MATERIAL SAFETY DATA SHEET
Sika Primer-150
HMIS
HEALTH *2
FLAMMABILITY 3
REACTIVITY 1
H
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Corporation Pecora Corporation
30800 Stephenson Highway 165 Wambold Road
Madison Heights, MI 48071 U.S.A. Harleysville, PA 19438 USA
Company Contact: EHS Department Company Contact: Main Office
Telephone Number: 201-933-8800 Telephone Number: 215-723-6051
FAX Number: 201-933-9379
Web Site: www.sikaindustry.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887 INTERNATIONAL: 703-527-3887
Issue Date: 06/26/2007
Product Name: Sika Primer-150
Chemical Name: Primer
CAS Number: Not Established
Chemical Family: Aliphatic Isocyanate
MSDS Number: 4119
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
ETHYL BENZENE 100-41-4 0 - 20
ISOCYANATE PREPOLYMER Not Establis 20 - 50
METHYLENE BIS(4-CYCLOHEXYLISOCYANATE) 5124-30-1 < 4
XYLENE (MIXED ISOMERS) 1330-20-7 40 - 80
3. Hazards Identification
Primary Routes(s) Of Entry
Dermal and Inhalation
Eye Hazards
Causes eye irritation.
Skin Hazards
Causes skin irritation.
Page 1 of 6
MATERIAL SAFETY DATA SHEET
Sika Primer-150
3. Hazards Identification - Continued
Ingestion Hazards
Harmful if swallowed.
Inhalation Hazards
Causes respiratory tract irritation. Reports have associated repeated and prolonged exposure to some of the
chemicals in this product with permanent brain, liver, kidney, and Central Nervous System damage. Headaches
and dizziness may result. Can also cause nausea and vomiting in high concentrations.
Conditions Aggravated By Exposure
Health studies have shown that many petroleum hydrocarbons pose potential human health risks which may vary
from person to person. Exposure should be minimize. Contains diisocyanates. Preclude from exposure those
individuals having a history of respiratory ailments.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation develops and persists.
Skin
In case of contact, immediately flush skin with soap, skin cream, and plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Seek medical attention
immediately.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration.
5. Fire Fighting Measures
Flash Point: > 79 掳F > 26 掳C
Flash Point Method: (TCC) based upon xylene
Autoignition Point: > 900 掳F > 500 掳C
Lower Explosive Limit: 1.9% (based on xylene)
Upper Explosive Limit: 12.3% (based on xylene)
Fire And Explosion Hazards
Minimize breathing gases, vapor, fumes, and decomposition products. Static electricity may accumulate and
ignite vapors. Follow safe grounding and bonding practice.
Extinguishing Media
In case of fire, use water spray (fog) foam, dry chemical, or CO2.
Fire Fighting Instructions
In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode.
Water may be unsuitable as an extinguishing media but helpful in keeping adjacent containers cool.
6. Accidental Release Measures
Shut off and eliminate all ignition sources. Recover free product, add sand, earth, or other suitable absorbent to spill
area. Minimize breathing vapors. Keep out of sewers and water courses by diking or impounding. Wash contaminated
areas with water to react with isocyanates.
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Sika Primer-150
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Keep containers tightly closed. Use only with adequate ventilation. Keep away
from sources of ignition.
Handling Precautions
Keep away from heat, sparks, flame, and other sources of ignition (i.e., pilot lights, electric motors, and static
electricity). Prevent vapor build-up by providing adequate ventilation during and after use. Residual vapors might
explode on ignition. Do not cut, drill, or weld on or near this container.
Storage Precautions
Keep product containers cool, dry and away from sources of ignition. Keep product containers closed when not in
use. If containers have bulged after shelf life has expired, discard containers and contents without opening.
Work/Hygienic Practices
Wash thoroughly with soap and water after handling.
8. Exposure Controls/Personal Protection
Engineering Controls
Use of a system of local and/or general exhaust is recommended to keep employee below applicable exposure
limits. Refer to the current edition of "Industrial Ventilation: A Manual of Recommended Practice" published by
the American Conference of Governmental Industrial Hygienists for information on the design, installation, use,
and maintenance of exhaust systems.
Eye/Face Protection
Faceshield over safety glasses or goggles.
Skin Protection
Chemical-resistant gloves. Barrier cream for hands. Lab coat or other work clothing to prevent skin exposure
(Long sleeve shirt and long pants). Launder before reuse.
Respiratory Protection
In areas where the Permissible Exposure Limits are exceeded, use a properly fitted NIOSH-approved, organic
vapor, respirator. A respirator protection program that meets 29 CFR 1910.134 requirement must be followed
whenever workplace conditions warrant a respirator's use.
Other/General Protection
Wash thoroughly after handling.
Ingredient(s) - Exposure Limits
ETHYL BENZENE
ACGIH TLV-STEL 125 ppm
ACGIH TLV-TWA 100 ppm
OSHA PEL-TWA 100 ppm
METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)
ACGIH TLV-TWA 0.005 ppm
XYLENE (MIXED ISOMERS)
ACGIH TLV-STEL 150 ppm
ACGIH TLV-TWA 100 ppm
OSHA PEL-TWA 100 ppm
9. Physical And Chemical Properties
Appearance
Clear Colorless Liquid
Page 3 of 6
MATERIAL SAFETY DATA SHEET
Sika Primer-150
9. Physical And Chemical Properties - Continued
Odor
Solvent Odor
Chemical Type: Mixture
Physical State: Liquid
Boiling Point: > 280 掳F > 140 掳C
Specific Gravity: 0.92
Percent Volatiles: ~70
Vapor Pressure: 14 (mm Hg) @ 100F based on xylene
Vapor Density: Heavier than air
pH Factor: N/A
Solubility: Negligible in water
Evaporation Rate: Slower than ether
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will Not Occur
Conditions To Avoid (Stability)
Heat, sparks and open flames
Incompatible Materials
Oxiding materials. Contact with water, strong bases and amines
Hazardous Decomposition Products
Possibly carbon dioxide, carbon monoxide, oxides of nitrogen, hydrogen cyanide and isocyanates.
Conditions To Avoid (Polymerization)
High heat and moisture.
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations. Waste generators must
determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA Information
Waste solutions may meet the RCRA Ignitable characteristic.
14. Transport Information
Proper Shipping Name
Resin Solution, Flammable
Hazard Class
3, PG III
DOT Identification Number
UN1866
Page 4 of 6
MATERIAL SAFETY DATA SHEET
Sika Primer-150
14. Transport Information - Continued
DOT Shipping Label
Flammable
Additional Shipping Paper Description
As packaged, this product may be shipped by ground transportation only. Air shipment is not permitted.
15. Regulatory Information
U.S. Regulatory Information
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
SARA Hazard Classes
Acute Health Hazard
Fire Hazard
SARA Title III - Section 313 Supplier Notification
This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
ETHYL BENZENE (100-41-4) 0 - 20 %
METHYLENE BIS(4-CYCLOHEXYLISOCYANATE) (5124-30-1) <4 %
XYLENE (MIXED ISOMERS) (1330-20-7) 40 - 80 %
This information must be included on all MSDSs that are copied and distributed for this material.
Ingredient(s) - U.S. Regulatory Information
ETHYL BENZENE
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
XYLENE (MIXED ISOMERS)
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
State Regulations
WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or
other reproductive harm.
Ingredient(s) - State Regulations
ETHYL BENZENE
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
California - Proposition 65
Massachusetts - Hazardous Substance
Page 5 of 6
MATERIAL SAFETY DATA SHEET
Sika Primer-150
15. Regulatory Information - Continued
Ingredient(s) - State Regulations - Continued
New York City - Hazardous Substance
METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
XYLENE (MIXED ISOMERS)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
16. Other Information
HMIS Rating
Health: *2
F i re : 3
Reactivity: 1
PP E: H
Revision/Preparer Information
MSDS Preparer: EHS Department
MSDS Preparer Phone Number: 201 933 8800
Disclaimer
The information contained in this Material Safety Data Sheet applies only to the actual Sika Corporation ("Sika")
product identified and described herein. This information is not intended to address, nor does it address the use
or application of the identified Sika product in combination with any other material, product or process. All of the
information set forth herein is based on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the
warnings and instructions on the product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this
MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS
INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY
OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacorp.com or
201-933-8800.
Sika Corporation
Printed Using MSDS Generator鈩? 2000
Page 6 of 6
|