09102002 MATERIAL SAFETY DATA SHEET : 00000694 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE REGULAR EPOXY GLUE (HARDENER)
Kit sub-component: LEPAGE REGULAR EPOXY GLUE (RESIN)
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2A. D2B. E. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS
EXEMPT FROM WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS
PRODUCTS ACT).
T.D.G. CLASSIFICATION............CORROSIVE LIQUIDS, N.O.S. (DIETHYLENETRIAMINE). CLASS 8 (9.2), UN1760, PKG
GP III, SPECIAL PROVISION 109. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER
COMMODITY IT IS EXEMPT FROM T.D.G. REGULATIONS (SEE SECTION 2.7(1) OF
TRANSPORTATION OF DANGEROUS GOODS REGULATIONS).
PRODUCT NAME.....................LEPAGE REGULAR EPOXY GLUE (HARDENER)
CHEMICAL FAMILY..................POLYAMIDE COMPOSITE
MATERIAL USE.....................CATALYST FOR EPOXY RESIN
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
C18-unsaturated fatty acid 40-70 Not available 68410-23-1 Not available Not available
dimers, reaction products
with polyethylene polyamines
Diethylene triamine 10-30 TLV-TWA: 4.2 mg/m3 111-40-0 1.08g/kg,oral,rat Not available
PEL-TWA: 4 mg/m3 1.046g/kg,dermal
rabbit
Bisphenol A Resin 10-30 Not available 80-05-7 4040mg/kg, RAT, ORAL > 150mg/m3 RAT,INHAL
3000mg/kg,RBT,DERMAL
Bisphenol A, polymer with 5-10 Not available 25068-38-6 Not available Not available
chloromethyloxirane
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Liquid
APPEARANCE & ODOUR...............Yellowish liquid. Viscous. Mild odour
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........< 5 at 25 deg C
VAPOUR DENSITY (AIR=1)...........Not available
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not available
BOILING POINT (deg C)............> 150 deg C
pH...............................Not available
SPECIFIC GRAVITY.................0.98
SOLUBILITY IN WATER (% W/W)......Insoluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................Non combustible
IF YES, UNDER WHICH
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes. Use water-spray
to keep containers cool
FLASH POINT (C), METHOD..........> 93 deg C, TCC
LOWER FLAMMABLE LIMIT (% VOL)....Not available
UPPER FLAMMABLE LIMIT (% VOL)....Not available
HAZARDOUS COMBUSTION PRODUCTS....Amines. Oxides of nitrogen. Oxides of carbon (CO,CO2)
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Under normal conditions
NO, WHICH CONDITIONS ?
09102002 MATERIAL SAFETY DATA SHEET : 00000694 PAGE:2
PRODUCT : LEPAGE REGULAR EPOXY GLUE (HARDENER)
SECTION 05: REACTIVITY DATA
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Epoxy resin. Strong oxidizing agents. Strong acids. Chlorinated
hydrocarbons
REACTIVITY CONDITIONS ?..........Water reactive
HAZARDOUS PRODUCTS OF............None
DECOMPOSITION
SECTION 06: TOXICOLOGICAL PROPERTIES
SKIN CONTACT...............Can cause severe irritation. May be a sensitizer.
SKIN ABSORPTION............No data
EYE CONTACT................If not removed promptly, will injure eye tissue, which may result in
permanent damage. Severe irritation causing irreversible corneal injury.
INHALATION.................Inhalation of mist or vapour may cause irritation of the respiratory
tract. May cause sensitization reaction.
INGESTION..................Irritation to throat, esophagus and stomach. May cause irritation of the
gastrointestinal tract.
EFFECTS OF ACUTE EXPOSURE........Skin allergies and irritation, eye damage. Possible gastrointestinal tract
irritation.
EFFECTS OF CHRONIC EXPOSURE......May aggravate existing eye, skin, and lung conditions.
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2).
ROUTE
EXPOSURE LIMIT OF MATERIAL.......Not available
IRRITANCY OF MATERIAL............Components of this formulation known to cause irritation. Irritating to
eyes and skin. Moderate to severe.
SENSITIZING CAPABILITY OF........May cause allergic skin reaction, especially on prolonged or repeated
MATERIAL contact. Possible respiratory sensitizer.
CARCINOGENICITY OF MATERIAL......Refer to route of entry.
REPRODUCTIVE EFFECTS.............A component of this product exhibited evidence of reproductive effects in
laboratory tests. Bisphenol A causes reduced fertility in male mice.
SYNERGISTIC MATERIALS............Not available
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber).
RESPIRATORY/TYPE...........None required under normal use. Use a NIOSH/MSHA approved respirator
whenever mist or spray is generated.
EYE/TYPE...................Safety glasses with side-shields
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Use adequate local exhaust ventilation.
LEAK/SPILL.......................Clean up spills immediately. Absorb residual material with sand, or other
absorbent material. Flush area with plenty of water. Collect waste in
sealed containers.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since
emptied container retains product residues all labelled hazard precautions
must be observed.
HANDLING PROCEDURES AND..........Use adequate ventilation. Wear chemical splash goggles, gloves, and
EQUIPMENT protective clothing. Avoid skin and eye contact. Wash thoroughly after
handling.
STORAGE NEEDS....................Store in a cool, dry place away from direct heat.
SPECIAL SHIPPING INSTRUCTIONS....Ship in accordance with applicable Transportation of Dangerous Goods (TDG)
regulations.
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush eyes with large amounts of water until irritation
subsides. If irritation persists, get medical attention.
INGESTION........................Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to an
unconscious person.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek
medical attention if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
09102002 MATERIAL SAFETY DATA SHEET : 00000694 PAGE:3
PRODUCT : LEPAGE REGULAR EPOXY GLUE (HARDENER)
SECTION 09: PREPARATION INFORMATION
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 13/2002
CANUTEC EMERGENCY (613) 996-6666
09102002 MATERIAL SAFETY DATA SHEET : 00000693 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE REGULAR EPOXY GLUE (RESIN)
Kit sub-component: LEPAGE REGULAR EPOXY GLUE (HARDENER)
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4 ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2B. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS EXEMPT FROM
WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS PRODUCTS ACT).
T.D.G. CLASSIFICATION............NOT REGULATED
PRODUCT NAME.....................LEPAGE REGULAR EPOXY GLUE (RESIN)
CHEMICAL FAMILY..................FORMULATED EPOXY RESIN
MATERIAL USE.....................ADHESIVE FOR GLASS, METAL AND CONCRETE
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
Bisphenol A, polymer with 60-100 Not available 25068-38-6 Not available Not available
chloromethyloxirane
Nonylphenol 10-30 Not available 25154-52-3 1.62g/kg,oral,rat Not available
2.14g/kg,dermal,
rabbit
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Liquid
APPEARANCE & ODOUR...............Yellowish. Viscous liquid. Mild odour
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........< 5 at 25 deg C
VAPOUR DENSITY (AIR=1)...........Not available
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not available
BOILING POINT (deg C)............> 150 deg C
pH...............................Not available
SPECIFIC GRAVITY.................1.16
SOLUBILITY IN WATER (% W/W)......Insoluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................Non combustible
IF YES, UNDER WHICH
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes.
FLASH POINT (C), METHOD..........> 93 deg C, TCC
LOWER FLAMMABLE LIMIT (% VOL)....Not available
UPPER FLAMMABLE LIMIT (% VOL)....Not available
HAZARDOUS COMBUSTION PRODUCTS....Amines. Combustion will result in the usual decomposition products,
including oxides of carbon.
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Under normal conditions
NO, WHICH CONDITIONS ?
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Strong oxidizing agents. Chlorinated hydrocarbons. Strong acids
REACTIVITY CONDITIONS ?..........Water reactive
HAZARDOUS PRODUCTS OF............None
DECOMPOSITION
09102002 MATERIAL SAFETY DATA SHEET : 00000693 PAGE:2
PRODUCT : LEPAGE REGULAR EPOXY GLUE (RESIN)
SECTION 06: TOXICOLOGICAL PROPERTIES
SKIN CONTACT...............May be a sensitizer. Can cause severe irritation.
SKIN ABSORPTION............No data
EYE CONTACT................Can cause severe irritation. Causes corneal damage.
INHALATION.................Not expected to be inhaled under ordinary use.
INGESTION..................May cause irritation of the gastrointestinal tract.
EFFECTS OF ACUTE EXPOSURE........Skin allergies and irritation, eye damage. Possible gastrointestinal tract
irritation.
EFFECTS OF CHRONIC EXPOSURE......May aggravate existing eye, skin, and lung conditions.
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....Not available
ROUTE
EXPOSURE LIMIT OF MATERIAL.......Not available
IRRITANCY OF MATERIAL............Components of this formulation known to cause irritation. Irritating to
eyes and skin.
SENSITIZING CAPABILITY OF........May cause allergic skin reaction, especially on prolonged or repeated
MATERIAL contact.
CARCINOGENICITY OF MATERIAL......No
MUTAGENICITY OF MATERIAL.........Not available
REPRODUCTIVE EFFECTS.............Not available
TERATOGENICITY OF MATERIAL.......Not available
SYNERGISTIC MATERIALS............Not available
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber).
RESPIRATORY/TYPE...........None required under normal use. Use a NIOSH/MSHA approved respirator
whenever mist or spray is generated.
EYE/TYPE...................Safety glasses with side-shields
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Use adequate local exhaust ventilation.
LEAK/SPILL.......................Clean up spills immediately. Absorb residual material with sand, or other
absorbent material. Collect waste in sealed containers.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since
emptied container retains product residues all labelled hazard precautions
must be observed.
HANDLING PROCEDURES AND..........Use adequate ventilation. Wear chemical splash goggles, gloves, and
EQUIPMENT protective clothing. Avoid skin and eye contact. Wash thoroughly after
handling.
STORAGE NEEDS....................Store in a cool, dry place away from direct heat.
SPECIAL SHIPPING INSTRUCTIONS....Not regulated. Protect against physical damage.
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush eyes with large amounts of water until irritation
subsides. If irritation persists, get medical attention.
INGESTION........................Do not induce vomiting. If vomiting should occur spontaneously, keep
airway clear. Get medical attention. Never give anything by mouth to an
unconscious person.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek
medical attention if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 13/2002
CANUTEC EMERGENCY (613) 996-6666
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