Written by 鈥揓P GROS SDS : RA100X/A
Edition : 1 - December 1998
Technical Manager
SAFETY DATA SHEET RA100X/A
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS In the event of fire, the recommended extinguishing agents are:
Special foams for polar liquids (known as alcohol resistant), powders, carbon dioxide.
In the event of fire, use specifically suitable extinguishing agents. Never use water.
DILUENT PU N掳 2
Name:
Extinguishing agents not to be used
Water is not generally recommended since it can be ineffective; however, it can be used successfully
Company / business
to cool containers exposed to the fire and to disperse fumes.
SICOMIN
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to
Address RN 568 BP 23 13161 Ch芒teauneuf-les-Martigues France
health.
T茅l 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Do not breathe in smoke.
Emergency telephone No.: 01 45 42 59 59 Association/ Organisation: ORFILA.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
2 - INFORMATION REGARDING CONSTITUENTS
Special equipment for fire-fighting personnel.
Hazardous substances present on their own.
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel
have in a 100% pure state)
are to be equipped with autonomous insulating breathing apparatus.
This preparation contains no hazardous substance in this category.
6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
Other substances representing a hazard:
Safety precautions:
No known substance in this category present.
Eliminate any possible source of ignition and ventilate the premises.
Substances present at a concentration below the minimum danger threshold.
Avoid inhaling the fumes.
606-010-00-7 CYCLOHEXANONE Concentration >=10.00% and <25.00%. Symbol: Xn R: 10-20
Consult the safety measures listed under headings 7 and 8.
607-195-00-7 2-METHOXY-1-METHYLETHYL ACETATE Concentration >=10.00% and <25.00%. Symbol:
Environmental safety precautions:
Xi R: 10-36
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth,
Other substances with occupational exposure limits.
vermiculite, diatom earth in drums for waste disposal.
603-064-00-3 MONOPROPYLENE GLYCOL METHYL ETHER Concentration >=10.00% and <25.00%.
Prevent any material from entering drains or waterways.
Symbol: R: 10
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
607-025-00-1 BUTYLACETATE N- Concentration >=50.00% and <100.00%. Symbol: R: 10
If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with
3 - IDENTIFICATION OF HAZARDS
statutory procedures
This preparation is not classed as hazardous to health by directive 88/379/EEC.
Cleaning methods:
This product is classed: Flammable.
Clean preferably with a detergent, do not use solvents.
4 - FIRST AID.
7 - HANDLING AND STORAGE
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
The regulations relating to storage premises apply to workshops where the product is handled.
NEVER induce swallowing in an unconscious person.
Handling:
In the event of exposure by inhalation.
Handle in well-ventilated areas.
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still.
The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
In the event of splashes or contact with eyes.
Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
higher than the occupational exposure limits.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
Fire prevention:
In the event of splashes or contact with skin.
Prevent the accumulation of electrostatic charges with connections to earth
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
The preparation may become electrostatically charged; always place on the ground during transfer.
DO NOT use solvents or thinners.
Wear antistatic shoes and clothes and make floors of conductive materials.
In the event of swallowing.
Use the product in premises where there are no naked flames or other sources of ignition and have
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with
protected electrical equipment
water and consult a doctor.
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
Keep still. DO NOT induce vomiting.
Do not use tools which may produce sparks. Do not smoke.
If swallowed accidentally, call a doctor to assess the need for monitoring and subsequent treatment in
Prevent access by unauthorised personnel.
hospital. Show him the label.
Recommended equipment and procedures
5 - FIRE-FIGHTING MEASURES Observe precautions stated on label and also industrial safety regulations
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
Packages which have been opened must be reclosed carefully and stored in an upright position
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by 鈥揓P GROS SDS : RA100X/A
Edition : 1 - December 1998
Technical Manager
Avoid inhaling fumes. Solubility of preparation in water: Insoluble.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation Vapour tension at 50掳C of volatile constituents: Below 110Kpa (1.10 bar).
may be inadequate to control particles and solvent fumes in every case. Physical state: fluid liquid
It is therefore recommended that personnel wear masks with a compressed air supply during spraying Flash point interval: 21掳C. < Flash point: <= 55掳C.
operations until the concentration of particles and solvent fumes has fallen below the exposure limits. The pH is impossible to measure or its value is not relevant.
Prohibited equipment and procedures. Self-ignition temperature: 325 掳C.
Smoking, eating and drinking are prohibited in premises where the preparation is used Decomposition temperature: not relevant.
Never open the packages under pressure Melting temperature interval: -89 掳C.
Storage. Average distillation temperature of solvents contained: 128 掳C.
Keep the container tightly closed in a dry place. 10 - STABILITY AND REACTIVITY
Keep away from all sources of ignition - do not smoke. When exposed to high temperatures, the preparation may release dangerous decomposition products
Keep well away from all sources of ignition, heat and direct sunlight such as carbon monoxide and dioxide, smoke and nitrogen oxide
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, 11 - TOXICOLOGICAL INFORMATION
the liquid cannot spread beyond this area. No data is available regarding the preparation itself.
8 - EXPOSURE CONTROL - PERSONAL SAFETY Exposure to fumes from solvents contained in the preparation beyond the exposure limits stated may
Technical measures. produce effects harmful to health, such as:
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general Irritation of mucous membrane and respiratory system, kidneys, liver and central nervous system.
extraction. Symptoms produced will include headaches, numbness, dizziness, fatigue, muscular asthenia and, in
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure limits, extreme cases, loss of consciousness.
wear breathing apparatus Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause
Exposure limits per INRS ND 1945-153-93/(1996) and ND 2022-163-96: non-allergic dermatitis on contact and absorption through the epidermis.
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳: Splashes in the eyes may cause irritation and reversible damage
603-064-00-3 100 360 - - - 84 12 - ECOLOGICAL INFORMATION
606-010-00-7 25 100 - - - 84 No ecological data on the product itself is available.
607-025-00-1 150 710 200 940 - 84 The product must not be allowed to run into drains or waterways.
607-195-00-7 - - - - - - 13 - DISPOSAL CONSIDERATIONS
Germany Class: MAK-ppm: MAK-mg/m3: Notes: Notes: Do not pour into drains or waterways.
603-064-00-3 I 100 375 -
14 - TRANSPORT INFORMATION
606-010-00-7 - - - B* Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and
607-025-00-1 I 200 950 - ICAO/IATA for air transport
607-195-00-7 I 50 275 - UN 1263 = Paint flammable (including lacquer, enamel, stain, shellac, varnish, polish and related
ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-mg/m3: Notes: Notes: material).
603-064-00-3 100 369 150 553 - ADR/RID Class Number Code Identif. Label
606-010-00-7 25 100 - - * 3 31掳 c) 30 1263 3
607-025-00-1 (150) (713) (200) (950) - IMDG Page N掳ONU Class Number 2掳Label Identif. N掳GSMU
607-195-00-7 - - - - - 1263 3.3 III - 3-05 310
Safety breathing apparatus: The page number 3372 should not appear anymore on the Dangerous Goods Declaration (Amendment 28-
Where workers encounter concentrations higher than the exposure limits, they must wear suitable, 96).
approved masks. IATA N掳ONU Class 2掳Label Number Passenger Passenger Freighter Freighter
Hand protection. nota
Protective creams may be used for exposed skin, but they should not be applied after contact with the 1263 3 - III 309 60 L 310 220 L
product. A72
Due to the solvents present, it is recommended that polyvinyl alcohol or neoprene rubber gloves be worn. 1263 3 - III Y309 10 L - - -
Eye and face protection.
15 - STATUTORY INFORMATION
Use eye protectors designed to protect against liquid splashes
This preparation was classified in compliance with the directive known as 88/379/EEC
Skin protection.
and its adaptations
For further information, see 搂 11 of S.D.S. - Toxicological information.
In addition directive 96/54/EC with the 22掳 adaptation of directive 67/548/EEC (Hazardous substances)
9 - PHYSICAL PROPERTIES have been taken into account.
Density: <1 Preparation classification.
Acid/base character of preparation: not relevant. Flammable.
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by 鈥揓P GROS SDS : RA100X/A
Edition : 1 - December 1998
Technical Manager
Contains:
Particular hazards associated with the preparation and safety recommendations:
R 10 Flammable.
S 23 Do not breathe vapour.
16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data
sheet is based on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first
obtaining written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal
requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety
requirements relating to our product and not a guarantee of its properties
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
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