MATERIAL SAFETY DATA SHEET
Sika Primer 209 D
HMIS
HEALTH *2
FLAMMABILITY 3
REACTIVITY 1
H
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Automotive Sika Deutschland GmbH
30,800 Stephenson Highway Kornwestheimer St. 103-107
Madison Heights, MI 48071 Stuttgart D-70439 Germany
Company Contact: EHS Department
Telephone Number: 201-933-8800 Telephone Number: +4971180090
FAX Number: 201-933-9379 FAX Number: +497118009321
Web Site: www.sika-automotive.com Web Site: www.sika.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 1-800-424-9300
INTERNATIONAL: 703-527-3887 INTERNATIONAL: 703-527-3887
Issue Date: 05/08/2007
Product Name: Sika Primer 209 D
CAS Number: Not Established
Chemical Family: Solvent based polyisocyanate
MSDS Number: 4097
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI) 101-68-8 0.1 - 1
ETHYL ACETATE 141-78-6
METHYL ETHYL KETONE 78-93-3 10 - 25
3. Hazards Identification
Eye Hazards
Causes eye irritation.
Skin Hazards
May causes skin irritation. May cause dermatitis (skin redness, dryness, scaling, etc.) from repeated or prolonged
contact. Prolonged and/or repeated skin contact may cause an allergic reaction/sensitization.
Ingestion Hazards
Harmful if swallowed.
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MATERIAL SAFETY DATA SHEET
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3. Hazards Identification - Continued
Inhalation Hazards
May cause respiratory tract irritation. May cause an allergic respiratory reaction / sensitization after prolonged or
repeated contact. May cause effects such as drowsiness, dizziness, decrease in motor functions, narcosis or
other central nervous system effects.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation develops and persists.
Skin
In case of contact, immediately flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical
attention immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
If swallowed, do not induce vomiting unless directed to do so by medical personnel.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration, seek medical attention.
5. Fire Fighting Measures
Flash Point: 24.8 掳F -4 掳C
Lower Explosive Limit: 1.8
Upper Explosive Limit: 11.5
Fire And Explosion Hazards
Flammable liquid and vapor. Protect against electrostatic charge. Possible formation of explosive mixtures
air/vapor. Above flash point, vapor-air mixtures are explosive within flammable limits notes above. Vapors may
flow along surfaces to distant ignition sources and flash back. Sealed containers may rupture when heated.
Extinguishing Media
In case of fire, use water spray (fog) foam, dry chemical, or CO2.
Fire Fighting Instructions
In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Eliminate all ignition sources. Use appropriate Personal Protective Equipment (PPE). Absorb and/or contain spill with
inert materials (e.g. sand, vermiculite) and then place in appropriate container. For large spills, use water spray to
disperse vapors. Prevent runoff from entering waterways or sewers.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store in a cool, dry, well ventilated area. Keep containers tightly closed. Use only
with adequate ventilation.
Handling Precautions
Use only with ventilation sufficient to reduce potential exposures (air borne levels of dust, fumes, vapors, etc.) to
below recommended exposure limits.
Storage Precautions
Keep away from heat, sparks, flame, and other sources of ignition (i.e., pilot lights, electric motors and static
electricity).
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MATERIAL SAFETY DATA SHEET
Sika Primer 209 D
7. Handling And Storage - Continued
Work/Hygienic Practices
Use good personal hygiene.
8. Exposure Controls/Personal Protection
Engineering Controls
Use of a system of local and/or general exhaust is recommended to keep employee below applicable expsoure
limits. Refer to the current edition of "Industrial Ventilation: A Manual of Recommended Practice" published by
the American Conference of Governmental Industrial Hygienists for information on the design, installation, use,
and maintenance of exhaust systems.
Eye/Face Protection
Faceshield over safety glasses or goggles.
Skin Protection
Chemical-resistant gloves. Lab coat or other work clothing to prevent skin exposure (Long sleeve shirt and long
pants). Launder before reuse.
Respiratory Protection
A respirator protection program that meets 29 CFR 1910.134 requirement must be followed whenever workplace
conditions warrant a respirator's use. In areas where the Permissible Expsosure Limits are exceeded, use a
properly fitted NIOSH-approved respirator.
Other/General Protection
Wash thoroughly after handling.
Ingredient(s) - Exposure Limits
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
ACGIH TLV-TWA 0.005 ppm
ACGIH TLV-TWA 0.051 mg/m3
OSHA PEL-CEILING 0.020 ppm
OSHA PEL-CEILING 0.2 mg/m3
ETHYL ACETATE
ACGIH TLV-TWA 400 ppm
OSHA PEL-TWA 400 ppm
METHYL ETHYL KETONE
ACGIH TLV-STEL 300 ppm
ACGIH TLV-TWA 200 ppm
OSHA PEL-TWA 200 ppm
9. Physical And Chemical Properties
Appearance
Black liquid
Odor
Hydrocarbon
Chemical Type: Mixture
Specific Gravity: 0.985 g/cm3
10. Stability And Reactivity
Stability: STABLE
Hazardous Polymerization: WILL NOT OCCUR
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MATERIAL SAFETY DATA SHEET
Sika Primer 209 D
10. Stability And Reactivity - Continued
Conditions To Avoid (Stability)
Formation of explosive gas/air mixtures.
Incompatible Materials
Oxidizing materials
11. Toxicological Information
Ingredient(s) - Carginogenicity
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
Listed In The IARC Monographs
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations. Waste generators must
determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA Information
Waste solutions may meet the RCRA Ignitable characteristic.
14. Transport Information
Proper Shipping Name
Resin Solution, flammable
Hazard Class
3, PG. II
DOT Identification Number
UN1866
DOT Shipping Label
FLAMMABLE
15. Regulatory Information
U.S. Regulatory Information
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
SARA Hazard Classes
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA Title III - Section 313 Supplier Notification
This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8) 0.1 - 1 %
METHYL ETHYL KETONE (78-93-3) 10 - 25 %
This information must be included on all MSDSs that are copied and distributed for this material.
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Sika Primer 209 D
15. Regulatory Information - Continued
Ingredient(s) - U.S. Regulatory Information
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
METHYL ETHYL KETONE
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
Ingredient(s) - State Regulations
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
ETHYL ACETATE
New Jersey - Workplace Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
METHYL ETHYL KETONE
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
16. Other Information
HMIS Rating
Health: *2
F i re : 3
Reactivity: 1
PP E: H
Revision/Preparer Information
MSDS Preparer: EHS Department
MSDS Preparer Phone Number: 201-933-8800
Disclaimer
The information contained in this Material Safety Data Sheet applies only to the actual Sika Corporation ("Sika")
product identified and described herein. This information is not intended to address, nor does it address the use
or application of the identified Sika product in combination with any other material, product or process. All of the
information set forth herein is based on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the
warnings and instructions on the product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this
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MATERIAL SAFETY DATA SHEET
Sika Primer 209 D
Disclaimer - Continued
MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS
INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY
OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacorp.com or
201-933-8800.
Sika Automotive
Printed Using MSDS Generator鈩? 2000
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