LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
ADHESIVE 81668
ADHESIVE 81668
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: ADHESIVE 81668 Part of Kit: 81668
Part No.: 81668
Product Name: Form-A-Thread(TM) Stripped Thread Repair
Product Type: Adhesive
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Aromatic dimethacrylate ester 24448-20-2 35-40
Glass 65997-17-3 25-30
ALUMINUM 7429-90-5 20-25
ACRYLIC ACID* 79-10-7 3-5
Heterocyclic methacrylate 2455-24-5 1-3
SILICA, AMORPHOUS (FUMED) 7631-86-9 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
CUMENE HYDROPEROXIDE* 80-15-9 0.1-1
2,6-DI-tert-BUTYL-p-CRESOL 128-37-0 0.1-0.5
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 respir.
ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin
5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin
SILICA, AMORPHOUS (FUMED) 10mg/m3 TWA 6mg/m3 TWA None
2,6-DI-tert-BUTYL-p-CRESOL None None 10 mg/m3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Liquid is an eye and skin irritant.
Vapors may irritate eye, nose and throat.
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: Irritation of eyes, skin , nose or throat. May
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Item No.: ADHESIVE 81668
3. HAZARDS IDENTIFICATION (continued)
cause dermatitis on,prolonged contact in sensitive
individuals.
Existing Conditions
Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases,
dermatitis
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Aromatic dimethacrylate ester ALG IRR NO NO NO
Glass No Data NO NO NO
ALUMINUM IRR LUN NO NO NO
ACRYLIC ACID ALG COR IRR NO N/A NO
Heterocyclic methacrylate ALG IRR NO NO NO
SILICA, AMORPHOUS (FUMED) NUI NO N/A NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
2,6-DI-tert-BUTYL-p-CRESOL IRR MUT NO N/A NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant LUN Lung
MUT Mutagen NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200掳F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: If ignited, burns with unusual heat evolution. In
a fire, reaction with water is possible.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Item No.: ADHESIVE 81668
5. FIRE FIGHTING MEASURES (continued)
Explosive Limits:
(% by volume in air)Lower 2.0% Acrylic acid
30% Aluminum metal
(% by volume in air)Upper 8.0% Acrylic acid
Unknown Aluminum metal
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up with an inert absorbent. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100掳F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
Avoid breathing of vapors.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Grey Liquid
Odor: Mild
Boiling Point: More than 300掳F
pH: Does not apply
Solubility in Water: Low
Specific Gravity 1.57
Volatile Organic Compound
(EPA Method 24) 9.9%
Vapor Pressure: Less than 5mm at 80掳C
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Item No.: ADHESIVE 81668
10. STABILITY AND REACTIVITY (continued)
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: No Prop65 chemicals are known to be present.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Item No.: ADHESIVE 81668
16. OTHER INFORMATION (continued)
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0028
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 04
ACTIVATOR 81668
ACTIVATOR 81668
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: ACTIVATOR 81668 Part of Kit: 81668
Part No.: 81668
Product Name: Form-A-Thread(TM) Stripped Thread Repair
Product Type: Activator
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Aromatic dimethacrylate ester 24448-20-2 40-45
Glass 65997-17-3 25-30
ALUMINUM 7429-90-5 20-25
Heterocyclic methacrylate 2455-24-5 1-3
SILICA, AMORPHOUS (FUMED) 7631-86-9 1-3
Organo-copper compound 1338-02-9 0.1-0.5
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 respir.
SILICA, AMORPHOUS (FUMED) 10mg/m3 TWA 6mg/m3 TWA None
Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3fume None
Cu 1 mg/m3 dust Cu 1 mg/m3 dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals. Liquid may be an eye
irritant
Existing Conditions
Aggravated by Exposure: None known
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 04
Item No.: ACTIVATOR 81668
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Aromatic dimethacrylate ester ALG IRR NO NO NO
Glass No Data NO NO NO
ALUMINUM IRR LUN NO NO NO
Heterocyclic methacrylate ALG IRR NO NO NO
SILICA, AMORPHOUS (FUMED) NUI NO N/A NO
Organo-copper compound BLO IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable ALG Allergen
BLO Blood IRR Irritant
LUN Lung NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200掳F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: If ignited, burns with unusual heat evolution. In
a fire, reaction with water is possible.
Explosive Limits:
(% by volume in air)Lower 30% Aluminum metal
(% by volume in air)Upper Unknown Aluminum metal
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up with an inert absorbent. Store in a partly
filled, closed container until disposal. Residue
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 04
Item No.: ACTIVATOR 81668
6. ACCIDENTAL RELEASE MEASURES (continued)
may be cleaned with solvent.
7. HANDLING AND STORAGE
Safe Storage: Store below 110掳F.
Observe normal safety precautions.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue-grey liquid
Odor: Mild
Boiling Point: More than 300掳F
pH: Does not apply
Solubility in Water: Low
Specific Gravity 1.57
Volatile Organic Compound
(EPA Method 24) 3.6%
Vapor Pressure: Less than 5mm at 80掳C
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers.
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 04
Item No.: ACTIVATOR 81668
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: No Prop65 chemicals are known to be present.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0024
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LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 04
REL.AGENT 81668
REL.AGENT 81668
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: REL.AGENT 81668 Part of Kit: 81668
Part No.: 81668
Product Name: Form-A-Thread(TM) Stripped Thread Repair
Product Type: Release Agent
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Water 7732-18-5 90-95
Poly(dimethylsiloxane),
dimethyl 63148-62-9 1-3
Substituted silicone 67923-07-3 1-3
Nonionic surfactant 9016-45-9 0.1-1
Octylphenoxypolyethoxyethanol 9036-19-5 0.1-1
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Minor components are eye and skin irritants.
Primary Routes of Entry: Eyes, skin
Signs and symptoms
of Exposure: Irritation of eyes or skin.
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Water No Data NO NO NO
Poly(dimethylsiloxane),
dimethyl IRR NO NO NO
Substituted silicone No Data NO NO NO
Nonionic surfactant IRR NO NO NO
Octylphenoxypolyethoxyethanol IRR NO NO NO
-------------------------------------------------------------------------------
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 04
Item No.: REL.AGENT 81668
3. HAZARDS IDENTIFICATION (continued)
Abbreviations
IRR Irritant
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Does not apply
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: None Method: Not Applicable
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors; traces of formaldehyde.
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up with an inert absorbent. Store in partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100掳F. Protect from freezing.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid contact with skin. Avoid breathing vapors.
Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 04
Item No.: REL.AGENT 81668
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue liquid
Odor: None
Boiling Point: 212掳F
pH: 9-11
Solubility in Water: Miscible
Specific Gravity 1.0
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: 17 mm at 70掳F
Vapor Density: 0.6
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 04
Item No.: REL.AGENT 81668
15. REGULATORY INFORMATION
CA Proposition 65: No prop65 chemicals are known to be present.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 0
Fire Hazard: 0
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 0
Flammability Hazard: 0
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0016
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