Written by 鈥揓P GROS SDS Edition : 1 鈥? September 2005
Technical Manager Page : 1/1
SAFETY DATA SHEET
Special equipment for fire-fighting personnel.
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
Preparation:
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be
EMP 914 Txx
Name:
equipped with autonomous insulating breathing apparatus.
Pastes for SRP 550 or SRP 910 polyurethan resin
Company/business:
6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
SICOMIN
Registered company name:
Safety precautions:
Address: RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues France Eliminate any possible source of ignition and ventilate the premises.
Phone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 e-mail: composites@sicomin.com Avoid inhaling the fumes.
Consult the safety measures listed under headings 7 and 8.
2 - INFORMATION REGARDING CONSTITUENTS Environmental safety precautions:
Hazardous substances present on their own. Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite,
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a diatom earth in drums for waste disposal.
100% pure state) Prevent any material from entering drains or waterways.
Methylethyl Ketone (MEK) cas n掳 78-93-3 Concentration < 40 % by weight Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
Symbol: Xi Irritating F : Hightly flammable liquid If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory
Risk phrases: R 11 R 36/37 procedures
Cleaning methods:
Clean preferably with a detergent, do not use solvents.
3 - IDENTIFICATION OF HAZARDS
This product is classed: Highly flammable liquid.
7 - HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
4 - FIRST AID.
Handling:
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
Handle in well-ventilated areas.
NEVER induce swallowing in an unconscious person.
The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
In the event of exposure by inhalation.
Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still.
the occupational exposure limits.
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
Fire prevention:
Do not give the patient anything orally.
Prevent the accumulation of electrostatic charges with connections to earth
In the event of splashes or contact with eyes.
The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
shoes and clothes and make floors of conductive materials.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
Use the product in premises where there are no naked flames or other sources of ignition and have protected
In the event of splashes or contact with skin.
electrical equipment
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
DO NOT use solvents or thinners.
Do not use tools which may produce sparks. Do not smoke.
In the event of swallowing.
Prevent access by unauthorised personnel.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and
Recommended equipment and procedures
consult a doctor.
Observe precautions stated on label and also industrial safety regulations
Keep still. DO NOT induce vomiting.
Packages which have been opened must be reclosed carefully and stored in an upright position
If swallowed accidentally, call a doctor to assess the need for monitoring and subsequent treatment in hospital. Show
Avoid inhaling fumes.
him the label.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation may be
inadequate to control particles and solvent fumes in every case.
5 - FIRE-FIGHTING MEASURES
It is therefore recommended that personnel wear masks with a compressed air supply during spraying operations until
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
the concentration of particles and solvent fumes has fallen below the exposure limits.
In the event of fire, the recommended extinguishing agents are:
Prohibited equipment and procedures.
Special foams for polar liquids (known as alcohol resistant), powders, carbon dioxide.
Smoking, eating and drinking are prohibited in premises where the preparation is used
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Never open the packages under pressure
Extinguishing agents not to be used
Storage.
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool
Keep the container tightly closed in a dry, well-ventilated place
containers exposed to the fire and to disperse fumes.
Keep away from all sources of ignition - do not smoke.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Keep well away from all sources of ignition, heat and direct sunlight
Do not breathe in smoke.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
SICOMIN RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 Mail: composites@sicomin.com
Written by 鈥揓P GROS SDS Edition : 1 鈥? September 2005
Technical Manager Page : 2/2
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, the liquid Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA
cannot spread beyond this area. for air transport
UN 1193 = Methyl Ethyl Ketone
ADR/RID Class Number Code Label Identif.
8 - EXPOSURE CONTROL - PERSONAL SAFETY
3 3掳b 33 3 1193
Technical measures.
IMDG Page Class Group Identif. N掳GSMU Marine pollutant
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction.
3226 3.2 II 3-06 300 no
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure limits, wear
breathing apparatus
IATA Class group Label
Exposure limits per INRS:
3.1 II 3
France: VME-ppm: VME-mg/m3: TWA-ppm: TWA-mg/m3: STEL ppm STEL mg/m3
200 600 200 590 300 885
Safety breathing apparatus: 15 - STATUTORY INFORMATION
With this preparation, avoid in particular any inhalation of fumes. This preparation was classified in compliance with the directive known as 88/379/EEC and its
Hand protection. adaptations
Protective creams may be used for exposed skin, but they should not be applied after contact with the product. In addition directive 96/54/EC with the 22掳 adaptation of directive 67/548/EEC (Hazardous substances) have been
Due to the solvents present, it is recommended that neoprene rubber or nitrile rubber gloves be worn taken into account.
Eye and face protection. Preparation classification.
Use eye protectors designed to protect against liquid splashes Harmful. Irritant - Highly flammable.
Skin protection. Contains: Methyl Ethyl Ketone (MEK)
For further information, see 搂 11 of S.D.S. - Toxicological information.
Particular hazards associated with the preparation and safety recommendations:
R 11 Highly flammable.
9 - PHYSICAL PROPERTIES
R 36/37 Irritating to eyes and respiratory system
Density: nearly 1 kg / litre
Color: various, depend of pigment (Txx)
S 23 Do not breathe vapour.
Acid/base character of preparation: na
S 33 Take precautionary measures against static discharges.
Solubility of preparation in water: partialy
S 16 Keep away from sources of ignition - no smoking.
Vapour tension at 60掳C of volatile constituents: Below 110Kpa (1.10 bar)
S9 Keep container in a well-ventilated place.
Physical state: Humid paste
S 51 Use only in well ventilated areas
Flash point interval: Flash point: - 9掳C
When a pH measure is possible, it has a value of: not stated
Self-ignition temperature: 515 掳C 16 - OTHER INFORMATION
Decomposition temperature: not relevant Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based
Melting temperature interval: na on our current level of knowledge and on national and community regulations.
Average distillation temperature of solvents contained: 80 掳C The product must not be used for any purposes other than those specified under heading 1 without first obtaining
written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and
10 - STABILITY AND REACTIVITY
local regulations.
When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon
The information given on this safety data sheet must be regarded as a description of the safety requirements relating
monoxide and dioxide, smoke
to our product and not a guarantee of its properties
Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs,
furnaces etc.) must not be allowed on the premises.
11 - TOXICOLOGICAL INFORMATION
LD 50 rat: 3000 mg/kg
LD 50 rabbit skin: 13000 mg/kg
Splashes in the eyes may cause irritation and reversible damage
12 - ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
The product must not be allowed to run into drains or waterways.
13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
14 - TRANSPORT INFORMATION
SICOMIN RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 Mail: composites@sicomin.com
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