VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 (REVISION A) CD 2002/3 Page 1 of 11
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
STATEMENT OF HAZARDOUS NATURE
Not considered a dangerous substance according to directive
67/548/EEC, point
4; and not hazardous according to OSHA 29 CFR 1910.1200
(USA).
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company: Virbac (Australia) Pty Ltd Company: Virbac (Australia) Pty Ltd ABN: 77 003 268 871
Address: Address:
Locked Bag 1000 15 Pritchard Place
Peakhurst Delivery Centre Peakhurst
NSW NSW
Australia Australia
Telephone: (+61 2) 9717 2000 Telephone: (+61 2) 9533 2000
Fax: (+61 2) 9533 1522 Fax: (+61 2) 9533 1522
HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
PRODUCT USE
Oral anthelmintic drench for sheep and cattle.
SYNONYMS
Product Code: FEN10010; FEN10005; FEN10001.
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME R CODE INT HAZ %
fenbendazole None None 1-10
additives unregulated 1-10
water None None >60
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 2 of 11
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified
under EC Directives), the material may still be damaging to the health of the
individual, following ingestion, especially where pre-existing organ (e.g
liver, kidney) damage is evident. Present definitions of harmful or toxic
substances are generally based on doses producing mortality rather than those
producing morbidity (disease, ill-health). Gastrointestinal tract discomfort
may produce nausea and vomiting. In an occupational setting however, ingestion
of insignificant quantities is not thought to be cause for concern.
EYE
Although the material is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient discomfort
characterised by tearing or conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin
irritation following contact (as classified by EC Directives using animal
models). Nevertheless, good hygiene practice requires that exposure be kept to
a minimum and that suitable gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Primary route of exposure is usually by skin contact
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
Section 4 - FIRST AID MEASURES
SWALLOWED
DO NOT induce vomiting. If vomiting occurs, lean patient forward or place on
left side (head-down position, if possible) to maintain open airway and prevent
aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
Give water (or milk) to rinse out mouth, then provide liquid slowly and as much
as casualty can comfortably drink.
Seek medical advice.
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 3 of 11
Section 4 - FIRST AID MEASURES ...
EYE
If this product comes in contact with the eyes:
Immediately hold the eyes open and wash with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
If pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If product comes in contact with the skin:
Immediately remove all contaminated clothing, including footwear
Wash affected areas thoroughly with water (and soap if available).
Seek medical attention in event of irritation.
INHALED
If fumes or combustion products are inhaled: Remove to fresh air.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures
If breathing is shallow or has stopped, ensure clear airway and apply
resuscitation, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
There is no restriction on the type of extinguisher which may be used.
FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves for fire only.
Prevent, by any means available, spillage from entering drains or water
courses.
Use fire fighting procedures suitable for surrounding area.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of
containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 4 of 11
Section 5 - FIRE FIGHTING MEASURES ...
Decomposes on heating and produces toxic fumes of carbon dioxide (CO2) , sulfur
dioxide (SO2) and nitrogen oxides (NOx)
FIRE INCOMPATIBILITY
None known
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact by using protective equipment as required.
Prevent spillage from entering drains or water ways.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
Wash area and prevent runoff into drains or waterways.
If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
direction distance
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance -
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 5 of 11
Section 6 - ACCIDENTAL RELEASE MEASURES ...
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide No guide found. is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately.
Use good occupational work practice.
Observe manufacturer's storing and handling recommendations.
Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
SUITABLE CONTAINER
Plastic container (10 L jerry can, 5 L backpack, 1 L jerry can)
Check that containers are clearly labelled
Packaging as recommended by manufacturer.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.
Store below 30 deg. C.
DO NOT allow product to freeze
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 6 of 11
Section 7 - HANDLING AND STORAGE ...
Store away from foodstuff containers.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
None assigned. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :3 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be over
overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
fenbendazole 3 10 0
INGREDIENT DATA
FENBENDAZOLE:
TLV TWA: 10 mg/m鲁 (Value for particulate matter containing no asbestos and <1% crystalline
silica,Inhalable fraction) [ACGIH]
TLV TWA: 3 mg/m鲁 (Value for particulate matter containing no asbestos and <1% crystalline
silica,Respirable fraction) [ACGIH]
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁
Particulate (insoluble or poorly soluble *) Not .Otherwise Specified (P.N.O.C)
TLV TWA: 10 mg/m鲁 Inhalable particulate
TLV TWA: 3 mg/m鲁 Respirable particulate
OEL-Sweden, United Kingdom: 10 mg/m鲁 total dust, 5 mg/m鲁 respirable dust
These "dusts" have little adverse effect on the lungs and do not produce toxic
effects or organic disease. Although there is no dust which does not evoke some
cellular response at sufficiently high concentrations, the cellular response
caused by P.N.O.C.s has the following characteristics:
the architecture of the air spaces remain intact,
scar tissue (collagen) is not synthesised to any degree,
tissue reaction is potentially reversible.
Extensive concentrations of P.N.O.C.s may:
seriously reduce visibility,
cause unpleasant deposits in the eyes, ears and nasal passages,
contribute to skin or mucous membrane injury by chemical or mechanical action,
per se, or by the rigorous skin cleansing procedures necessary for their
removal. [ACGIH]
This limit does not apply:
to brief exposures to higher concentrations
nor does it apply to those substances that may cause physiological impairment
at lower concentrations but for which a TLV has as yet to be determined.
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 7 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
This exposure standard applies to particles which
are insoluble or poorly soluble* in water (or, preferably, in aqueous lung
fluid (if data is available) and
have a low toxicity (i.e.. are not cytotoxic, genotoxic, or otherwise
chemically reactive with lung tissue, and do not emit ionizing radiation, cause
immune sensitization, or cause toxic effects other than by inflammation or by a
mechanism of lung overload)
* Notice of intended change
WATER:
No exposure limits set by NOHSC or ACGIH
PERSONAL PROTECTION
EYE
Safety glasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear.
OTHER
Overalls.
Barrier cream
Eyewash unit.
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
water
BUTYL A
NEOPRENE A
VITON A
PVA C
NATURAL RUBBER C
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 8 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a
choice of gloves which might otherwise be unsuitable following long-term or
frequent use. A qualified practitioner should be consulted.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Half-face Full-Face
Level ppm Protection Factor Respirator Respirator
(volume)
1000 10 -AUS P -
1000 50 - -AUS P
5000 50 Airline * -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in 1-2.5 m/s (200-500 f/min)
shallow booths, drum filling, conveyer
loading, crusher dusts, gas discharge
(active generation into zone of rapid
air motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity
into zone of very high rapid air
motion).
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 9 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.)
for extraction of solvents generated in a tank 2 meters distant from the
extraction point. Other mechanical considerations, producing performance
deficits within the extraction apparatus, make it essential that theoretical
air velocities are multiplied by factors of 10 or more when extraction systems
are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not applicable Vapour Pressure (kPa): Not available
Boiling Range (掳C): Not available Volatile Component (%vol): Not available
Melting Range (掳C): Not available Relative Vapour Density (air=1): Not available
Specific Gravity (water=1): 1.01-1.03 Flash Point (掳C): Not applicable
Solubility in water (g/L): Miscible Lower Explosive Limit (%): Not applicable
pH (as supplied): 4.0-4.5 Upper Explosive Limit (%): Not applicable
pH (1% solution): Not available Autoignition Temp (掳C): Not applicable
Evaporation Rate: Not available Decomposition Temp (掳C): Not available
State: Liquid
APPEARANCE
White to off-white suspension; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 10 of 11
Section 11 - TOXICOLOGICAL INFORMATION
Virbac Fencare 100 Anthelmintic for Cattle and Horses
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic
Effects of Chemical Substances
FENBENDAZOLE:
TOXICITY IRRITATION
Oral (rat) LD50: >10000 mg/kg Nil reported
Intraperitoneal (rat) LD50: >1250 mg/kg
Subcutaneous (rat) LD50: >2000 mg/kg
Oral (mouse) LD50: >10000 mg/kg
Oral (dog) LD50: >500 mg/kg
Oral (pig) LD50: >5000 mg/kg
Changes in serum composition recorded.
NOTE: Substance has been shown to be mutagenic in at least one assay, or
belongs to a family of chemicals producing damage or change to cellular DNA.
WATER:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
No data for Virbac Fencare 100 Anthelmintic for Cattle and Horses.
Refer to data for ingredients, which follows:
FENBENDAZOLE:
No data for fenbendazole.
WATER:
No data for water.
Section 13 - DISPOSAL CONSIDERATIONS
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
NONE
Hazard Class: None
UN/NA Number: None
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None IMDG Page Number: None
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VIRBAC FENCARE 100 ANTHELMINTIC FOR CATTLE AND HORSES
ChemWatch Material Safety Data Sheet CHEMWATCH 4606-96
Issue Date: Sat 27-Jul-2002 CD 2002/3 Page 11 of 11
Section 14 - TRANSPORTATION INFORMATION ...
Section 15 - REGULATORY INFORMATION
SAFETY
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Sat 27-Jul-2002
Print Date: Tue 20-Aug-2002
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