1 - IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation:
EPOXYTAR EP 200 BASE.
Name:
Product code: H 1691 B.
Company/undertaking identification:
Registered company name: MAP YACHTING.
Address : ZI ATHELIA IV 鈥? 296 Av de la Tramontane 鈥? 13705 LA CIOTAT - France.
Telephone : 33 (0)4 42 98 14 50 Fax :33 (0)4 42 98 14 51. Email : sales@map-yachting.com
Emergency telephone: 01 45 42 59 59.
Association/Organisation: ORFILA.
Use of the substance/preparation:
2 - COMPOSITION/INFORMATION ON INGREDIENTS
Full text of risk phrases appearing in section 2: see section 16.
Hazardous substances present on their own:
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% pure state)
INDEX CAS EC Name Symb. R: %
648-055-00-5 65996-93-2 266-028-2 PITCH, COAL TER, HIGH-TEMP. T 45.C2 10 <= x % < 25
M 00355 90640-84-9 292-605-3 BENZOLE ABSORBING OIL T 45.C2 36/38 65 2.5 <= x % < 10
M 00356 90640-86-1 292-607-4 BASE OIL T 45.C2 46.M2 60.F2 61.G2 2.5 <= x % < 10
Other substances representing a hazard:
INDEX CAS EC Name Symb. R: %
601-022-00-9 1330-20-7 215-535-7 O-XYLENE Xn 10 38 20/21 10 <= x % < 25
M 00036 68410-23-1 POLYAMINOAMIDE Xi 41 2.5 <= x % < 10
Substances present at a concentration below the minimum danger threshold:
INDEX CAS EC Name Symb. R: %
601-025-00-5 108-67-8 203-604-4 MESITYLENE Xi N 10 37 51/53 0 <= x % < 2.5
601-043-00-3 95-63-6 202-436-9 1,2,4-TRIMETHYLBENZENE Xn N 10 36/37/38 51/53 20 0 <= x % < 2.5
M 00129 64742-95-6 265-199-0 SOLVANT NAPHTE AROMATIQUE LEGER (PETROLE) Xn 65 66 67 0
<= x % < 2.5
M 00147 64742-82-1 265-185-4 NAPHTA LOURD (PETROLE), HYDROD脡SULFURE Xn N 10 51/53 65 66 67
0 <= x % < 2.5
Other substances with occupational exposure limits:
No known substance in this category present.
Other components:
May produce an allergic reaction:
INDEX CAS EC Name Symb. R: %
612-060-00-0 112-57-2 203-986-2 3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE CN 34 43 51/53 21/22 0 <= x % <
2.5
3 - IDENTIFICATION OF HAZARDS
This product is classed: Flammable.
Possibility of irritation to the eyes.
Possibility of category two carcinogenic effects.
Possibility of category two mutagenic effects.
Possibility of category two toxic effects on reproduction.
Possibility of noxious effects with symptoms of slight poisoning by inhalation and contact with the skin.
May impair fertility.
May cause harm to the unborn child.
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May produce an allergic reaction.
Other data:
4 - FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing in an unconscious person.
In the event of exposure by inhalation:
If a large quantity is inhaled, move the patient into the fresh air and keep him/her warm and still.
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
Do not give the patient anything orally.
In the event of splashes or contact with eyes:
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment.
Regardless of the initial state, refer the patient to an ophthalmologist and show him the label.
In the event of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
DO NOT use solvents or thinners.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital
In the event of swallowing:
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.
Call a doctor immediately and show him the label.
Specific and immediate treatment:
Information for the doctor:
5 - FIRE-FIGHTING MEASURES
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
Suitable extinguishing media:
Carbon dioxide, chemical powders, foams, and other extinguishing gases.
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Extinguishing media which must not be used for safety reasons:
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool containers exposed to the fire and to
disperse fumes.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
Prevent the effluent of fire-fighting measures from entering drains or waterways.
Special protective equipment for fire-fighters:
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
On account of the organic solvents contained in the preparation, eliminate sources of ignition and ventilate the premises.
Avoid inhaling the vapors.
Avoid any contact with the skin and eyes.
Consult the safety measures listed under headings 7 and 8.
Environmental precautions:
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for
waste disposal.
Prevent any material from entering drains or waterways.
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
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If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures
Methods for cleaning up:
Clean preferably with a detergent, do not use solvents.
7 - HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
Avoid exposure to pregnant women and warn women of child-bearing age of the possible risks
Handling:
Handle in well-ventilated areas.
The vapors are denser than air. They can spread along the ground and form explosive mixtures with air
Prevent the formation of flammable or explosive concentrations in air and avoid vapor concentrations higher than the occupational exposure limits.
Fire prevention:
Prevent the accumulation of electrostatic charges with connections to earth
The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic shoes and clothes and make
floors of conductive materials.
Use the product in premises where there are no naked flames or other sources of ignition and have protected electrical equipment
Keep packages tightly closed and away from sources of heat, sparks and naked flames.
Do not use tools which may produce sparks. Do not smoke.
Prevent access by unauthorised personnel.
Recommended equipment and procedures:
For personal safety, see 搂8.
Observe precautions stated on label and also industrial safety regulations
Avoid inhaling solvent vapors and spray-gun aerosols
Avoid exposure - obtain special instructions before use.
Packages which have been opened must be reclosed carefully and stored in an upright position
Avoid inhaling vapors.
Where the personnel must carry out work in a booth, whether for spraying or otherwise, the ventilation may be inadequate to control particles and
solvent vapors in every case.
It is therefore recommended that personnel wear masks with a compressed air supply during spraying operations until the concentration of
particles and solvent vapors has fallen below the exposure limits.
In the case of paints, also avoid inhaling dust, particles and fumes during treatment of surfaces coated with this preparation by dry sand blasting or
by heating operations (welding, soldering, cutting etc.)
Avoid contact of product with the skin and eyes
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the preparation is used
Never open the packages under pressure
Storage:
Keep the container tightly closed in a dry, well-ventilated place
Keep away from all sources of ignition - do not smoke.
Keep well away from all sources of ignition, heat and direct sunlight
The floor must be impermeable and form a collecting basin so that, in the event of an accidental spillage, the liquid cannot spread beyond this
area.
Specific use(s):
8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Use personal protection equipment as per Directive 89/686/EEC.
Technical measures:
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction.
If this ventilation is insufficient to maintain the concentration of solvent vapors below the exposure limits, wear breathing apparatus
Exposure limit values per INRS ND 2098-174-99 and ND 2114-176-99:
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N掳:
65996-93-2 - 0,2 - - C2 16,16bis
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95-63-6 20 100 - - - 84 -
108-67-8 20 100 - - - 84 -
1330-20-7 50 221 100 442 * 4 bis, 84 -
Exposure limit values per 2000/39/EC and 98/24/EC:
EC VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes:
95-63-6 20 100 - - -
108-67-8 20 100 - - -
1330-20-7 50 221 100 442 Peau
Exposure limit values (2003):
UK/OES TWA: STEL: Ceiling: Definition: Criterion:
95-63-6 25 ppm - - - -
108-67-8 25 ppm - - - -
1330-20-7 50 ppm 100 ppm - - -
ACGIH/TLV TWA: STEL: Ceiling: Definition: Criterion:
65996-93-2 0.2 mg/m3 - - - -
95-63-6 25 ppm - - - -
108-67-8 25 ppm - - - -
1330-20-7 100 ppm - - - -
Germany/MAK TWA: STEL: Ceiling: Definition: Criterion:
95-63-6 20 ppm 40 ppm - - -
108-67-8 20 ppm 40 ppm - - -
1330-20-7 100 ppm 200 ppm - - -
Respiratory protection:
With this preparation, avoid in particular any inhalation of vapors.
Hand protection:
Protective creams may be used for exposed skin, but they should not be applied after contact with the product.
Due to the solvents present, it is recommended that polyvinyl alcohol or nitrile rubber gloves be worn.
Eye and face protection:
Avoid contact with eyes.
Wear safety goggles.
Provide eye washes in workshops where the product is constantly handled
Skin protection:
For further information, see 搂 11 of S.D.S. - Toxicological information.
Environmental exposure controls:
9 - PHYSICAL AND CHEMICAL PROPERTIES
General information:
Physical state: viscous liquid
Important health, safety and environmental information:
pH of the substance or preparation: not relevant.
The pH is impossible to measure or its value is not relevant.
Boiling point/boiling range: not specified.
Flash point interval: 23掳C. < Flash point: <= 55掳C.
vapour pressure: Below 110 kPa (1.10 bar).
Density: >1
water solubility: Insoluble.
Other information:
melting point/melting range: not specified.
Self-ignition temperature: not specified.
Decomposition point/decomposition range : not specified.
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10 - STABILITY AND REACTIVITY
When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon monoxide and dioxide,
smoke and nitrogen oxide
Conditions to avoid:
Materials to avoid:
Hazardous decomposition products:
11 - TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
Exposure to vapors from solvents contained in the preparation beyond the exposure limits stated may produce effects harmful to health, such as:
Irritation of mucous membrane and respiratory system, kidneys, liver and central nervous system.
Symptoms produced will include headaches, numbness, dizziness, fatigue, muscular asthenia and, in extreme cases, loss of consciousness.
Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause non-allergic dermatitis on contact and
absorption through the epidermis.
Splashes in the eyes may cause irritation and reversible damage
It is generally agreed that substances contained are likely to cause, when applied to the eye of an animal, the appearance of major lesions which
persist for at least twenty-four hours
It is generally agreed that substances contained are likely to cause category 2 carcinogenic effects.
It is generally agreed that substances contained are likely to cause category 2 mutagenic effects.
It is generally agreed that substances contained are likely to cause category 2 teratogenic effects.
In the event of exposure by inhalation:
In the event of swallowing:
In the event of splashes or contact with skin:
In the event of splashes or contact with eyes:
Other data:
12 - ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
The product must not be allowed to run into drains or waterways.
Mobility:
Persistence and degradability:
Bioaccumulative potential:
Ecotoxicity:
Other adverse effects:
13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
Waste:
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
Local arrangements:
Codes of wastes (Decision 2001/573/EC, Directive 75/442/EEC, Directive 91/689/EEC on hazardous waste) :
14 - TRANSPORT INFORMATION
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2005 - IMDG
2004 - ICAO/IATA 2005).
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UN1263=PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED
MATERIAL (including paint thinning and reducing compound)
ADR/RID Class Code Pack gr. Label Ident. LQ Provis.
3 F1 III 3 30 LQ7 163-650-640E
Not subject to this regulation if Q < 450l.
IMDG Class 2掳Label Pack gr. LQ EMS Provis.
3 - III 5L F-E,S-E 163 223 944 955
Not subject to this regulation if Q < 30l
IATA Class 2掳Label Pack gr. Passager Passager Cargo Cargo note
3 - III 309 60 L 310 220 L A3 A72
3 - III Y309 10 L - - -
15 - STATUTORY INFORMATION
This preparation was classified in compliance with the directive known as 1999/45/EC and its adaptations
In addition directive 2004/73/EC with the 29掳 adaptation of directive 67/548/EEC (Hazardous substances) have been taken into account.
Preparation classification:
Toxic. Flammable.
Contains:
601-022-00-9 O-XYLENE
Contains 612-060-00-0 3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE. May produce an allergic reaction.
648-055-00-5 PITCH, COAL TER, HIGH-TEMP.
M 00355 BENZOLE ABSORBING OIL
M 00356 BASE OIL
Particular hazards associated with the preparation and safety recommendations:
R 36 Irritating to eyes.
R 20/21 Harmful by inhalation and in contact with skin.
R 10 Flammable.
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 60 May impair fertility.
R 61 May cause harm to the unborn child.
For professional use only.
S 23 Do not breathe vapour.
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
Product not to be sold to the general public.
Particular provisions:
Product not to be sold to the general public. (Dir 94/60/EC) - For professional use only.
Attention - Avoid exposure - obtain special instructions before use.
16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety requirements relating to our product and not a
guarantee of its properties
Full text of risk phrases appearing in section 2:
R 10 Flammable.
R 20 Harmful by inhalation.
R 20/21 Harmful by inhalation and in contact with skin.
R 21/22 Harmful in contact with skin and if swallowed.
R 34 Causes burns.
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R 36/37/38 Irritating to eyes, respiratory system and skin.
R 36/38 Irritating to eyes and skin.
R 37 Irritating to respiratory system.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitization by skin contact.
R 45.C2 May cause cancer.
R 46.M2 May cause heritable genetic damage.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 60.F2 May impair fertility.
R 61.G2 May cause harm to the unborn child.
R 65 Harmful. may cause lung damage if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
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