1 - IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation:
Name: ACRYLTOP PU 77 BASE.
Product code: H 1693 B.
Company/undertaking identification:
Registered company name: MAP YACHTING.
Address : ZI ATHELIA IV 鈥? 296 Av de la Tramontane 鈥? 13705 LA CIOTAT - France.
Telephone : 33 (0)4 42 98 14 50 Fax :33 (0)4 42 98 14 51. Email : sales@map-yachting.com
Emergency telephone: 01 45 42 59 59.
Association/Organisation: ORFILA.
Use of the substance/preparation:
2 - COMPOSITION/INFORMATION ON INGREDIENTS
Full text of risk phrases appearing in section 2: see section 16.
Hazardous substances present on their own:
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% pure state)
INDEX CAS EC Name Symb. R: %
601-022-00-9 1330-20-7 215-535-7 O-XYLENE Xn 10 38 20/21 10 <= x % < 25
Other substances representing a hazard:
INDEX CAS EC Name Symb. R: %
601-023-00-4 100-41-4 202-849-4 ETHYLBENZENE Xn F 11 20 0 <= x % < 2.5
607-281-00-4 127519-17-9 407-000-3 A MIXTURE OF BRANCHED AND LINEAR C7-C9 ALKYL 3-[3-(2H-BENZOTRIAZOL-2-
YL)-5-(1,1-DIMETHYLETHYL)-4-HYDROXYPHENYL]PROPIONATES N 51/53 0 <= x % < 2.5
M 00357 64742-95-6 265-199-0 SOLVESSO 100 Xi N 10 37 51/53 66 67 2.5 <= x % < 10
Substances present at a concentration below the minimum danger threshold:
INDEX CAS EC Name Symb. R: %
607-025-00-1 123-86-4 204-658-1 N-BUTYL ACETATE 10 66 67 2.5 <= x % < 10
607-195-00-7 108-65-6 203-603-9 2-METHOXY-1-METHYLETHYL ACETATE Xi 10 36 0 <= x % < 2.5
Other substances with occupational exposure limits:
No known substance in this category present.
Other components:
INDEX CAS EC Name Symb. R: %
649-345-00-4 8052-41-3 232-489-3 STODDARD SOLVENT Xn 65 0 <= x % < 2.5
3 - IDENTIFICATION OF HAZARDS
This product is classed: Flammable.
Possibility of irritation to the skin.
Possibility of noxious effects with symptoms of slight poisoning by inhalation and contact with the skin.
Harmful to aquatic organisms, may cause long-termadverse effects in the aquatic environment.
Other data:
4 - FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing in an unconscious person.
In the event of exposure by inhalation:
If a large quantity is inhaled, move the patient into the fresh air and keep him/her warm and still.
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If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
Do not give the patient anything orally.
In the event of splashes or contact with eyes:
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
In the event of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
DO NOT use solvents or thinners.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital
In the event of swallowing:
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.
Keep still. DO NOT induce vomiting.
Call a doctor immediately and show him the label.
Specific and immediate treatment:
Information for the doctor:
5 - FIRE-FIGHTING MEASURES
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
Suitable extinguishing media:
Carbon dioxide, chemical powders, foams, and other extinguishing gases.
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Extinguishing media which must not be used for safety reasons:
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool containers exposed to the fire and to
disperse fumes.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
Special protective equipment for fire-fighters:
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
On account of the organic solvents contained in the preparation, eliminate sources of ignition and ventilate the premises.
Avoid inhaling the vapors.
Avoid any contact with the skin and eyes.
Consult the safety measures listed under headings 7 and 8.
Environmental precautions:
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for
waste disposal.
Prevent any material from entering drains or waterways.
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures
Methods for cleaning up:
Clean preferably with a detergent, do not use solvents.
7 - HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
Handling:
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Handle in well-ventilated areas.
The vapors are denser than air. They can spread along the ground and form explosive mixtures with air
Prevent the formation of flammable or explosive concentrations in air and avoid vapor concentrations higher than the occupational exposure limits.
Fire prevention:
Prevent the accumulation of electrostatic charges with connections to earth
The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic shoes and clothes and make
floors of conductive materials.
Use the product in premises where there are no naked flames or other sources of ignition and have protected electrical equipment
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
Do not use tools which may produce sparks. Do not smoke.
Prevent access by unauthorised personnel.
Recommended equipment and procedures:
For personal safety, see 搂8.
Observe precautions stated on label and also industrial safety regulations
Avoid inhaling solvent vapors and spray-gun aerosols
Packages which have been opened must be reclosed carefully and stored in an upright position
Avoid inhaling vapors.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation may be inadequate to control particles and
solvent vapors in every case.
It is therefore recommended that personnel wear masks with a compressed air supply during spraying operations until the concentration of
particles and solvent vapors has fallen below the exposure limits.
Avoid contact of product with the skin and eyes
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the preparation is used
Never open the packages under pressure
Storage:
Keep the container tightly closed in a dry, well-ventilated place
Keep away from all sources of ignition - do not smoke.
Keep well away from all sources of ignition, heat and direct sunlight
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, the liquid cannot spread beyond this
area.
Specific use(s):
8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Use personal protection equipment as per Directive 89/686/EEC.
Technical measures:
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction.
If this ventilation is insufficient to maintain the concentration of solvent vapors below the exposure limits, wear breathing apparatus
Exposure limit values per INRS ND 2098-174-99 and ND 2114-176-99:
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳:
8052-41-3 - - - - - -
108-65-6 50 275 100 550 * --
123-86-4 150 710 200 940 - 84
100-41-4 100 442 200 884 * 84 -
1330-20-7 50 221 100 442 * 4 bis, 84 -
Exposure limit values per 2000/39/EC and 98/24/EC:
EC VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes:
108-65-6 50 275 100 550 Peau
100-41-4 100 442 200 884 Peau
1330-20-7 50 221 100 442 Peau
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Exposure limit values (2003):
UK/OES TWA: STEL: Ceiling: Definition: Criterion:
108-65-6 50 ppm 100 ppm - - -
123-86-4 150 ppm 200 ppm - - -
100-41-4 100 ppm 125 ppm - - -
1330-20-7 50 ppm 100 ppm - - -
ACGIH/TLV TWA: STEL: Ceiling: Definition: Criterion:
8052-41-3 100 ppm - - - -
123-86-4 150 ppm 200 ppm - - -
100-41-4 100 ppm 125 ppm - - -
1330-20-7 100 ppm - - - -
Germany/MAK TWA: STEL: Ceiling: Definition: Criterion:
108-65-6 50 ppm 50 ppm - - -
123-86-4 100 ppm 200 ppm - - -
1330-20-7 100 ppm 200 ppm - - -
Respiratory protection:
With this preparation, avoid in particular any inhalation of vapors.
Hand protection:
Protective creams may be used for exposed skin, but they should not be applied after contact with the product.
Due to the solvents present, it is recommended that polyvinyl alcohol or nitrile rubber gloves be worn.
Eye and face protection:
Avoid contact with the skin and eyes. Wear safety goggles
Provide eye washes in workshops where the product is constantly handled
Skin protection:
For further information, see 搂 11 of S.D.S. - Toxicological information.
Environmental exposure controls:
9 - PHYSICAL AND CHEMICAL PROPERTIES
General information:
Physical state: viscous liquid
Important health, safety and environmental information:
pH of the substance or preparation: not relevant.
The pH is impossible to measure or its value is not relevant.
Boiling point/boiling range: 130 掳C.
Flash point interval: 23掳C. < Flash point: <= 55掳C.
vapour pressure: Below 110 kPa (1.10 bar).
Density: >1
water solubility: Insoluble.
Other information:
melting point/melting range: not specified.
Self-ignition temperature: 315 掳C.
Decomposition point/decomposition range : not specified.
10 - STABILITY AND REACTIVITY
When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon monoxide and dioxide,
smoke and nitrogen oxide
Conditions to avoid:
Materials to avoid:
Hazardous decomposition products:
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11 - TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
Exposure to vapors from solvents contained in the preparation beyond the exposure limits stated may produce effects harmful to health, such as:
Irritation of mucous membrane and respiratory system, kidneys, liver and central nervous system.
Symptoms produced will include headaches, numbness, dizziness, fatigue, muscular asthenia and, in extreme cases, loss of consciousness.
Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause non-allergic dermatitis on contact and
absorption through the epidermis.
Splashes in the eyes may cause irritation and reversible damage
It is generally agreed that substances contained are likely to cause significant irritation which lasts for at least twenty four hours after application to
the healthy, unbroken skin of an animal for a period of up to 4 hours.
In the event of exposure by inhalation:
In the event of swallowing:
In the event of splashes or contact with skin:
In the event of splashes or contact with eyes:
Other data:
12 - ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
The product must not be allowed to run into drains or waterways.
Mobility:
Persistence and degradability:
Bioaccumulative potential:
Ecotoxicity:
Harmful to aquatic organisms, may cause long-termadverse effects in the aquatic environment.
Other adverse effects:
13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
Waste:
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
Local arrangements:
Codes of wastes (Decision 2001/573/EC, Directive 75/442/EEC, Directive 91/689/EEC on hazardous waste) :
14 - TRANSPORT INFORMATION
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2005 - IMDG
2004 - ICAO/IATA 2005).
UN1263=PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED
MATERIAL (including paint thinning and reducing compound)
ADR/RID Class Code Pack gr. Label Ident. LQ Provis.
3 F1 III 3 30 LQ7 163-650-640E
Not subject to this regulation if Q < 450l.
IMDG Class 2掳Label Pack gr. LQ EMS Provis.
3 - III 5L F-E,S-E 163 223 944 955
Not subject to this regulation if Q < 30l
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IATA Class 2掳Label Pack gr. Passager Passager Cargo Cargo note
3 - III 309 60 L 310 220 L A3 A72
3 - III Y309 10 L - - -
15 - STATUTORY INFORMATION
This preparation was classified in compliance with the directive known as 1999/45/EC and its adaptations
In addition directive 2004/73/EC with the 29掳 adaptation of directive 67/548/EEC (Hazardous substances) have been taken into account.
Preparation classification:
Harmful. Flammable.
Contains:
601-022-00-9 O-XYLENE
Particular hazards associated with the preparation and safety recommendations:
R 52/53 Harmful to aquatic organisms, may cause long-termadverse effects in the aquatic environment.
R 38 Irritating to skin.
R 20/21 Harmful by inhalation and in contact with skin.
R 10 Flammable.
S 23 Do not breathe vapour.
S 36/37 Wear suitable protective clothing and gloves.
Particular provisions:
16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety requirements relating to our product and not a
guarantee of its properties
Full text of risk phrases appearing in section 2:
R 10 Flammable.
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 20/21 Harmful by inhalation and in contact with skin.
R 36 Irritating to eyes.
R 37 Irritating to respiratory system.
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 65 Harmful. may cause lung damage if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
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