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R茅vision n掳10 /06/08/2002 Version n掳1 06/08/2002
SAFETY DATA SHEET
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS
Preparation:
Name: EPODUX PRIMER 61-134 DURCISSEUR.
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Product code: H609D.
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Company/business:
Registered company name: MAESTRIA PEINTURES.
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Address: RUE DENIS PAPIN ZI DU PIC .09100.PAMIERS.FRANCE.
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Telephone: 05 61 67 97 40. Fax:05 61 67 05 47. Telex:.
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Emergency telephone No.: 01 45 42 59 59.
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Association/Organisation: ORFILA.
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2 - INFORMATION REGARDING CONSTITUENTS
Hazardous substances present on their own.
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it
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would have in a 100% pure state)
601-022-00-9 Cas 1330-20-7 EEC 215-535-7 O-XYLENE Concentration >=25.00% and <50.00%.
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Symbol: Xn R: 10-38-20/21
Other substances representing a hazard:
612-059-00-5 Cas 112-24-3 EEC 203-950-6 3,6-DIAZAOCTANETHYLENEDIAMIN Concentration
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>=2.50% and <10.00%. Symbol: C R: 34-43-52/53-21
Substances present at a concentration below the minimum danger threshold.
603-069-00-0 Cas 90-72-2 EEC 202-013-9 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
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Concentration >=2.50% and <10.00%. Symbol: Xn R: 22-36/38
Other substances with occupational exposure limits.
No known substance in this category present.
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3 - IDENTIFICATION OF HAZARDS
This product is classed: Flammable.
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Possibility of irritation to the skin.
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Possibility of skin sensitisation. The preparation may also irritate the skin and prolonged contact may
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aggravate this effect.
Possibility of noxious effects with symptoms of slight poisoning by inhalation and contact with the
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skin.
4 - FIRST AID.
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
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NEVER induce swallowing in an unconscious person.
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In the event of exposure by inhalation.
If a large quantity is inhaled, move the patient into the fresh air and keep him/her warm and still.
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If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
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Do not give the patient anything orally.
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In the event of splashes or contact with eyes.
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
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Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
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In the event of splashes or contact with skin.
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised
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cleaner.
DO NOT use solvents or thinners.
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If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted
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or the patient transferred to hospital
In the event of swallowing.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with
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water and consult a doctor.
Call a doctor immediately and show him the label.
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N/A !
5 - FIRE-FIGHTING MEASURES
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
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In the event of fire, the recommended extinguishing agents are:
Carbon dioxide, chemical powders, foams, and other extinguishing gases.
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In the event of fire, use specifically suitable extinguishing agents. Never use water.
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Extinguishing agents not to be used
Water is not generally recommended since it can be ineffective; however, it can be used successfully to
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cool containers exposed to the fire and to disperse fumes.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous
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to health.
Do not breathe in smoke.
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Prevent the effluent of fire-fighting measures from entering drains or waterways.
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Special equipment for fire-fighting personnel.
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
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6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
Safety precautions:
Eliminate any possible source of ignition and ventilate the premises.
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On account of the organic solvents contained in the preparation, eliminate sources of ignition and
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ventilate the premises.
Avoid inhaling the fumes.
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Avoid any contact with the skin and eyes.
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Consult the safety measures listed under headings 7 and 8.
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Environmental safety precautions:
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth,
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vermiculite, diatom earth in drums for waste disposal.
Prevent any material from entering drains or waterways.
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Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
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If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance
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with statutory procedures
Cleaning methods:
Clean preferably with a detergent, do not use solvents.
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7 - HANDLING AND STORAGE
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The regulations relating to storage premises apply to workshops where the product is handled.
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Anyone with a history of skin sensitisation must on no account handle such products
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Handling:
Handle in well-ventilated areas.
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The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
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Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations
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higher than the occupational exposure limits.
Fire prevention:
Prevent the accumulation of electrostatic charges with connections to earth
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The preparation may become electrostatically charged; always place on the ground during transfer.
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Wear antistatic shoes and clothes and make floors of conductive materials.
Use the product in premises where there are no naked flames or other sources of ignition and have
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protected electrical equipment
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
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Do not use tools which may produce sparks. Do not smoke.
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Prevent access by unauthorised personnel.
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Recommended equipment and procedures
For personal safety, see 搂8.
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Observe precautions stated on label and also industrial safety regulations
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Avoid inhaling solvent fumes and spray-gun aerosols
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Packages which have been opened must be reclosed carefully and stored in an upright position
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Avoid inhaling fumes.
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Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation
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may be inadequate to control particles and solvent fumes in every case.
It is therefore recommended that personnel wear masks with a compressed air supply during spraying
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operations until the concentration of particles and solvent fumes has fallen below the exposure limits.
Avoid contact of product with the skin and eyes
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Prohibited equipment and procedures.
Smoking, eating and drinking are prohibited in premises where the preparation is used
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Never open the packages under pressure
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Storage.
Keep the container tightly closed in a dry, well-ventilated place
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Keep away from all sources of ignition - do not smoke.
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Keep well away from all sources of ignition, heat and direct sunlight
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The floor must be impermeable and form a collecting basin so that, in the event of an accidental
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spillage, the liquid cannot spread beyond this area.
8 - EXPOSURE CONTROL - PERSONAL SAFETY
Anyone with a history of skin sensitisation must on no account handle such products.
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Technical measures.
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general
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extraction.
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure
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limits, wear breathing apparatus
Exposure limits per INRS ND 2098-174-99 and ND 2114-176-99:
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France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳:
601-022-00-9 100 435 150 650 - 4bis, 84
Germany Class: MAK-ppm: MAK-mg/m3: Notes: Notes:
601-022-00-9 II,1 100 440 D,*
ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-mg/m3: Notes: Notes:
601-022-00-9 100 434 150 651 A4 S
Exposure limits per 2000/39/EC and 98/24/EC:
VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes:
601-022-00-9 50 221 100 442 Peau
Safety breathing apparatus:
With this preparation, avoid in particular any inhalation of fumes.
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Hand protection.
Protective creams may be used for exposed skin, but they should not be applied after contact with the
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product.
Due to the solvents present, it is recommended that polyvinyl alcohol or nitrile rubber gloves be worn.
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Eye and face protection.
Avoid contact with the skin and eyes. Wear safety goggles
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Provide eye washes in workshops where the product is constantly handled
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Skin protection.
For further information, see 搂 11 of S.D.S. - Toxicological information.
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9 - PHYSICAL PROPERTIES
Density: >1
Acid/base character of preparation: neutral.
Solubility of preparation in water: Insoluble.
Vapour tension at 50掳C of volatile constituents: Below 110 kPa (1.10 bar).
Physical state: viscous liquid
Flash point interval: 23掳C. < Flash point: <= 55掳C.
When a pH measure is possible, it has a value of: not stated.
Self-ignition temperature: not specified.
Decomposition temperature: not specified.
Melting temperature interval: not specified.
Average distillation temperature of solvents contained: not specified.
10 - STABILITY AND REACTIVITY
When exposed to high temperatures, the preparation may release dangerous decomposition products
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such as carbon monoxide and dioxide, smoke and nitrogen oxide
11 - TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
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Exposure to fumes from solvents contained in the preparation beyond the exposure limits stated may
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produce effects harmful to health, such as:
Irritation of mucous membrane and respiratory system, kidneys, liver and central nervous system.
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Symptoms produced will include headaches, numbness, dizziness, fatigue, muscular asthenia and, in
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extreme cases, loss of consciousness.
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Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause
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non-allergic dermatitis on contact and absorption through the epidermis.
Splashes in the eyes may cause irritation and reversible damage
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It is generally agreed that substances contained are likely to cause significant irritation which lasts for
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at least twenty four hours after application to the healthy, unbroken skin of an animal for a period of up
to 4 hours.
It is generally agreed that substances contained are likely to cause, among certain predisposed subjects,
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a sensitisation reaction by cutaneous route
12 - ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
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The product must not be allowed to run into drains or waterways.
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13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
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14 - TRANSPORT INFORMATION
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and
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ICAO/IATA for air transport
UN 1263 = Paint flammable (including lacquer, enamel, stain, shellac, varnish, polish and related
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material).
ADR/RID Class Number Code Identif. Label
Not subject to this regulation (Q < 450 l).
Transport following Nota E of the 2301
marginal.
3 31掳 c) 30 1263 3
N掳 2掳 N掳
IMDG Page Class Number Identif.
ONU Label GSMU
1263 3.3 III - 3-05 310,313
The page number 3372 should not appear anymore on the Dangerous Goods Declaration
(Amendment 28-96).
IATA N掳ONU Class 2掳Label Number Passenger Passenger Freighter Freighter nota
1263 3 - III 309 60 L 310 220 L A72
1263 3 - III Y309 10 L - - -
15 - STATUTORY INFORMATION
This preparation was classified in compliance with the directive known as
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1999/45/EC and its adaptations
In addition directive 2001/59/EC with the 28掳 adaptation of directive 67/548/EC (Hazardous
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substances) have been taken into account.
Preparation classification.
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Harmful. Flammable.
Contains:
601-022-00-9 O-XYLENE
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612-059-00-5 3,6-DIAZAOCTANETHYLENEDIAMIN
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Particular hazards associated with the preparation and safety recommendations:
R 43 May cause sensitization by skin contact.
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R 38 Irritating to skin.
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R 20/21 Harmful by inhalation and in contact with skin.
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R 10 Flammable.
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S 23 Do not breathe vapour.
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S 36/37 Wear suitable protective clothing and gloves.
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S 25 Avoid contact with eyes.
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S 60 This material and/or its container must be disposed of as hazardous waste.
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S 9 Keep container in a well-ventilated place.
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16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data
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sheet is based on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first
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obtaining written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal
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requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety
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requirements relating to our product and not a guarantee of its properties
- Conform茅ment 脿 licence d'exploitation de la proc茅dure InfoDyne toute revente de cette FDS 脿 un tiers est interdite -
(漏)InfoDyne 2001
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