Written by 鈥揓P GROS SDS : RA 011X/A
Technical Manager Version: December 2001
Page : 1/2
SAFETY DATA SHEET RA011X/A
1 - IDENTIFICATION OF PREPARATION AND COMPANY/BUSINESS Special equipment for fire-fighting personnel.
Preparation: Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped
Diluent n掳6
Name:
with autonomous insulating breathing apparatus.
Deck Line and Full Grip鈥檚 Diluent
Company/business:
SICOMIN 6 - MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL SPILLAGE
Registered company name:
Safety precautions:
Address: RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues France
Eliminate any possible source of ignition and ventilate the premises.
Phone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 Mail: composites@sicomin.com
Avoid inhaling the fumes.
Consult the safety measures listed under headings 7 and 8.
2 - INFORMATION REGARDING CONSTITUENTS Environmental safety precautions:
Hazardous substances present on their own. Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatom
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% earth in drums for waste disposal.
pure state) Prevent any material from entering drains or waterways.
Methylethyl Ketone (MEK) cas n掳 78-93-3 Concentration > 90 % by weight Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
Symbol: Xi Irritating F : Hightly flammable liquid If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory
Risk phrases: R 11 R 36 R 66 R 67 procedures
Cleaning methods:
3 - IDENTIFICATION OF HAZARDS Clean preferably with a detergent, do not use solvents.
This product is classed: Highly flammable liquid.
7 - HANDLING AND STORAGE
4 - FIRST AID. The regulations relating to storage premises apply to workshops where the product is handled.
As a general rule, in case of doubt or if symptoms persist, always call a doctor. Handling:
NEVER induce swallowing in an unconscious person. Handle in well-ventilated areas.
In the event of exposure by inhalation. The fumes are denser than air. They can spread along the ground and form explosive mixtures with air
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still. Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than the
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor. occupational exposure limits.
Do not give the patient anything orally. Fire prevention:
In the event of splashes or contact with eyes. Prevent the accumulation of electrostatic charges with connections to earth
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic shoes
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment. and clothes and make floors of conductive materials.
In the event of splashes or contact with skin. Use the product in premises where there are no naked flames or other sources of ignition and have protected electrical
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. equipment
DO NOT use solvents or thinners. Keep packages tightly closed and away from sources of heat, sparks and naked flames.
In the event of swallowing. Do not use tools which may produce sparks. Do not smoke.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a Prevent access by unauthorised personnel.
doctor. Recommended equipment and procedures
Keep still. DO NOT induce vomiting. Observe precautions stated on label and also industrial safety regulations
If swallowed accidentally, call a doctor to assess the need for monitoring and subsequent treatment in hospital. Show him Packages which have been opened must be reclosed carefully and stored in an upright position
the label. Avoid inhaling fumes.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation may be inadequate
to control particles and solvent fumes in every case.
5 - FIRE-FIGHTING MEASURES
It is therefore recommended that personnel wear masks with a compressed air supply during spraying operations until the
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
concentration of particles and solvent fumes has fallen below the exposure limits.
In the event of fire, the recommended extinguishing agents are:
Prohibited equipment and procedures.
Special foams for polar liquids (known as alcohol resistant), powders, carbon dioxide.
Smoking, eating and drinking are prohibited in premises where the preparation is used
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Never open the packages under pressure
Extinguishing agents not to be used
Storage.
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool containers
Keep the container tightly closed in a dry, well-ventilated place
exposed to the fire and to disperse fumes.
Keep away from all sources of ignition - do not smoke.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Keep well away from all sources of ignition, heat and direct sunlight
Do not breathe in smoke.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
SICOMIN RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 Mail: composites@sicomin.com
Written by 鈥揓P GROS SDS : RA 011X/A
Technical Manager Version: December 2001
Page : 2/2
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, the liquid cannot Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air
spread beyond this area. transport
UN 1263 = Paint flammable (including lacquer, enamel, stain, shellac, varnish, polish and related material).
ADR/RID Class Number Code Label Identif.
8 - EXPOSURE CONTROL - PERSONAL SAFETY
3 3掳b 33 3 1193
Technical measures.
IMDG Page Class Group Identif. N掳GSMU Marine pollutant
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction.
3226 3.2 II 3-06 300 no
If this ventilation is insufficient to maintain the concentration of solvent fumes below the exposure limits, wear breathing
apparatus
IATA Class group Label
Exposure limits per INRS (nd 1945-153鈥?93 et 2022-163-96
3.1 II 3
VME-ppm: VME-mg/m3: TWA-ppm: TWA-mg/m3: STEL ppm STEL mg/m3
200 600 200 590 300 885
Safety breathing apparatus: 15 - STATUTORY INFORMATION
With this preparation, avoid in particular any inhalation of fumes. This preparation was classified in compliance with the directive known as 88/379/EEC and its
Hand protection. adaptations
Protective creams may be used for exposed skin, but they should not be applied after contact with the product. In addition directive 98/98/EC with the 25掳 adaptation of directive 67/548/EEC (Hazardous substances) have been taken
Due to the solvents present, it is recommended that neoprene rubber or nitrile rubber gloves be worn into account.
Eye and face protection. Preparation classification.
Use eye protectors designed to protect against liquid splashes Harmful. Irritant - Highly flammable.
Skin protection. Contains: Methyl Ethyl Ketone (MEK)
For further information, see 搂 11 of S.D.S. - Toxicological information.
Particular hazards associated with the preparation and safety recommendations:
R 11 Highly flammable.
9 - PHYSICAL PROPERTIES
R 36 Irritating to eyes
Density: 0.805
R 66 Repeated exposure may cause skin dryness or cracking
Color: clear
R 67 Vapours may cause drowsiness and dizziness
Acid/base character of preparation: na
Solubility of preparation in water: 270 g/l
S 23 Do not breathe vapour.
Vapour tension of volatile constituents: 110 kPa (@60掳C)), 13.3 kPa (@25掳C)
S 33 Take precautionary measures against static discharges.
Physical state: Liquid
S 16 Keep away from sources of ignition - no smoking.
Flash point interval: - 9掳C
S9 Keep container in a well-ventilated place.
When a pH measure is possible, it has a value of: not stated
S 51 Use only in well ventilated areas
Self-ignition temperature: 515 掳C
Decomposition temperature: not relevant
Melting temperature interval: - 86 掳C 16 - OTHER INFORMATION
Average distillation temperature of solvents contained: 80 掳C Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our
current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining written
10 - STABILITY AND REACTIVITY
handling instructions.
When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local
monoxide and dioxide, smoke
regulations.
Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces
The information given on this safety data sheet must be regarded as a description of the safety requirements relating to our
etc.) must not be allowed on the premises.
product and not a guarantee of its properties
11 - TOXICOLOGICAL INFORMATION
LD 50 rat ingestion: 2800 - 5600 mg/kg
LD 50 rabbit skin: 5000 - 13000 mg/kg
CL 50 (rat, 4h) inhalation = 11700 ppm (34.5 mg/l)
Splashes in the eyes may cause irritation and reversible damage
12 - ECOLOGICAL INFORMATION
Fish CL 50 (96 h) > 3000 mg /l Daphnia CE 50 (48h) = 1382 mg/l
The product must not be allowed to run into drains or waterways.
13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
14 - TRANSPORT INFORMATION
SICOMIN RN 568 BP 23 13 161 Ch芒teauneuf-les-Martigues c茅dex France
Telephone: 33.(0)4.42.42.30.20 Fax: 33.(0)4.42.81.29.29 Mail: composites@sicomin.com
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