09102002 MATERIAL SAFETY DATA SHEET : 00000698 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE EPOXY STEEL (HARDENER)
Kit sub-component: LEPAGE EPOXY STEEL (RESIN)
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2A. D2B. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS EXEMPT
FROM WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS PRODUCTS ACT).
T.D.G. CLASSIFICATION............NOT REGULATED
PRODUCT NAME.....................LEPAGE EPOXY STEEL (HARDENER)
CHEMICAL FAMILY..................POLYAMIDE COMPOSITE
MATERIAL USE.....................CATALYST FOR EPOXY RESIN
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
Mercaptan terminated polymer 30-60 Not available Proprietary Not available Not available
Crystalline silica 30-60 0.1 mg/m3 (dust) 14808-60-7 Not available Not available
2,4,6-Tridimethylaminomethyl 1-5 NOT AVAILABLE 90-72-2 2500mg/kg, RAT, NOT AVAILABLE
phenol ORAL 1200mg/kg,
RBT, DERMAL
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Liquid
APPEARANCE & ODOUR...............Amber liquid. Mild odour
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........Not applicable
VAPOUR DENSITY (AIR=1)...........Not applicable
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not applicable
BOILING POINT (deg C)............Not available
pH...............................Not applicable
SPECIFIC GRAVITY.................1.61
SOLUBILITY IN WATER (% W/W)......Slightly Soluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................None
IF YES, UNDER WHICH..............Not applicable
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes.
FLASH POINT (C), METHOD..........> 93 deg C, Pensky-Martens
LOWER FLAMMABLE LIMIT (% VOL)....Not available
UPPER FLAMMABLE LIMIT (% VOL)....Not available
HAZARDOUS COMBUSTION PRODUCTS....Oxides of carbon (CO,CO2). Ammonia. Aldehydes. Ketones. Oxides of nitrogen
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Under normal conditions
NO, WHICH CONDITIONS ?
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Oxidizing agents. Alkalies. Nitrites. Strong acids
REACTIVITY CONDITIONS ?
HAZARDOUS PRODUCTS OF............Stable under normal temperature and pressure.
DECOMPOSITION
09102002 MATERIAL SAFETY DATA SHEET : 00000698 PAGE:2
PRODUCT : LEPAGE EPOXY STEEL (HARDENER)
SECTION 06: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:
SKIN CONTACT...............May cause allergic skin reaction. May cause irritation, especially on
prolonged contact.
SKIN ABSORPTION............No data
EYE CONTACT................Irritating, and may injure eye tissue if not removed promptly
INHALATION.................High vapour concentrations are irritating to the eyes and the respiratory
tract.
INGESTION..................Considered slightly toxic to practically non-toxic.
EFFECTS OF ACUTE EXPOSURE........Skin, eye, and respiratory tract irritation.
EFFECTS OF CHRONIC EXPOSURE......May aggravate existing skin and eye conditions. This product contains
crystalline silica. Prolonged exposure to respirable crystalline quartz
may cause delayed (chronic) lung injury (silicosis).
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2).
ROUTE
EXPOSURE LIMIT OF MATERIAL.......See hazardous ingredients section (2)
IRRITANCY OF MATERIAL............Refer to route of entry
SENSITIZING CAPABILITY OF........May cause allergic skin reaction, especially on prolonged or repeated
MATERIAL contact.
MUTAGENICITY OF MATERIAL.........Not available
TERATOGENICITY OF MATERIAL.......Not available
CARCINOGENICITY OF MATERIAL......Crystalline silica is an IARC-listed known lung carcinogen. The
crystalline silica contained in this product will not typically become
airborne during normal conditions of use.
REPRODUCTIVE EFFECTS.............Not available
SYNERGISTIC MATERIALS............Not available
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber).
RESPIRATORY/TYPE...........None required under normal use. Use a NIOSH/MSHA approved respirator
whenever mist or spray is generated. Use approved respirator for dusts and
mists when sanding, grinding or machining cured compound.
EYE/TYPE...................Safety glasses with side-shields
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Use adequate general ventilation.
LEAK/SPILL.......................Clean up spills immediately. Spills should be taken up with suitable
absorbent and placed in containers. Spill area can be washed with water;
collect wash water for approved disposal. Do not flush to storm sewer or
waterway. Provide adequate ventilation to spill area.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since
emptied container retains product residues all labelled hazard precautions
must be observed.
HANDLING PROCEDURES AND..........Use adequate ventilation. Wear chemical splash goggles, gloves, and
EQUIPMENT protective clothing. Avoid skin and eye contact. Wash thoroughly after
handling.
STORAGE NEEDS....................Store in a cool, dry place away from direct heat.
SPECIAL SHIPPING INSTRUCTIONS....Not regulated. Protect against physical damage.
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids
apart to ensure flushing of entire surface. Washing within 1 minute is
essential to achieve maximum effectiveness. If irritation persists, get
medical attention.
INGESTION........................Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to an
unconscious person.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek
medical attention if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 13/2002
09102002 MATERIAL SAFETY DATA SHEET : 00000698 PAGE:3
PRODUCT : LEPAGE EPOXY STEEL (HARDENER)
SECTION 09: PREPARATION INFORMATION
CANUTEC EMERGENCY (613) 996-6666
09102002 MATERIAL SAFETY DATA SHEET : 00000697 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE EPOXY STEEL (RESIN)
Kit sub-component: LEPAGE EPOXY STEEL (HARDENER)
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4 ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2A. D2B. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS EXEMPT
FROM WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS PRODUCTS ACT).
T.D.G. CLASSIFICATION............NOT REGULATED
PRODUCT NAME.....................LEPAGE EPOXY STEEL (RESIN)
CHEMICAL FAMILY..................FORMULATED EPOXY RESIN
MATERIAL USE.....................EPOXY FILLER
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
Crystalline silica 15-40 0.1 mg/m3 (dust) 14808-60-7 Not available Not available
Bisphenol A, polymer with 10-30 Not available 25068-38-6 Not available Not available
chloromethyloxirane
Bisphenol A - epichlorohydrin 10-30 Not available 25085-99-8 >5g/kg,oral,rat Not available
resin 20g/kg,skin,rabbit
Phenol, polymer with 3-7 Not available 28064-14-4 Not available Not available
formaldehyde, glycidyl ether
Carbon black 0.5-1.5 3.5mg/m3 1333-86-4 Not available 27g/m3/1hr.
inhl.,rat
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Liquid
APPEARANCE & ODOUR...............Black liquid. Mild odour
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........Not applicable
VAPOUR DENSITY (AIR=1)...........Not applicable
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not applicable
BOILING POINT (deg C)............Not applicable
pH...............................Not applicable
SPECIFIC GRAVITY.................1.585
SOLUBILITY IN WATER (% W/W)......Insoluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................Non combustible
IF YES, UNDER WHICH
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes.
FLASH POINT (C), METHOD..........> 93 deg C, Pensky-Martens
LOWER FLAMMABLE LIMIT (% VOL)....Not available
UPPER FLAMMABLE LIMIT (% VOL)....Not available
HAZARDOUS COMBUSTION PRODUCTS....Aldehydes. Acrid fumes. Oxides of carbon (CO,CO2). Oxides of silicon.
Chlorine
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Under normal conditions
NO, WHICH CONDITIONS ?
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Oxidizing agents. Strong acids. Strong bases. Curing agents. Amines
REACTIVITY CONDITIONS ?..........Water reactive
09102002 MATERIAL SAFETY DATA SHEET : 00000697 PAGE:2
PRODUCT : LEPAGE EPOXY STEEL (RESIN)
SECTION 05: REACTIVITY DATA
HAZARDOUS PRODUCTS OF............Oxides of carbon (CO,CO2) at high temperatures.
DECOMPOSITION
SECTION 06: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:
SKIN CONTACT...............May be a sensitizer. May cause irritation, especially on prolonged contact.
SKIN ABSORPTION............No data
EYE CONTACT................Contains materials that are moderately irritating to the eyes. Irritating,
but does not injure eye tissue.
INHALATION.................Exposure to mist or spray may cause irritation of respiratory passages.
INGESTION..................No hazard in normal industrial use.
EFFECTS OF ACUTE EXPOSURE........May cause allergic reaction. Possible skin and eye irritation.
EFFECTS OF CHRONIC EXPOSURE......Prolonged or repeated contact may cause irritation. May aggravate existing
eye, skin, and lung conditions. This product contains crystalline silica.
Prolonged exposure to respirable crystalline quartz may cause delayed
(chronic) lung injury (silicosis).
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2).
ROUTE
EXPOSURE LIMIT OF MATERIAL.......See hazardous ingredients section (2)
IRRITANCY OF MATERIAL............Components of this formulation known to cause irritation.
SENSITIZING CAPABILITY OF........May cause allergic skin reaction, especially on prolonged or repeated
MATERIAL contact.
CARCINOGENICITY OF MATERIAL......Carbon black is an IARC-listed probable lung carcinogen. The carbon black
contained in this product will not typically become airborne during normal
conditions of use. Crystalline silica is an IARC-listed known lung
carcinogen. The crystalline silica contained in this product will not
typically become airborne during normal conditions of use.
MUTAGENICITY OF MATERIAL.........A component of this product exhibited evidence of mutagenicity in
laboratory tests.
REPRODUCTIVE EFFECTS.............Not available
TERATOGENICITY OF MATERIAL.......Not available
SYNERGISTIC MATERIALS............Not available
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber).
RESPIRATORY/TYPE...........None required under normal use. Use a NIOSH/MSHA approved respirator
whenever mist or spray is generated. Use approved respirator for dusts and
mists when sanding, grinding or machining cured compound.
EYE/TYPE...................Safety glasses with side-shields
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Use adequate local exhaust ventilation.
LEAK/SPILL.......................Clean up spills immediately. Put in appropriate labelled container for
disposal.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since
emptied container retains product residues all labelled hazard precautions
must be observed.
HANDLING PROCEDURES AND..........Use adequate ventilation. Wear chemical splash goggles, gloves, and
EQUIPMENT protective clothing. Avoid skin and eye contact. Wash thoroughly after
handling.
STORAGE NEEDS....................Keep container closed when not in use. Store in a cool, dry place away
from direct heat.
SPECIAL SHIPPING INSTRUCTIONS....Not regulated. Protect against physical damage.
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids
apart to ensure flushing of entire surface. Washing within 1 minute is
essential to achieve maximum effectiveness. If irritation persists, get
medical attention.
INGESTION........................If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical
attention.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek
medical attention if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
09102002 MATERIAL SAFETY DATA SHEET : 00000697 PAGE:3
PRODUCT : LEPAGE EPOXY STEEL (RESIN)
SECTION 09: PREPARATION INFORMATION
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 13/2002
CANUTEC EMERGENCY (613) 996-6666
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