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SAFETY DATA SHEET gelcoat Enguard PX
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
1.1 Identification of the article
Product name
ENGUARD : Gel coat, P芒te colorante, Colle - MAXGUARD "2G100"
Product code
"2G100" = Code (SAFETY DATA
SHEET)
1.2 Identification of the manufacturer/importer/supplier
1.2.1 Supplier
ASHLAND POLYESTER
S.A.S
Quartier des Bonnelles
1.2.2 Address
30131 PUJAUT, FRANCE
+33-04-66-90-30-70
Telephone number
Fax +33-04-66-90-30-96
1.2.3 Name and address of the informant in emergency cases
Emergency telephone number
+33-04-66-90-30-70 ( France )
2. COMPOSITION/INFORMATION ON INGREDIENTS
2.1 Chemical characterisation
Resin solution
2.2 Hazardous components
2.2.1 2.2.2 2.2.3 2.2.4
CAS-No. Components Weight % Classification
. . . .
100-42-5 Styrene 15-50% Xn; R10-20-36/38
3. HAZARDS IDENTIFICATION
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Flammable. Harmful by inhalation. Irritating to eyes and skin.
4. FIRST AID MEASURES
4.2 Inhalation
Move to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician.
4.3 Skin contact
Take off all contaminated clothing immediately. Wash off with soap and plenty of water. If skin
irritation persists, call a physician.
4.4 Eye contact
Rinse immediately with plenty of water for at least 15 minutes. Keep eye wide open while rinsing.
Rinse thoroughly with plenty of water, also under the eyelids. Consult a physician.
4.5 Ingestion
Do not induce vomiting. Rinse mouth. Ingest activated charcoal. Obtain medical attention.
4.6 Notes to physician
Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media
dry powder, alcohol-resistant foam, carbon dioxide (CO2), water. Water may be ineffective.
5.3 Specific hazards
smoke cloudy black.
5.4 Special protective equipment for firefighters
In the event of fire, wear self contained breathing apparatus.
5.5 Specific methods
Cool containers / tanks with water spray.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions
Remove all sources of ignition. Keep people away from and upwind of spill/leak. Use personal
protective equipment.
6.2 Environmental precautions
Do not flush into surface water or sanitary sewer system.
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6.3 Methods for cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste.
7. HANDLING AND STORAGE
7.1 Handling
Use only in area provided with appropriate exhaust ventilation. The product should only be used
in areas from which all naked lights and other sources of ignition have been excluded. wear
personal protective equipment. When using do not smoke.
7.2 Storage
Take precautionary measures against static discharges. Keep in a dry, cool and well-ventilated
place. Do not repack.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Engineering measures
Ensure adequate ventilation, especially in confined areas.
8.2 Control parameters
8.2.1 National occupational exposure limits
CAS number 100-42-5
Components Styrene / FRANCE
50 ppm (8 h)
215 mg/m鲁 (8 h)
100-42-5
CAS number
Styrene / FIN (1993)
Components
20 ppm (8 h) 100 ppm (15 min)
86 mg/m鲁 (8 h) 430 mg/m鲁 (15 min)
CAS number 100-42-5
Components Styrene / D (1993) MAK-WERT
20 ppm (8 h)
85 mg/m鲁 (8 h)
8.3 Personal protective equipment
8.3.1 Hygiene measures
When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and
safety practice.
8.3.2 Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment.
8.3.3 Hand protection
solvent-resistant gloves.
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8.3.4 Eye protection
safety glasses.
8.3.5 Skin and body protection
Wear suitable protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Form, Colour, Odour viscous liquid : stinging
9.2 pH not applicable
9.3 Information on changes in the
physical state
145掳C (Styrene)
9.3.1 Boiling point/range
9.3.2 Melting point/range -31掳C (Styrene)
9.4 Flash point 32掳C (closed cup, Styrene)
9.6 Autoignition temperature 480掳C (Styrene)
9.8 Explosion limits
1.2 VOL.-% (Styrene)
- lower
8.9 VOL.-% (Styrene)
- upper
6 mbar (20掳C, Styrene)
9.10 Vapour pressure
approx 1,0-2,0 kg/dm鲁
9.11 Relative density
9.12 Solubility
Water solubility practically insoluble
- fat solubility
9.13 Partition coefficient (n- logK_o_w = 2.95 (Styrene)
octanol/water)
10 STABILITY AND REACTIVITY
10.1 Conditions to avoid
Polymerisation occurs when exposed to white light, ultraviolet light or heat. Exothermic reaction.
10.2 Materials to avoid
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid
exothermic reactions. Reacts violently with peroxides.
11 TOXICOLOGICAL INFORMATION
11.1 Acute toxicity
LD50/oral/rat = 5000 mg/kg (Styrene)
11.2 Local effects
Vapours may be irritating to eyes, nose, throat, and lungs.
11.4 Long term toxicity
Prolonged skin contact may cause skin irritation and/or dermatitis.
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11.5 Human experience
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
12 ECOLOGICAL INFORMATION
12.1 Persistence and degradability
12.1. Biodegradation
1
Biochemical oxygen demand within 5 days (BOD5) = 0.55-1.95 (Styrene)
12.1. Chemical degradation
2
ABIOTIC DEGRADATION / CALCULATED HALF-LIFE (T1/2) IN AIR = 2.5 HOURS (Styrene)
12.2 Bioaccumulation
logK_o_w = 2.95 (Styrene) BCF/GOLDFISH = 13.5 (Styrene)
12.3 Mobility
HENRY'S LAW CONSTANT/25掳C = 5.2 x 10^-鲁ATM x M鲁 / MOL (Styrene, CALCULATED)
12.4 Ecotoxicity effects
12.4. Toxicity to algae
1
LC50/48h/daphnia = 23 mg/l (Styrene) LC50/96h/LEPOMIS MACROCHIRUS = 25 mg/l (Styrene)
13 DISPOSAL CONSIDERATIONS
The following actions are recommended : 1. solution : Dispose of as special waste in compliance
with local and national regulations. 2. Toughened : Can be disposed of as a solid waste or burned
in a suitable installation subject to local regulations. 3. Empty containers : In accordance with local
and national regulations
14 TRANSPORT INFORMATION
1866
14.1 UN-No
III
14.2 Packaging group
14.3 ADR/RID
3,31 (c) ADR/ RTMDR
14.3. Class
1
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30
14.3. HI/UN No
2
Resin solution POLYESTER RESIN
14.3. Proper shipping name
3
14.3. Further Information -
4
14.4 IMO
3.3 IMDG CODE : 3379
14.4. Class
1
UNSATURATED POLYESTER RESIN
14.4. Proper shipping name
2
MFAG 310
EmS 3-05
14.4. Further Information MARINE POLLUANT
3
14.5 ICAO
3
14.5. Class
1
14.5. Proper shipping name UNSATURATED POLYESTER RESIN
2
14.5. Further Information -
3
15 REGULATORY INFORMATION
15.1 Labelling
15.1. Danger classification
1
Xn harmful
15.1. Contains STYRENE
2
15.1. R-phrases
3
R10 Flammable.
R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
15.1. S-phrases
4
S2 Keep out of reach of children.
S23 Do not breathe vapour.
15.2 National regulations
The product is classified and labelled in accordance with EC directives.
16 OTHER INFORMATION
16.3 Further information
Contact manufacturer.
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16.4 Additional information available from
ASHLAND POLYESTER S.A.S./ PRODUCT LIABILITY / TEL. +33-04-66-90-30-70
16.5 Sources of information used in the compilation of the safety data sheet
HOMMEL (1993) : HANDBUCH DER GEF脛HRLICHEN G脺TER PHILIP H. HOWARD (1990) :
HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA FOR ORGANIC
CHEMICALS.
The information presented in this document is based on our latest knowledge.
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