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MATERIAL SAFETY DATA SHEET


I PRODUCT IDENTIFICATION

Sod ium Titanate Metal titanate
Trade Name: Ch em ical Fam ily:
Sod ium trititanate Na 2Ti3O 7
Synonyms: Form ula:
12034 -36-5
CAS #:


II HAZAR DOUS INGRED IENTS

Haz ardous C omp onents % OSHA/PEL ACGIH/TLV Sec. 302 Sec. 304 Sec. 313
15 m g/m 3 10 m g/m 3 (5 m g/m 3 resp.)
Sod ium Titanate 0-100 No No No

HM IS Ratings: Hea lth: 1 Flam mab ility: 0 Reactivity: 0 Protective Equipment: G: glasses, gloves, comb . respirator.


III PHYSICAL DATA

1128 oC
N/E or N /A
Boiling Point: Melting Point:
N/A 3.941 g/cc
Vapor Pressure: Specific Gravity (H 2O = 1):
N/A Insoluble
Vapo r Density: Solubility in H 2O:
Wh ite powder and pieces, no odor. N/E or N /A
Appearance and Odor: % Vo latile:


IV FIRE AND EXPLOSION HAZARD DATA

Flash Point: N/E or N /A Method U sed: Non-flam ma ble
Explosive Lim its: Lower: N/A Upper: N/A

Extingu ishing Media: Use suitable extinguishing agents for surrounding materials and type of fire.
Special Firefighting Procedures: Firefighters m ust w ear fu ll face, self-con tained breathing apparatus with full pro tective clothing to
prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution.

Unusual Fire and Explosion Hazards: When heated to decomposition, sodium titanate may emit toxic fumes of Na 2O.


V HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of sodium titanate have not been
thoroughly investigated and recorded.

Sodium com pounds have variable toxicity. Sodium ions as such is practically nontoxic.

Titanium is generally considered to be physiologically inert. There are no reported cases in the literature where titanium as
such has cause human intoxication. The dusts of titanium or most titanium compounds such as titanium oxide may be placed in the
nuisa nce category. (Sax, Dan gero us Prope rties of In dustrial M aterials, eig hth edition.)

Acute an d Chro nic Effects:
Inhalation: May cause irritation to the u pper respiratory tract an d mucou s mem branes.
Ingestion: No health effects recorded.
Skin : May cause abrasive irritation.
Eye: Prolonged or repeated contact may cause abrasive irritation.

Routes of Entry: Inhalation

Target Organs: No target organ effects recorded.

Medical Conditions Generally Aggravated by Exposure: Pre-existing resp iratory disord ers.

Carcino genicity: NTP: No IARC: No OSHA: No

EMERG ENCY AND FIRST AID PROCEDURES:

INHALATION: Rem ove victim to fresh air, kee p w arm and quiet, give o xyg en if breathing is d ifficult an d seek m edica l attention if
sym ptom s persist.
INGESTION: Give 1-2 glasses of milk or water and induce vom iting, seek medical attention if symptoms persist. Never induce
vomiting or give anything by mouth to an unconscious person.
SK IN: Remove contaminated clothing, brush material off skin, wash affected area with mild soap and water. Seek medical attention
if sym ptom s persist.
EYE: Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention if symptoms
persist.


VI REACTIVITY DATA

Stability: Stable

Co nditio ns to Av oid: None
Incompatibility (Material to Avoid): None recorded

Haz ardous D ecomposition Produc ts: Na 2O
Hazardous Polymerization: Will not occur.


VII SPILL OR LEAK PROC EDURES

Steps to Be Taken in Case Material is Released: We ar appropriate respira tory and protective equipm ent specified in sectio n V III.
Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a
closed container for proper d isposal. Tak e care not to raise dust.

Waste Disposal Method: Dispose o f in accord ance w ith Federal, State and L ocal regu lations.


VIII SPECIAL PROTECTION INFORMATION

Respiratory Protection: NIOSH approved respirator.

Ventilation: Local exhaust ventilation may be necessary to control any air contaminants to within their the PEL's or TLV's during the
use of this pro duct. Good general ventilation sho uld be su fficient to control airborne levels.

Protective Gloves: Rubber gloves
Eye Protection: Safety glasses

Other Protective Clothing or Equipment: Protective gear suitable to prevent contamination.



-Sodium Titanate 2-
IX SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage: Store in a tightly sealed container in a cool, dry area. Store away from
oxidizers. Wash thoroughly after handling.

Wo rk/Hygienic/Maintenance Practices: Implement engineering and work practice controls to reduce and maintain concentration of
exp osure at low levels. U se go od h ousekeeping and san itation p ractices. Do not u se tobacco or food in wo rk are a. W ash thorough ly
before eating and sm oking. Do not blow du st off clothing or skin with com pressed air.

The abo ve inform ation is believ ed to be co rrect, but do es no t purp ort to b e all inclu sive an d sha ll be used only as a gu ide.
ESPI shall not be held liab le for any d am age resulting from h and ling o r from contact with the abov e pro duc t.


Issued by: S. Dierks
Date: February 2000




-Sodium Titanate 3-

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