06182002 MATERIAL SAFETY DATA SHEET : 00000171 PAGE:1
HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO CANADA L6T 2J4
(905) 459-1140
PRODUCT : LEPAGE SILICONE ADHESIVE SEALANT - BATH & KITCHEN
SECTION 01: PRODUCT INFORMATION
MANUFACTURER.....................HENKEL CONSUMER ADHESIVES
50 WEST DRIVE
BRAMPTON, ONTARIO
CANADA ; L6T 2J4
(905) 459-1140
AFTER HOURS - CANUTEC (613) 996-6666
WHMIS CLASSIFICATION.............D2B. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT IT IS EXEMPT FROM
WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS PRODUCTS ACT).
T.D.G. CLASSIFICATION............NOT REGULATED
PRODUCT NAME.....................LEPAGE SILICONE ADHESIVE SEALANT - BATH & KITCHEN
CHEMICAL FAMILY..................SILOXANE
MATERIAL USE.....................SEALANT
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
Silica 7-13 10 mg/m3 (ACGIH) 7631-86-9 >3.1g/kg,oral,rat Not available
Ethyl triacetoxysilane 1-5 Not available 17689-77-9 Not available Not available
Methyl triacetoxysilane 1-5 Not available 4253-34-3 >2.0g/kg,oral,rat Not available
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................Solid
APPEARANCE & ODOUR...............Paste
ODOUR THRESHOLD (ppm)............Not available
VAPOUR PRESSURE (mm Hg)..........< 5 at 25 deg C
VAPOUR DENSITY (AIR=1)...........> 1
BY VOLUME
BY WEIGHT
EVAPORATION RATE.................Not applicable
BOILING POINT (deg C)............Not available
pH...............................Not available
SPECIFIC GRAVITY.................1.05
SOLUBILITY IN WATER (% W/W)......Insoluble
COEFFICIENT OF WATER/OIL.........Not available
DISTRIBUTION
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................No
IF YES, UNDER WHICH
CONDITIONS?
AUTO IGNITION TEMPERATURE........Not available
EXTINGUISHING MEDIA..............Water fog; Foam; CO2; Dry chemical
SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus
to protect against potentially toxic and irritating fumes.
FLASH POINT (C), METHOD..........>100 deg C, Cleveland open cup
LOWER FLAMMABLE LIMIT (% VOL)....Not applicable
UPPER FLAMMABLE LIMIT (% VOL)....Not applicable
HAZARDOUS COMBUSTION PRODUCTS....Silicon dioxide, carbon dioxide and unknown carbon products.
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY:
YES........................Stable under normal temperature and pressure.
NO, WHICH CONDITIONS ?
COMPATIBILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES?............Strong oxidizing agents. Air and moisture cause polymerization and acetic
acid vapours are formed
REACTIVITY CONDITIONS ?..........On contact with air and water
HAZARDOUS PRODUCTS OF............Silicon dioxide. Oxides of carbon (CO,CO2) at high temperatures.
DECOMPOSITION
SECTION 06: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:
SKIN CONTACT...............May cause irritation, especially on prolonged contact.
SKIN ABSORPTION............No data
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PRODUCT : LEPAGE SILICONE ADHESIVE SEALANT - BATH & KITCHEN
SECTION 06: TOXICOLOGICAL PROPERTIES
EYE CONTACT................Irritating, and may injure eye tissue if not removed promptly
INHALATION.................Air and moisture cause polymerization and acetic acid vapours are formed.
Avoid breathing vapours. High concentrations are irritating. High
concentrations may cause headaches and nausea. Vapours may be irritating
to respiratory system and nasal passages
INGESTION..................Considered slightly toxic. No hazard in normal industrial use.
EFFECTS OF ACUTE EXPOSURE........Refer to route of entry.
EFFECTS OF CHRONIC EXPOSURE......May aggravate existing eye, skin, and lung conditions.
LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2)
ROUTE
LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2).
ROUTE
EXPOSURE LIMIT OF MATERIAL.......See hazardous ingredients section (2). Acetic acid: 15 ppm TLV STEL
(ACGIH), (local authorities should be consulted for acceptable provincial
values).
IRRITANCY OF MATERIAL............Refer to route of entry
SENSITIZING CAPABILITY OF........Refer to route of entry
MATERIAL
CARCINOGENICITY OF MATERIAL......No
MUTAGENICITY OF MATERIAL.........Not available
TERATOGENICITY OF MATERIAL.......Not available
SYNERGISTIC MATERIALS............Not available
SECTION 07: PREVENTATIVE MEASURES
GLOVES/ TYPE...............Gloves are not normally required for foreseeable conditions of use.
RESPIRATORY/TYPE...........Use NIOSH approved respirator for organic vapours. Avoid prolonged or
repeated breathing of vapour or mists. If exposure may or does exceed
occupational exposure limits, use a NIOSH approved respirator to prevent
overexposure.
EYE/TYPE...................Wear an eye protection apparatus. Safety glasses, goggles or face shield
to protect against splashing.
FOOTWEAR/TYPE..............Standard work shoes.
CLOTHING/TYPE..............Standard work clothes.
VENTILATION REQUIREMENTS.........Ventilate adequately. Consult local authorities for acceptable exposure
limits. Good industrial practice dictates that indoor work areas be
isolated and provided with adequate local exhaust ventilation. Wear an
appropriate, properly fitted respirator when contaminant levels exceed the
recommended exposure limits.
LEAK/SPILL.......................Spills should be taken up with suitable absorbent and placed in
containers. Spill area can be washed with water; collect wash water for
approved disposal. Do not flush to storm sewer or waterway.
WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations.
HANDLING PROCEDURES AND..........Avoid breathing vapours. Avoid all skin contact and ventilate adequately,
EQUIPMENT otherwise wear an appropriate breathing apparatus. Acetic acid vapours are
formed during curing process of this product. Ensure adequate ventilation
at workplace. Wear chemical splash goggles, gloves, and protective
clothing. Wash thoroughly after handling.
STORAGE NEEDS....................Store in a cool and dry place, for product integrity.
SPECIAL SHIPPING INSTRUCTIONS....Not regulated
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids
apart to ensure flushing of entire surface. Washing within 1 minute is
essential to achieve maximum effectiveness. Seek medical attention
immediately.
INGESTION........................If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical
attention.
INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention.
SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek
medical attention if irritation occurs or persists.
SECTION 09: PREPARATION INFORMATION
PREPARED BY:.....................Regulatory Affairs
TELEPHONE NUMBER:................(905) 459-1140
DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein
concerning our product are based upon tests and data believed to be
reliable. However, it is the user's responsibility to determine the
safety, toxicity, and suitability for his own use of the product described
herein. Since the actual use by others is beyond our control, no
guarantee, express or implied, is made by Henkel Consumer Adhesives as to
the effects of such use, the results obtained, or the safety and toxicity
of the product nor does Henkel Consumer Adhesives assume any liability
arising out of use, by others, of the product referred to herein. The
information herein is not to be construed as absolutely complete since
additional information may be necessary or desirable when particular or
exceptional conditions or circumstan ces exist or because of applicable
laws or government regulations.
PREPARATION DATE.................JUN 17/2002
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PRODUCT : LEPAGE SILICONE ADHESIVE SEALANT - BATH & KITCHEN
SECTION 09: PREPARATION INFORMATION
CANUTEC EMERGENCY (613) 996-6666
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