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MSDS Material Safety Data Sheet
CAS

111-30-8

File Name: midwesternmud_com---GREEN-CIDE_25G.asp
10271 - GREEN-CIDE 25G


MATERIAL SAFETY DATA SHEET
GREEN-CIDE 25G


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

GREEN-CIDE 25G
TRADE NAME:

Aldehydes.
CHEMICAL CLASS:

Biocide
APPLICATIONS:

281-561-1600
EMERGENCY TELEPHONE:

Supplied by a Business Unit of
SUPPLIER:
M-I L.L.C.
P.O. Box 42842, Houston, Texas 77242-2842
See cover sheet for local supplier.
281-561-1509
TELEPHONE:
281-561-7240
FAX:

Sam Hoskin
CONTACT PERSON:



2. COMPOSITION, INFORMATION ON INGREDIENTS

INGREDIENT NAME: CAS No.: CONTENTS : EPA RQ: TPQ:
Glutaraldehyde 111-30-8 25 %



3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:
WARNING! CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Avoid contact with eyes, skin and
clothing. Avoid breathing airborne product. Keep container closed. Use with adequate ventilation. Wash thoroughly
after handling.
This product is a/an yellow to colorless liquid No significant immediate hazards for emergency response personnel are
known. Dike and contain spills. Keep out of sewers and waterways.

ACUTE EFFECTS:
Severely irritating to the respiratory tract if inhaled.
INHALATION:

May cause burns in mucous membranes, throat, oesophagus and stomach. May cause gastric distress, nausea and
INGESTION:
vomiting if ingested.

Severely irritating to the skin.
SKIN:

Severely irritating to the eyes. May cause severe eye injury.
EYES:

CHRONIC EFFECTS:
CARCINOGENICITY:
IARC: Not listed. OSHA: Not regulated. NTP: Not listed.

ROUTE OF ENTRY:
Inhalation. Skin and/or eye contact.



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10271 - GREEN-CIDE 25G

TARGET ORGANS:
Respiratory system, lungs. Skin. Eyes.



4. FIRST AID MEASURES

Persons seeking medical attention should carry a copy of this MSDS with them.
GENERAL:

Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Get medical attention.
INHALATION:

Drink a couple of glasses water or milk. Do NOT induce vomiting unless directed to do so by a physician. Never give
INGESTION:
anything by mouth to an unconscious person. Get medical attention.

Wash skin thoroughly with soap and water. Remove contaminated clothing. Get medical attention if any discomfort
SKIN:
continues.

Promptly wash eyes with lots of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
EYES:
attention if any discomfort continues.



5. FIRE FIGHTING MEASURES

N/D
AUTO IGNITION TEMP. (掳F):
N/A
FLAMMABILITY LIMIT - LOWER(%):
N/A
FLAMMABILITY LIMIT - UPPER(%):

EXTINGUISHING MEDIA:
Carbon dioxide (CO2). Dry chemicals. Foam. Water spray, fog or mist.

SPECIAL FIRE FIGHTING PROCEDURES:
Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (including fire
fighting helmet, coat, pants, boots, and gloves). If protective equipment is not available or not used, fight fire from a
protected location or safe distance.

UNUSUAL FIRE & EXPLOSION HAZARDS:
No unusual fire or explosion hazards noted.

HAZARDOUS COMBUSTION PRODUCTS:
Irritating gases/vapors/fumes. Oxides of: Carbon.



6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS:
Wear proper personal protective equipment (see MSDS Section 8).

SPILL CLEAN-UP PROCEDURES:
Absorb in vermiculite, dry sand or earth and place into containers. Rinse area with water. Dike far ahead of larger spills for
later disposal. Do not contaminate drainage or waterways.



7. HANDLING AND STORAGE

HANDLING PRECAUTIONS:
Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Wear full
protective clothing for prolonged exposure and/or high concentrations. Eye wash and emergency shower must be
available at the work place. Wash hands often and change clothing when needed.


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10271 - GREEN-CIDE 25G

STORAGE PRECAUTIONS:
Store at moderate temperatures in dry, well ventilated area. Keep in original container.



8. EXPOSURE CONTROLS, PERSONAL PROTECTION

OSHA PEL: ACGIH TLV: OTHER:
INGREDIENT NAME: CAS No.: TWA: STEL: TWA: STEL: TWA: STEL: UNITS:
Glutaraldehyde 111-30-8 0.2 C mg/m3

INGREDIENT COMMENTS:
C = Ceiling Limit

PROTECTIVE EQUIPMENT:




ENGINEERING CONTROLS:
Use appropriate engineering controls such as, exhaust ventilation and process enclosure, to reduce air contamination and
keep worker exposure below the applicable limits.

Supply natural or mechanical ventilation adequate to exhaust airborne product and keep exposures below the applicable
VENTILATION:
limits.

RESPIRATORS: If exposed to particulates/aerosols:
Use at least a NIOSH-approved N95 half-mask disposable or reuseable particulate respirator. In work environments
containing oil mist/aerosol use at least a NIOSH-approved P95 half-mask disposable or reuseable particulate respirator.
If exposed to organic vapors:
Use a NIOSH/MSHA-approved organic vapor respirator. CCROV: CCR with organic vapor cartridge.

PROTECTIVE GLOVES:
Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Impermeable
material. Such as, Neoprene, nitrile, polyethylene or PVC.

EYE PROTECTION:
Wear chemical safety goggles where eye exposure is reasonably probable.

PROTECTIVE CLOTHING:
Wear appropriate clothing to prevent repeated or prolonged skin contact.

HYGIENIC WORK PRACTICES:
Wash promptly with soap and water if skin becomes contaminated. Change work clothing daily if there is any possibility
of contamination.



9. PHYSICAL AND CHEMICAL PROPERTIES

Liquid.
APPEARANCE/PHYSICAL STATE:
Yellow. to Colorless.
COLOR:
Pungent.
ODOR:
Soluble in water.
SOLUBILITY DESCRIPTION:
1.066 TEMPERATURE (掳F): 68
DENSITY/SPECIFIC GRAVITY (g/ml):
N/D
VAPOR DENSITY (air=1):
16.4 mmHg TEMPERATURE (掳F): 68
VAPOR PRESSURE:
N/D REFERENCE:
EVAPORATION RATE:
3.1 - 4.5
pH-VALUE, CONC. SOLUTION:




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10271 - GREEN-CIDE 25G




10. STABILITY AND REACTIVITY

Normally stable.
STABILITY:

CONDITIONS TO AVOID:
Avoid heat.

HAZARDOUS POLYMERIZATION:
Will not polymerize.

POLYMERIZATION DESCRIPTION:
Not relevant.

MATERIALS TO AVOID:
Strong alkalies.

HAZARDOUS DECOMPOSITION PRODUCTS:
No specific hazardous decomposition products noted.



11. TOXICOLOGICAL INFORMATION

TOXICOLOGICAL INFORMATION:
No toxicological data is available for this product. Toxicological data for major component(s):

Component: Glutaraldehyde

134 mg/kg (oral rat)
TOXIC DOSE - LD 50:


12. ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION:
No ecological information is available for this product.



13. DISPOSAL CONSIDERATIONS

WASTE MANAGEMENT:
This product, should it become a waste, may be a hazardous waste by U.S. RCRA criteria. Contact M-I's Environmental
Affairs Department for more information. Empty containers retain residues. All labeled precautions must be observed.

DISPOSAL METHODS:
Recover and reclaim or recycle, if practical. Should this product become a waste, dispose of in a permitted industrial
landfill. Ensure that containers are empty by RCRA criteria prior to disposal in a permitted industrial landfill.



14. TRANSPORT INFORMATION

RQ = N/A
GENERAL:

U.S. DOT:
Not regulated.
U.S. DOT CLASS:

CANADIAN TRANSPORT:


4/6
10271 - GREEN-CIDE 25G

Not regulated.
TDGR CLASS:

SEA TRANSPORT:
Not regulated.
IMDG CLASS:

AIR TRANSPORT:
Not regulated.
ICAO CLASS:


15. REGULATORY INFORMATION

REGULATORY STATUS OF INGREDIENTS:
NAME: CAS No: TSCA: CERCLA: SARA 302: SARA 313: DSL(CAN):
Glutaraldehyde 111-30-8 Yes No No No Yes


US FEDERAL REGULATIONS:
May be a hazardous waste by RCRA criteria. Consult M-I Environmental Affairs before
WASTE CLASSIFICATION:
disposal.

This Product or its components, if a mixture, is subject to following regulations (Not meant to
REGULATORY STATUS:
be all inclusive - selected regulations represented):

SECTION 313: This product does not contain toxic chemical subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization
Act of 1986 and 40 CFR Part 372.

SARA 311 Categories:
1: Immediate (Acute) Health Effects.

The components of this product are listed on or are exempt from the following international
chemical registries:
TSCA (U.S.)


STATE REGULATIONS:
This product or its components, if a mixture, is subject to following regulations (Not meant to
STATE REGULATORY STATUS:
be all inclusive - selected regulations represented):.

Illinois Right-to-Know.
New Jersey Right-to-Know.
Pennsylvania Right-to-Know.
PROPOSITION 65: This product does not contain chemicals considered by the State of
California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer or
reproductive toxicity, and for which warnings are now required.


CANADIAN REGULATIONS:
LABELS FOR SUPPLY:




This Material Safety Data Sheet has been prepared in compilance with the Controled Product
REGULATORY STATUS:
Regulations.

Canadian WHMIS Classification: D1B - Immediate and Serious Toxic Effects: Toxic
Material



16. OTHER INFORMATION



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10271 - GREEN-CIDE 25G


3 Serious Hazard
NPCA HMIS HAZARD INDEX:
0 Minimal Hazard
FLAMMABILITY:
0 Minimal Hazard
REACTIVITY:
J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapor Respirator.
NPCA HMIS PERS. PROTECT. INDEX:

N/A = Not applicable N/D = Not determined
USER NOTES:

OSHA Permissible Exposure Limits, 29 CFR 1910, Subpart Z, Section 1910.1000, Air
INFORMATION SOURCES:
Contaminants.
ACGIH Threshold Limit Values and Biological Exposure Indices for Chemical Substances
and Physical Agents (latest edition).
Sax's Dangerous Properties of Industrial Materials, 9th ed., Lewis, R.J. Sr., (ed.), VNR, New
York, New York, (1997).

Product information provided by the commercial vendor(s).


Sam Hoskin
PREPARED BY:

0
REVISION No.:



Approved.
MSDS STATUS:

May 13, 1998
DATE:


DISCLAIMER:
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from sources
beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely on it only at user's risk. We have
made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditiions under which this information and
product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the obligation of
each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional information will be
furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this product or to the data
herein is made or incurred hereunder.




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