DM 06
E 1121.4
Rewiewed: 2002 September
Material Safety Data Sheet 91 / 155 / CEE Page 1 / 4
1- Product and company identification
DM 06
Trade name:
Curing agent for epoxy resin
Manufacturer / Supplier:
SICOMIN Composites RN 568 Quartier la Moutte BP 23
13 161 Ch芒teauneuf-les-Martigues C茅dex -France-
T茅l: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
2- Composition / Information on ingredients
Chemical characterization: Polyamines and base Mannich
Chemical Name Cas number % Symbol Risk Classification
m-Xylene diamin XDA 1477-55-0 < 40 C 20/22 34 43
Bisphenol A 80-05-7 < 40 Xi 36/37/38 43
3- Hazards Identification
C: Corrosive
R 21/22 Harmful by skin contact and if swallowed
R 34: Causes burns
R 43: May cause sensitization by skin contact
Signs and symptoms of exposure (Possible longer term effects):
Repeated and/or prolonged exposures may result in : adverse respiratory effects (such as cough,
tightness of chest or shortness of breath); adverse skin effects (such as defatting, rash, irritation
or corrosion); adverse eye effects (such as conjunctivitis or corneal damage).
4- First aid measures
Signs and symptoms of exposure (acute effects)
Eye contact:
Rinse immediately with plenty of water for at least 15'. Get medical attention.
Skin contact:
Immediatly remove contaminated clothing. Remove the excess and wash with water and soap.
Get medical attention.
Ingestion:
Do not induce vomiting. Consult immediately a physician
Inhalation:
Remove from the contaminated area and keep warm and at rest.
5- Fire fighting measures
Suitable extinguishing agents:
Powder CO2, foam. Cool the containers with water spray
Products to avoid:
ND
Products of combustion will include:
Poison gas as nitrogen gas (NOx), ammoniac, carbon monoxide (CO)
Protective equipment:
Use breathing apparatus
DM 06
E 1121.4
Rewiewed: 2002 September
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6- Accidental release measures
Individual precautions:
Use gloves, goggles, masks and protective clothing
Use breathing equipment if the area is narrow, keep fire sources away
Environmental precautions:
Keep the product away from superficial and underground water. In the event of product entering
waters or drainage system or pollution soil or plants, informing fire service or police.
Cleaning procedures:
Soak up inert material in accordance with law regulations. Wash with water & detergents.
7- Handling and storring
Handling:
Use personal protection (see point 8). Provide adquate ventilation. Avoid inhalation vapours.
Storring:
Store in well ventilated area, in close containers.
The product is sensitive to CO2 and humidity.
8- Exposure controls / personal protection
Precautionary measures:
Provide adequate ventilation
CAS 1477-55-0: VME 0.1 mg/m3
Respiratory protection:
Necessary in case the area is not well ventilated: mask with adequate filters
Hand protection:
Use appropriate gloves
Eyes protection:
Wear goggles or a face visor
Skin protection:
Use protective clothing, exercising reasonable personal cleanliness
9- Chemical / Physical properties
Appearence : Liquid
Colour : Yellow
Odour : Amoniacal
Ph : 11, Alcaline ISO 8975
Boiling point : > 200 掳C DIN 53171
Flash point : > 100掳C DIN 51758
Solubility in water : Partially soluble
Solubility in organic solvents : Alcohols and aromatic hydrocarbons
Specific gravity (Kg / l 20掳C) : 1.02 + 0.02 ISO 2811
Viscosity (mPa.s 25掳C) : 1100 + 100 ISO 9371
Pression de vapeur (mm Hg 脿 25掳C) : < 0.1 mbar
10- Stability and reactity data
Precautions: ND
Materials to avoid:
Acids, strong oxidizers, epoxidies, ketones
Hazardous decomposition products:
In case of fire, the product may develop toxic gas as nitrous gas (NOx), carbon monoxide (CO),
NHx, etc..
DM 06
E 1121.4
Rewiewed: 2002 September
Page 3 / 4
11- Toxicological information
Consider the concentration of each substance to evaluate toxicological effects caused by exposure
Cas number Inhalation Ingestion Skin contact Long term effect
LD 50 (rat) LD 50 (rat) LD 50 (rabbit) Skin cobaye
mg / l / 4h mg/kg mg/kg
1477-55-0 2.4 1040 nd nd
80-05-7 nd 3300 3000 no irritating
Ingestion:
Corrosive. May cause burns of mouth and severe gastrointestinal trouble.
Skin absorption:
Prolonged of widespread exposure may result in the absorption of potentially harmful amounts
of material.
May cause chemical burns and develop skin allergy.
Inhalation:
Vapours are irritating and may develop allergy.
Eye contact:
May cause severe irritation with corneal injury wich may result in permanent impairment of vision,
even blindness.
12- Ecological Information
General notes:
Do not empty into drains
13- Disposal considerations
Dispose of in accordance with local and national regulations
14- Transport Information
Correct technical name: Amines, liquid, corrosives, nos
Content: m-Xylenediamin, Bisphenol A
ONU N掳: 2735
Air transport - OACI / IATA Class 8 Group: II
Sea transport - IMDG Class 8 Group: II IMDG page: 8109.2
N掳 EMS: 8-05 MFAG: 320 Marine pollutant: no
Road transport - ADR / RID Class 8, 53(b) HI/Kemler n掳: 80 label: 8
15- Regulatory information
Label EEC:
Regulation 88 / 379
Hazard symbol:
C Corrosive
Risk Phrases :
R 21/22 Harmful by skin contact and if swallowed
R 34: Causes burns
R 43: May cause sensitization by skin contact
DM 06
E 1121.4
Rewiewed: 2002 September
Page 4 / 4
Safety Phrases:
S 26: In case of contact with eye, rinse immediatly with plenty of water and seek medical
advice
S 36/37/39: Wear suitable protective clothing, gloves, and eye face protection
S 38: In case the area is not well ventilated: mask with adequate filters
S 46 In case of accident or if you feel unwell, seek medical advice
S 61 Avoid release to the environment. Refer to special instructions / safety data sheets
16-Other information
Note:
The information herein is given in good faith and to the best of our knowledge but no warranty, express
or implied, is made. Since the use of this information and the conditions of use of the product are not
within our control, it is the user's obligation to determine the condition of safe use of the products.
NA: Not applicable ND: Not determined
Department issuing data specification sheet / Contact:
Tel: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 jean.pierre.gros@sicomin.com
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