hypergolic oxidiser. It ignites on contact (without external source of
heat or ignition) with recognised fuels - contact with these materials, following an
ambient or slightly elevated temperature, is often violent and may produce ignition. The
state of subdivision may affect the results.
STORAGE REQUIREMENTS
Observe manufacturer's storing and handling recommendations.
_____________________________________________________
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ X + X 0 +
_____________________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m鲁 STEL mg/m鲁
_________ _________ _____ _____
Australia Exposure manganese sulfate 1 3
Standards (Manganese, fume (as
Mn))
Australia Exposure manganese sulfate 1
Standards (Manganese, dust &
compounds (as Mn))
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
manganese sulfate 500
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
MATERIAL DATA
Ceiling values were recommended for manganese and compounds in earlier publications. As
manganese is a chronic toxin a TWA is considered more appropriate. Because workers
exposed to fume exhibited manganism at air-borne concentrations below those that affect
workers exposed to dust a lower value has been proposed to provide an extra margin of
safety. This value is still above that experienced by two workers exposed to manganese
fume in the course of one study.
A number of studies have shown that susceptibility to the effects of manganese at or
about 1 - 5 mg/m3 (TWA) can lead to clinical manifestations of manganism or more commonly
to the development of indicators of sub-clinical manganism (e.g. hand tremor, exaggerated
reflexes, short-term memory deficits, poor psychomotor performance). Controlling long
-term exposure to the recommended ES TWA level or below should provide protection for
those individuals susceptible to neurological effects of prolonged exposure.
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.
RESPIRATOR
Protection Factor Half- Face Respirator Full- Face Respirator Powered Air Respirator
10 x ES P1 Air- line* -- PAPR- P1 -
50 x ES Air- line** P2 PAPR- P2
100 x ES - P3 -
Air- line* -
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
100+ x ES - Air- line** PAPR- P3
* - Negative pressure demand ** - Continuous flow.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved
respirator. Correct fit is essential to obtain adequate protection. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure
adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants
generated in the workplace possess varying "escape" velocities which, in turn, determine
the "capture velocities" of fresh circulating air required to effectively remove the
contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., evaporating 0.25- 0.5 m/s (50- 100 f/min.)
from tank (in still air).
aerosols, fumes from pouring operations, 0.5- 1 m/s (100- 200 f/min.)
intermittent container filling, low speed
conveyer transfers, welding, spray drift,
plating acid fumes, pickling (released at low
velocity into zone of active generation)
direct spray, spray painting in shallow booths, 1- 2.5 m/s (200- 500 f/min.)
drum filling, conveyer loading, crusher dusts,
gas discharge (active generation into zone of
rapid air motion)
grinding, abrasive blasting, tumbling, high 2.5- 10 m/s (500- 2000 f/min.)
speed wheel generated dusts (released at high
initial velocity into zone of very high rapid
air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to 1: Disturbing room air currents
capture
2: Contaminants of low toxicity or of nuisance 2: Contaminants of high toxicity
value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood- local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 9 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
multiplied by factors of 10 or more when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Pale pink, odourless, hygroscopic powder or crystals. Insoluble in ether. This material
exists in anhydrous and hydrated forms. On heating, the tetrahydrate readily converts to
the monohydrate, which in turn loses water at approximately 450 C to form the anhydrous
salt. Solubility in water is 52 g/100 ml at 5 C and 70 g/100 ml at 70 C. Commercially
supplied as a mixture of the tetra- and the pentahydrate forms or in the monohydrate form.
PHYSICAL PROPERTIES
Solid.
Mixes with water.
Molecular Weight: 151.00 Boiling Range (掳C): 850 decomposes.
Melting Range (掳C): 700 Specific Gravity (water=1): 2.95 - 3.25
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not available. Vapour Pressure (kPa): Not applicable
Volatile Component (%vol): Not applicable. Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not applicable Flash Point (掳C): Not applicable
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (掳C): Not applicable Decomposition Temp (掳C): 850
State: Divided solid Viscosity: Not Applicable
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Poisonings rarely occur after oral administration of manganese salts because they are
poorly absorbed from the gut.
EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may cause transient discomfort characterised by tearing or
conjunctival redness (as with windburn). Slight abrasive damage may also result. The
material may produce foreign body irritation in certain individuals.
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
Inhalation of dusts, generated by the material during the course of normal handling, may
be damaging to the health of the individual.
The material is not thought to produce respiratory irritation (as classified by EC
Directives using animal models). Nevertheless inhalation of dusts, or fumes, especially
for prolonged periods, may produce respiratory discomfort and occasionally, distress.
Manganese fume is toxic and produces nervous system effects characterised by tiredness.
Acute poisoning is rare although acute inflammation of the lungs may occur. A chemical
pneumonia may also result from frequent exposure. Inhalation of freshly formed metal
oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may
result in "metal fume fever". Symptoms may be delayed for up to 12 hours and begin with
the sudden onset of thirst, and a sweet, metallic or foul taste in the mouth. Other
symptoms include upper respiratory tract irritation accompanied by coughing and a dryness
of the mucous membranes, lassitude and a generalised feeling of malaise. Mild to severe
headache, nausea, occasional vomiting, fever or chills, exaggerated mental activity,
profuse sweating, diarrhoea, excessive urination and prostration may also occur.
Tolerance to the fumes develops rapidly, but is quickly lost. All symptoms usually
subside within 24-36 hours following removal from exposure.
CHRONIC HEALTH EFFECTS
Harmful: danger of serious damage to health by prolonged exposure through inhalation and
if swallowed.
This material can cause serious damage if one is exposed to it for long periods. It can
be assumed that it contains a substance which can produce severe defects. This has been
demonstrated via both short- and long-term experimentation.
TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2150 mg/kg
Oral (Mouse) LD50: 2330 mg/kg
Intraperitoneal (Mouse) LD50: 147 mg/kg
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Management Authority for disposal.
路 Bury residue in an authorised landfill.
路 Recycle containers if possible, or dispose of in an authorised landfill.
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 11 of 12
Section 14 - TRANSPORTATION INFORMATION
Labels Required: MISCELLANEOUS
HAZCHEM: 2X
UNDG:
Dangerous Goods Class: 9 Subrisk: None
UN Number: 3077 Packing Group: III
Shipping Name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains manganese sulfate)
Air Transport IATA:
ICAO/IATA Class: 9 ICAO/IATA Subrisk: None
UN/ID Number: 3077 Packing Group: III
Special provisions: A97
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID
N.O.S.
Maritime Transport IMDG:
IMDG Class: 9 IMDG Subrisk: None
UN Number: 3077 Packing Group: III
EMS Number: F- A, S- F Special provisions: 274 909 944
Marine Pollutant: Not Determined
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
manganese sulfate (CAS: 7785-87-7) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - inorganic chemicals)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Agricultural uses (Stock)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
MANGANESE SULFATE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 26-Jul-2006 CHEMWATCH 10215
NC317TCP Version No:3
CD 2007/3 Page 12 of 12
Section 16 - OTHER INFORMATION
Issue Date: 26-Jul-2006
Print Date: 2-Jan-2008
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