Written by 鈥揓P GROS SDS : RA 011X/A
Technical Manager Edition : 1 - December 1998
Revision :
Page : 1/3
SAFETY DATA SHEET RA011X/A
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS If swallowed accidentally, call a doctor to assess the need for monitoring and subsequent treatment in hospital.
Preparation: Show him the label.
Diluent Wash Primer WP N掳1 5 - FIRE-FIGHTING MEASURES
Name:
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
Product code: 15 011 000 X - 51 011 000 X
In the event of fire, the recommended extinguishing agents are:
Company/business:
SICOMIN Special foams for polar liquids (known as alcohol resistant), powders, carbon dioxide.
Registered company name:
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Address: RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues France
Extinguishing agents not to be used
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool
composites@sicomin.com
containers exposed to the fire and to disperse fumes.
Emergency telephone No.: 01 45 42 59 59 . Association/Organisation: ORFILA.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
2 - INFORMATION REGARDING CONSTITUENTS Do not breathe in smoke.
Hazardous substances present on their own. Prevent the effluent of fire-fighting measures from entering drains or waterways.
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a Special equipment for fire-fighting personnel.
100% pure state) Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
601-021-00-3 TOLUENE Concentration >=10.00% and <25.00%. Symbol: Xn F R: 11-20-902 Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be
603-004-00-6 BUTANOL, EXCEPT TERT-BUTYL ALCOHOL Concentration >=25.00% and <50.00%. Symbol: equipped with autonomous insulating breathing apparatus.
Xn R: 10-20
6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
Other substances representing a hazard:
Safety precautions:
603-001-00-X METHANOL Concentration >=0.00% and <2.50%. Symbol: T F R: 11-23/25-901
Eliminate any possible source of ignition and ventilate the premises.
Substances present at a concentration below the minimum danger threshold.
Avoid inhaling the fumes.
No known substance in this category present.
Consult the safety measures listed under headings 7 and 8.
Other substances with occupational exposure limits.
Environmental safety precautions:
603-002-00-5 ETHANOL Concentration >=25.00% and <50.00%. Symbol: F R: 11
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite,
603-003-00-0 PROPYL AND ISOPROPYL ALCOHOL Concentration >=25.00% and <50.00%. Symbol: F R:
diatom earth in drums for waste disposal.
11
Prevent any material from entering drains or waterways.
3 - IDENTIFICATION OF HAZARDS Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
This product is classed: Highly flammable liquid. If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory
Possibility of acute, lethal, noxious effects with symptoms of slight poisoning by inhalation. procedures
4 - FIRST AID. Cleaning methods:
As a general rule, in case of doubt or if symptoms persist, always call a doctor. Clean preferably with a detergent, do not use solvents.
NEVER induce swallowing in an unconscious person. 7 - HANDLING AND STORAGE
In the event of exposure by inhalation. The regulations relating to storage premises apply to workshops where the product is handled.
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still. Handling:
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor. Handle in well-ventilated areas.
Do not give the patient anything orally. The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
In the event of splashes or contact with eyes. Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. the occupational exposure limits.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment. Fire prevention:
In the event of splashes or contact with skin. Prevent the accumulation of electrostatic charges with connections to earth
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic
DO NOT use solvents or thinners. shoes and clothes and make floors of conductive materials.
In the event of swallowing. Use the product in premises where there are no naked flames or other sources of ignition and have protected
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and electrical equipment
consult a doctor. Keep packages tightly closed and away from sources of heat, sparks and naked flames.
Keep still. DO NOT induce vomiting. Do not use tools which may produce sparks. Do not smoke.
Prevent access by unauthorised personnel.
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by 鈥揓P GROS SDS : RA 011X/A
Technical Manager Edition : 1 - December 1998
Revision :
Page : 2/3
Recommended equipment and procedures Density: <1
Observe precautions stated on label and also industrial safety regulations Acid/base character of preparation: neutral.
Packages which have been opened must be reclosed carefully and stored in an upright position Solubility of preparation in water: Insoluble.
Avoid inhaling fumes. Vapour tension at 50掳C of volatile constituents: Below 110Kpa (1.10 bar).
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation may be Physical state: fluid liquid
inadequate to control particles and solvent fumes in every case. Flash point interval: Flash point: <= 21掳C.
It is therefore recommended that personnel wear masks with a compressed air supply during spraying operations When a pH measure is possible, it has a value of: not stated.
until the concentration of particles and solvent fumes has fallen below the exposure limits. Self-ignition temperature: 365 掳C.
Prohibited equipment and procedures. Decomposition temperature: not relevant.
Smoking, eating and drinking are prohibited in premises where the preparation is used Melting temperature interval: -89 掳C.
Never open the packages under pressure Average distillation temperature of solvents contained: 80 掳C.
Storage. 10 - STABILITY AND REACTIVITY
Keep the container tightly closed in a dry, well-ventilated place When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon
Keep away from all sources of ignition - do not smoke. monoxide and dioxide, smoke and nitrogen oxide
Keep well away from all sources of ignition, heat and direct sunlight Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs,
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, the liquid furnaces etc.) must not be allowed on the premises.
cannot spread beyond this area. 11 - TOXICOLOGICAL INFORMATION
8 - EXPOSURE CONTROL - PERSONAL SAFETY No data is available regarding the preparation itself.
Technical measures. Splashes in the eyes may cause irritation and reversible damage
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction. 12 - ECOLOGICAL INFORMATION
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure limits, wear No ecological data on the product itself is available.
breathing apparatus The product must not be allowed to run into drains or waterways.
Exposure limits per INRS ND 1945-153-93/(1996) and ND 2022-163-96:
13 - DISPOSAL CONSIDERATIONS
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳:
Do not pour into drains or waterways.
601-021-00-3 100 375 150 550 - 4bis, 84
14 - TRANSPORT INFORMATION
603-001-00-X 200 260 1000 1300 - 84
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA
603-002-00-5 1000 1900 5000 9500 - 84
for air transport
603-003-00-0 - - 400 980 - 84
UN 1263 = Paint flammable (including lacquer, enamel, stain, shellac, varnish, polish and related material).
603-004-00-6 - - 50 150 - 84
ADR/RID Class Number Code Identif. Label
Germany Class: MAK-ppm: MAK-mg/m3: Notes: Notes:
3 5掳 b 33 1263 3
601-021-00-3 II,2 50 190 -
IMDG Page N掳ONU Class Number 2掳Label Identif. N掳GSMU
603-001-00-X II,1 200 260 *
1263 3.2 II - 3-07 -
603-002-00-5 IV 1000 1900 -
The page number 3230 should not appear anymore on the Dangerous Goods Declaration (Amendment 28-96).
603-003-00-0 II,1 400 980 -
IATA N掳ONU Class 2掳Label Number Passenger Passenger Freighter Freighter nota
603-004-00-6 P II,1 100 300 -
1263 3 - II 305 5L 307 60 L A3
ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-mg/m3: Notes: Notes:
1263 3 - II Y305 1L - - A7
601-021-00-3 50 188 - - *
15 - STATUTORY INFORMATION
603-001-00-X 200 262 250 328 *
This preparation was classified in compliance with the directive known as 88/379/EEC and its
603-002-00-5 1000 1880 - - -
adaptations
603-003-00-0 400 983 500 1230 -
In addition directive 96/54/EC with the 22掳 adaptation of directive 67/548/EEC (Hazardous substances) have been
603-004-00-6 50 152 - - *
taken into account.
Safety breathing apparatus:
Preparation classification.
With this preparation, avoid in particular any inhalation of fumes.
Harmful. Highly flammable.
Hand protection.
Contains:
Protective creams may be used for exposed skin, but they should not be applied after contact with the product.
601-021-00-3 TOLUENE
Due to the solvents present, it is recommended that neoprene rubber or nitrile rubber gloves be worn
603-001-00-X METHANOL
Eye and face protection.
603-004-00-6 BUTANOL, EXCEPT TERT-BUTYL ALCOHOL
Use eye protectors designed to protect against liquid splashes
Particular hazards associated with the preparation and safety recommendations:
Skin protection.
R 20 Harmful by inhalation.
For further information, see 搂 11 of S.D.S. - Toxicological information.
R 11 Highly flammable.
9 - PHYSICAL PROPERTIES
S 23 Do not breathe vapour.
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
Written by 鈥揓P GROS SDS : RA 011X/A
Technical Manager Edition : 1 - December 1998
Revision :
Page : 3/3
S 33 Take precautionary measures against static discharges.
S 16 Keep away from sources of ignition - no smoking.
S9 Keep container in a well-ventilated place.
S 29 Do not empty into drains.
16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based
on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining
written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and
local regulations.
The information given on this safety data sheet must be regarded as a description of the safety requirements relating
to our product and not a guarantee of its properties
S I C O M I N RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.04.42.42.30.20 Fax: 33.04.42.81.29.29 composites@sicomin.com
|