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MATERIAL SAFETY DATA SHEET


I PRODUCT IDENTIFICATION

Vanadium Nitride Metal nitride
Trade Name: Ch em ical Fam ily:
VN 24646 -85-3
Form ula: CAS #:
Listed in the EPA T SCA Inventory 64.949
TSCA: Molecular Weight:


II HAZAR DOUS INGRED IENTS

Hazardous Component % OSHA/PEL ACGIH/TLV
0.05 mg /m 3 (as V) 0.05 mg /m 3 (as V 2O 5)
Vanadium Nitride 100

HM IS Hazard Rating (0-4): Health: 3 Flam mab ility: 0 Reactivity: 2 Personal Protection: E


III PHYSICAL DATA

N/D 2320
Boiling Point: Melting Point:
N/A 6.13
Vapor Pressure: Density gm/cc:
None Insoluble
Reaction with H 2O: Solubility in Water:
Sligh tly solu ble in aqua regia N/A
Other C omm ents: % Volatile by Volume:
Black crystalline powder
Appearance and Odor:


IV FIRE AND EXPLOSION H AZARDS DATA

Flash Point: N/A Autoignition Temperature: N/A
Flam mab le Limits: Lower: N/A Upper: N/A

Extingu ishing Media: Use dry chem ical, graphite, age nts for m etal fires.
Special Firefighting Procedures: We ar a self-con tained breathing apparatus and full pro tective clothing to prev ent co ntact w ith skin
and ey es.

Unusual Fire and Explosion Hazards: May evo lve toxic fumes of V xOy and Nx Oy if involved in a fire


V HEALTH HAZARD INFORMATION

Effects of Exposure:

Inhalation: Sym ptom s include pallor, parox ysm al cou gh, p ain in chest, bron chitis, rales and rhonch i, bron cho spasm s, radio grap hic
reticulation, and tremors of the arms and fingers. Prolonged exposure leads to pulmonary involvement. Serious overexposure may
lead to pulm ona ry ed em a and pneum onia.
Ingestion: Greenish tong ue, m etallic taste, tremo rs, pallor, sore th roat. V anadium is an eq uivtu rmorigenic agen t. Responses to
vanadium exposure are acute, never chronic. Recent reports describe symptoms which are generally restricted to the conjunctiva and
respiratory tracts, with no evidence of disturbances of the G.I. tract, kidneys, blood or CNS.
Skin : Irritation, redn ess, inflamm ation possible. M ay also cause eczem atous type lesions and hives.
Eye: Irritant to conjunctiva. May cause burning sensation , watering, inflamm ation.
Toxicity Da ta: No specified data on this compound
Routes of Entry: Inhalation, Skin, and ingestion
Medical Conditions Generally Aggravated by Exposure: Respiratory and ey e disorde rs.
Carcino genicity: NTP: No IARC M onographs: No OSH A Regulated: Yes

EMERG ENCY AND FIRST AID PROCEDURES:

INHALATION: Rem ove victim to fresh air. Seek m edica l attention. Give oxyg en if breathing is d ifficult.
INGESTION: Give victim 1-2 glasses of milk or water and induce vomiting. Seek medical attention.
SK IN: Brush material off skin. Wash affected area with soap and water. Seek medical attention.
EYES: Flush eyes with lukewarm water for 15 minutes. Seek medical attention.


VI REACTIVITY DATA

Stability: Stable
Co nditio ns to Av oid: Exp osure to high temp , incomp atible m aterials
Incompatibility (Material to Avoid): No data. Possibly inco mp atible with H F, halog ens, oxid izers, interhalogens.

Haz ardous D ecomposition Produc ts: V 2O 5, NxOy (heat)
Hazardous Polymerization: Will not occur


VII SPILL OR LEAK PROC EDURES

Steps to Be Taken in Case Material Is Released or Spilled: We ar a self-con tained breathing apparatus and full pro tective clothing.
Isolate the are a where the spill occu rred and insure that p roper ventilation is available. V acuum up sp ill using a high efficiency unit
and place in a co ntainer for proper d isposal. Tak e care not to raise dust.

Waste Disposal Method: Dispose o f in accord ance w ith applicable Federa l, State and L ocal regu lations.


VIII SPECIAL PROTECTION INFORMATION

Respiratory Protection (Specify Type): Wear NIO SH-app roved du st-mist-fume cartridge respirator.
Ventilation: Use local exhaust to maintain exposure be low TL V for V 2O 5. Han dle in controlled atmosphere Mechanica l exhaust is
not recommended.

Eye Protection: Safety glasses Protective Gloves: Neoprene
Other Protective Equipment: Wear protective clothing to p revent contam ination of sk in and c lothes


IX SPECIAL PRECAUTIONS

Other Handling and Storage Conditions: Store in a tigh tly closed co ntainers in a cool, dry p lace. W ash h and s and face th orough ly
after handling and before eating.

The abo ve inform ation is believ ed to be co rrect, but do es no t purp ort to b e all inclu sive an d sha ll be used only as a gu ide.
ESPI shall not be held liab le for any d am age resulting from h and ling o r from contact with the abov e pro duc t.


Issued by: S. Dierks
Date: December 1992




-Vanadium Nitride 2-

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