06142002 MATERIAL SAFETY DATA SHEET : 00000630 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE LEP40 HIGH HEAT SILICONE SEALANT
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2A. D2B. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS EXEMPT
FROM WHMIS REGULATIONS (SEE SECTION 12(f) OF THE HAZARDOUS PRODUCT ACT)
T.D.G. CLASSIFICATION............NOT REGULATED
PRODUCT NAME.....................LEPAGE LEP40 HIGH HEAT SILICONE SEALANT
CHEMICAL FAMILY..................SILOXANE
MATERIAL USE.....................SEALANT
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
Silica 10-30 10 mg/m3 (ACGIH) 7631-86-9 >3.1g/kg,oral,rat Not available
Ethyl triacetoxysilane 1-5 Not available 17689-77-9 Not available Not available
Methyl triacetoxysilane 1-5 Not available 4253-34-3 >2.0g/kg,oral,rat Not available
Octamethylcyclotetrasiloxane 0.1-1 Not available 556-67-2 1.54g/Kg, rat, oral
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Paste
APPEARANCE & ODOUR...............Smooth paste with acetic acid odor. Red
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........Not applicable
VAPOUR DENSITY (AIR=1)...........Not applicable
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not available
BOILING POINT (deg C)............Not applicable
pH...............................Not available
SPECIFIC GRAVITY.................1.04
SOLUBILITY IN WATER (% W/W)......Insoluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................No
IF YES, UNDER WHICH
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes.
FLASH POINT (C), METHOD..........Not applicable
LOWER FLAMMABLE LIMIT (% VOL)....Not applicable
UPPER FLAMMABLE LIMIT (% VOL)....Not applicable
HAZARDOUS COMBUSTION PRODUCTS....Silicon dioxide, carbon dioxide and unknown carbon products. Formaldehyde
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Stable, hazardous polymerization will not occur
NO, WHICH CONDITIONS ?
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Strong oxidizing agents. Air and moisture cause polymerization and acetic
acid vapours are formed
REACTIVITY CONDITIONS ?..........On contact with air and water
HAZARDOUS PRODUCTS OF............Silicon dioxide. Oxides of carbon (CO,CO2) at high temperatures.
DECOMPOSITION
SECTION 06: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:
SKIN CONTACT...............May cause irritation, especially on prolonged contact.
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PRODUCT : LEPAGE LEP40 HIGH HEAT SILICONE SEALANT
SECTION 06: TOXICOLOGICAL PROPERTIES
SKIN ABSORPTION............No data
EYE CONTACT................Irritating, and may injure eye tissue if not removed promptly
INHALATION.................Air and moisture cause polymerization and acetic acid vapours are formed.
Avoid breathing vapours. High concentrations are irritating. High
concentrations may cause headaches and nausea. Vapours may be irritating
to respiratory system and nasal passages
INGESTION..................Considered slightly toxic. No hazard in normal industrial use.
EFFECTS OF ACUTE EXPOSURE........Refer to route of entry.
EFFECTS OF CHRONIC EXPOSURE......May aggravate existing eye, skin, and lung conditions.
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2).
ROUTE
EXPOSURE LIMIT OF MATERIAL.......See hazardous ingredients section (2). Acetic acid: 15 ppm TLV STEL
(ACGIH), (local authorities should be consulted for acceptable provincial
values).
IRRITANCY OF MATERIAL............Refer to route of entry
SENSITIZING CAPABILITY OF........None known
MATERIAL
CARCINOGENICITY OF MATERIAL......No
REPRODUCTIVE EFFECTS.............A component of this product exhibited evidence of reproductive effects in
laboratory tests
MUTAGENICITY OF MATERIAL.........None known
TERATOGENICITY OF MATERIAL.......None known
SYNERGISTIC MATERIALS............None known
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber).
RESPIRATORY/TYPE...........Use NIOSH approved respirator for organic vapours. Avoid prolonged or
repeated breathing of vapour or mists. If exposure may or does exceed
occupational exposure limits, use a NIOSH approved respirator to prevent
overexposure.
EYE/TYPE...................Wear an eye protection apparatus. Safety glasses with side-shields.
Chemical goggles
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Ventilate adequately. Consult local authorities for acceptable exposure
limits. Good industrial practice dictates that indoor work areas be
isolated and provided with adequate local exhaust ventilation. Wear an
appropriate, properly fitted respirator when contaminant levels exceed the
recommended exposure limits.
LEAK/SPILL.......................Evacuate all non-essential personnel. Ventilate area. Wear appropriate
protective equipment during cleanup. Scrape or shovel into containers. Put
in appropriate labelled container for disposal.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations.
HANDLING PROCEDURES AND..........Avoid breathing vapours. Avoid all skin contact and ventilate adequately,
EQUIPMENT otherwise wear an appropriate breathing apparatus. Acetic acid vapours are
formed during curing process of this product. Ensure adequate ventilation
at workplace. Wear chemical splash goggles, gloves, and protective
clothing. Wash thoroughly after handling.
STORAGE NEEDS....................KEEP AWAY FROM CHILDREN. Keep container closed and store away from water
or moisture. Store in a dry place. Store under 30 deg C. Store product at
between 5 and 25 degree celcius sheltered from air moisture. Store in
tightly sealed container and protect from moisture and foreign materials.
SPECIAL SHIPPING INSTRUCTIONS....Not regulated
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids
apart to ensure flushing of entire surface. Washing within 1 minute is
essential to achieve maximum effectiveness. Cured adhesive will not bond
well to surface of eye, but corneal damage from abrasion may result. Do
not wear contact lenses when working with this material. Seek medical
attention immediately.
INGESTION........................Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to an
unconscious person. Get immediate medical attention. If swallowed, DO NOT
induce vomiting. Keep at rest. Get prompt medical attention.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Do not remove material from skin. Obtain medical assistance for removal.
No attempt should be made to remove material from skin or to remove
contaminated clothing, as the bonded skin can be easily torn. Wash with
large volumes of soap and water while flexing bonded skin parts. This
procedure will slowly release bonded areas. DO NOT mechanically remove
cured adhesive or attempt to pull skin apart. Remove contaminated
clothing. Wash affected area with water and soap. Seek medical attention
if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
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PRODUCT : LEPAGE LEP40 HIGH HEAT SILICONE SEALANT
SECTION 09: PREPARATION INFORMATION
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 13/2002
CANUTEC EMERGENCY (613) 996-6666
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