Written by Checked by SDS : RA707X/A
Jean-Pierre GROS A. DURRIEU
Edition : 1 - February 1999
Technical Manager Quality insurance
SAFETY DATA SHEET RA707X/A
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
In the event of fire, the recommended extinguishing agents are:
Special foams for polar liquids (known as alcohol resistant), powders, carbon dioxide.
DILUENT EP N掳 3 In the event of fire, use specifically suitable extinguishing agents. Never use water.
Extinguishing agents not to be used
Water is not generally recommended since it can be ineffective; however, it can be used successfully
SICOMIN
Registered company name to cool containers exposed to the fire and to disperse fumes.
Address RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues France A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to
Tel 33 04 42 42 30 20 Fax 33 04 42 81 29 29 health.
composites@sicomin.com Do not breathe in smoke.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
Special equipment for fire-fighting personnel.
Association/ Organisation: ORFILA.
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
2 - INFORMATION REGARDING CONSTITUENTS
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel
Hazardous substances present on their own.
are to be equipped with autonomous insulating breathing apparatus.
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would
6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
have in a 100% pure state)
Safety precautions:
This preparation contains no hazardous substance in this category.
Eliminate any possible source of ignition and ventilate the premises.
Other substances representing a hazard:
Avoid inhaling the fumes.
No known substance in this category present.
Consult the safety measures listed under headings 7 and 8.
Substances present at a concentration below the minimum danger threshold.
Environmental safety precautions:
No known substance in this category present.
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth,
Other substances with occupational exposure limits.
vermiculite, diatom earth in drums for waste disposal.
603-064-00-3 MONOPROPYLENE GLYCOL METHYL ETHER Concentration >=25.00% and <50.00%.
Prevent any material from entering drains or waterways.
Symbol: R: 10
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
606-004-00-4 METHYL ISOBUTYL KETONE Concentration >=25.00% and <50.00%. Symbol: F R: 11
If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with
607-025-00-1 BUTYLACETATE N- Concentration >=25.00% and <50.00%. Symbol: R: 10
statutory procedures
3 - IDENTIFICATION OF HAZARDS
Cleaning methods:
This preparation is not classed as hazardous to health by directive 88/379/EEC.
Clean preferably with a detergent, do not use solvents.
This product is classed: Flammable.
7 - HANDLING AND STORAGE
4 - FIRST AID.
The regulations relating to storage premises apply to workshops where the product is handled.
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
Handling:
NEVER induce swallowing in an unconscious person.
Handle in well-ventilated areas.
In the event of exposure by inhalation.
The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still.
Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations
In the event of splashes or contact with eyes.
higher than the occupational exposure limits.
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
Fire prevention:
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
Prevent the accumulation of electrostatic charges with connections to earth
In the event of splashes or contact with skin.
The preparation may become electrostatically charged; always place on the ground during transfer.
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Wear antistatic shoes and clothes and make floors of conductive materials.
DO NOT use solvents or thinners.
Use the product in premises where there are no naked flames or other sources of ignition and have
In the event of swallowing.
protected electrical equipment
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
water and consult a doctor.
Do not use tools which may produce sparks. Do not smoke.
Keep still. DO NOT induce vomiting.
Prevent access by unauthorised personnel.
If swallowed accidentally, call a doctor to assess the need for monitoring and subsequent treatment in
Recommended equipment and procedures
hospital. Show him the label.
Observe precautions stated on label and also industrial safety regulations
5 - FIRE-FIGHTING MEASURES
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues cedex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by Checked by SDS : RA707X/A
Jean-Pierre GROS A. DURRIEU
Edition : 1 - February 1999
Technical Manager Quality insurance
Packages which have been opened must be reclosed carefully and stored in an upright position Flash point interval: 21掳C. < Flash point: <= 55掳C.
Avoid inhaling fumes. The pH is impossible to measure or its value is not relevant.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation Self-ignition temperature: 370 掳C.
may be inadequate to control particles and solvent fumes in every case. Decomposition temperature: not relevant.
It is therefore recommended that personnel wear masks with a compressed air supply during spraying Melting temperature interval: -100 掳C.
operations until the concentration of particles and solvent fumes has fallen below the exposure limits. Average distillation temperature of solvents contained: 116 掳C.
Prohibited equipment and procedures. 10 - STABILITY AND REACTIVITY
Smoking, eating and drinking are prohibited in premises where the preparation is used When exposed to high temperatures, the preparation may release dangerous decomposition products
Never open the packages under pressure such as carbon monoxide and dioxide, smoke and nitrogen oxide
Storage. 11 - TOXICOLOGICAL INFORMATION
Keep the container tightly closed in a dry place. No data is available regarding the preparation itself.
Keep away from all sources of ignition - do not smoke. Exposure to fumes from solvents contained in the preparation beyond the exposure limits stated may
Keep well away from all sources of ignition, heat and direct sunlight produce effects harmful to health, such as:
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, Irritation of mucous membrane and respiratory system, kidneys, liver and central nervous system.
the liquid cannot spread beyond this area. Symptoms produced will include headaches, numbness, dizziness, fatigue, muscular asthenia and, in
8 - EXPOSURE CONTROL - PERSONAL SAFETY extreme cases, loss of consciousness.
Technical measures. Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause non-allergic
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general dermatitis on contact and absorption through the epidermis.
extraction. Splashes in the eyes may cause irritation and reversible damage
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure limits, 12 - ECOLOGICAL INFORMATION
wear breathing apparatus No ecological data on the product itself is available.
Exposure limits per INRS ND 1945-153-93/(1996) and ND 2022-163-96: The product must not be allowed to run into drains or waterways.
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳:
13 - DISPOSAL CONSIDERATIONS
603-064-00-3 100 360 - - - 84
Do not pour into drains or waterways.
606-004-00-4 50 205 - - - 84
14 - TRANSPORT INFORMATION
607-025-00-1 150 710 200 940 - 84
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA
Germany Class: MAK-ppm: MAK-mg/m3: Notes: Notes:
for air transport
603-064-00-3 I 100 375 -
UN 1263 = Paint flammable (including lacquer, enamel, stain, shellac, varnish, polish and related material).
606-004-00-4 II,2 100 400 -
ADR/RID Class Number Code Identif. Label
607-025-00-1 I 200 950 -
3 31掳 c) 30 1263 3
ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-mg/m3: Notes: Notes:
IMDG Page N掳ONU Class Number 2掳Label Identif. N掳GSMU
603-064-00-3 100 369 150 553 -
1263 3.3 III - 3-05 310
606-004-00-4 50 205 75 307 -
The page number 3372 should not appear anymore on the Dangerous Goods Declaration (Amendment 28-96).
607-025-00-1 (150) (713) (200) (950) -
IATA N掳ONU Class 2掳Label Number Passenger Passenger Freighter Freighter
Safety breathing apparatus:
nota
Where workers encounter concentrations higher than the exposure limits, they must wear suitable,
1263 3 - III 309 60 L 310 220 L
approved masks.
A72
Hand protection.
1263 3 - III Y309 10 L - - -
Protective creams may be used for exposed skin, but they should not be applied after contact with the
15 - STATUTORY INFORMATION
product.
This preparation was classified in compliance with the directive known as 88/379/EEC and its
Due to the solvents present, it is recommended that polyvinyl alcohol or latex rubber gloves be worn
adaptations
Eye and face protection.
In addition directive 96/54/EC with the 22掳 adaptation of directive 67/548/EEC (Hazardous substances) have been
Use eye protectors designed to protect against liquid splashes
taken into account.
Skin protection.
Preparation classification.
For further information, see 搂 11 of S.D.S. - Toxicological information.
Flammable.
9 - PHYSICAL PROPERTIES
Contains:
Density: <1
Particular hazards associated with the preparation and safety recommendations:
Acid/base character of preparation: not relevant.
R 10 Flammable.
Solubility of preparation in water: Insoluble.
S 23 Do not breathe vapour.
Vapour tension at 50掳C of volatile constituents: Below 110Kpa (1.10 bar).
16 - OTHER INFORMATION
Physical state: fluid liquid
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues cedex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by Checked by SDS : RA707X/A
Jean-Pierre GROS A. DURRIEU
Edition : 1 - February 1999
Technical Manager Quality insurance
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based
on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining
written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and
local regulations.
The information given on this safety data sheet must be regarded as a description of the safety requirements relating
to our product and not a guarantee of its properties
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues cedex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
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