Material Safety Data Sheet
Sika庐 Cleaner S
1. Product and company identification
Product name : Sika庐 Cleaner S
Supplier : Sika Corporation, Industry
30800 Stephenson Highway
Madison Heights, MI 48071
www.sikaindustry.com
Telephone no. : (888) 832 - 7452
Fax no. : (248) 577 - 0810
In case of emergency : CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
Manufacturer : Sika Corporation, Operations
201 Polito Avenue
Lyndhurst, NJ 07071
www.sikacorp.com
Telephone no. : (201) 933 - 8800
Validation date : 27. May 2008.
Print date : 27. May 2008.
Product type : Aerosol.
2. Hazards identification
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Potential acute health effects
Inhalation Slightly irritating to the respiratory system.
:
Ingestion : Harmful if swallowed.
Skin : Slightly irritating to the skin.
Eyes : Slightly irritating to the eyes.
Potential chronic health effects
Chronic effects :Repeated or prolonged contact with spray or mist may produce chronic eye irritation and
severe skin irritation.
See toxicological information (section 11)
3. Composition/information on ingredients
Name CAS number %
distillates (petroleum), hydrotreated light 64742-47-8 30 - 60
petroleum gases, liquefied 68476-85-7 15 - 40
silica, amorphous, fumed 7631-86-9 0.5 - 1.5
There are no ingredients or additional ingredients present which, within the current knowledge of the supplier and
in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
4. First aid measures
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
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Sika庐 Cleaner S
5. Fire-fighting measures
Flammability of the product : Extremely flammable. Flammable aerosol. In a fire or if heated, a pressure increase will
occur and the container may burst, with the risk of a subsequent explosion. Gas may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back, causing fire or explosion. Bursting aerosol containers may be
propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous combustion : Decomposition products may include the following materials:
carbon oxides
products
metal oxide/oxides
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
6. Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via
a licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble or absorb with an inert dry material and place in an appropriate waste
disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of
via a licensed waste disposal contractor.
7. Handling and storage
Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use non-sparking tools. Empty containers retain product
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Sika庐 Cleaner S
7. Handling and storage
residue and can be hazardous. Pressurized container: protect from sunlight and do not
expose to temperatures exceeding 50掳C. Do not pierce or burn, even after use.
Storage : Store in accordance with local regulations. Store in a segregated and approved area.
Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see section 10) and food and drink. Eliminate all ignition
sources. Use appropriate containment to avoid environmental contamination.
8. Expose controls/personal protection
Product name Exposure limits
distillates (petroleum), hydrotreated light ACGIH TLV (United States, 1/2007). Skin Notes: Refers to Appendix
A -- Carcinogens. Application restricted to conditions in which
there are negligible aerosol exposures. ACGIH 2003 Adoption
TWA: 200 mg/m鲁 8 hour(s).
petroleum gases, liquefied ACGIH TLV (United States, 1/2007).
TWA: 1000 ppm 8 hour(s).
NIOSH REL (United States, 12/2001).
TWA: 1800 mg/m鲁 10 hour(s).
TWA: 1000 ppm 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 1800 mg/m鲁 8 hour(s).
TWA: 1000 ppm 8 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 1800 mg/m鲁 8 hour(s).
TWA: 1000 ppm 8 hour(s).
silica, amorphous, fumed NIOSH REL (United States, 12/2001).
TWA: 6 mg/m鲁 10 hour(s).
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
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Sika庐 Cleaner S
9. Physical and chemical properties
Flash point : Closed cup: -20掳C (-4掳F)
Auto-ignition temperature : 180掳C (356掳F)
Flammable limits : Lower: 0.6%
Upper: 6.5%
Color : Colorless.
Odor : Hydrocarbon.
Solubility : Insoluble in the following materials: cold water.
10 . Stability and reactivity
Stability : The product is stable. Under normal conditions of storage and use, hazardous
polymerization will not occur.
Conditions to avoid : Avoid all possible sources of ignition (spark or flame).
Materials to avoid : No specific data.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
11 . Toxicological information
Acute toxicity
Conclusion/Summary : Not available.
Carcinogenicity
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
distillates (petroleum), hydrotreated light A3 - - - - -
silica, amorphous, fumed - 3 - - - -
12 . Ecological information
Environmental effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Do not puncture or incinerate container.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping name Classes PG* Additional
information information
DOT Classification UN1950 Aerosols 2.1 - -
TDG Classification UN1950 Aerosols 2.1 - -
ADR/RID Class UN1950 Aerosols 2 - -
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Sika庐 Cleaner S
14 . Transport information
IMDG Class UN1950 Aerosols 2.1 - Emergency
schedules (EmS)
F-D, S-U
IATA-DGR Class UN1950 Aerosols 2.1 - -
PG* : Packing group
15 . Regulatory information
U.S. Federal regulations : United States inventory (TSCA 8b): Not determined.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: distillates (petroleum), hydrotreated
light; petroleum gases, liquefied
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
distillates (petroleum), hydrotreated light: Delayed (chronic) health hazard; petroleum
gases, liquefied: Fire hazard, Sudden release of pressure
State regulations : Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are
listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: LIQUIFIED
PETROLEUM GAS (L.P.G.);AMORPHOUS SILICA
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed:
LIQUEFIED PETROLEUM GAS;SILICA, AMORPHOUS (FUMED)
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: None of the components are listed.
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:
PETROLEUM GASES, LIQUEFIED;SILICA
Rhode Island Hazardous Substances: None of the components are listed.
United States inventory : United States inventory (TSCA 8b): Not determined.
(TSCA 8b)
16 . Other information
Hazardous Material :
Information System (U.S.A.)
* 1
Health
3
Flammability
0
Physical hazards
C
Personal Protection
Equipment
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Sika庐 Cleaner S
16 . Other information
Caution: HMIS庐 ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS庐 ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS庐 ratings are to be used with a fully implemented
HMIS庐 program. HMIS庐 is a registered mark of the National Paint & Coatings Association (NPCA). HMIS庐
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of printing : 27.05.2008.
: 27.05.2008.
Date of issue
Date of previous issue : 24.04.2008.
Version : 1.03
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Corporation ("Sika")
product identified and described herein. This information is not intended to address, nor does it address the use
or application of the identified Sika product in combination with any other material, product or process. All of the
information set forth herein is based on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the
warnings and instructions on the product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this
MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS
INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY
OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacorp.com or
201-933-8800.
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