Material Safety Data Sheet
Revision: 03/26/2002
Hazard information is provided for compliance with both the UK Chemicals
(Hazard Information and Packaging) (CHIP) Regulations and the US Hazard
Communication Standard (HCS)
IDENTIFICATION OF THE PRODUCT NAME: PRODUCT CODE: EEC NUMBER:
SUBSTANCE/PREPARATION Linoleic Acid 18455 None
AND COMPANY
SUPPLIER: Emergency Contact:
USB Corporation, 26111 Miles Road, Cleveland, Ohio 44128 Phone: (216) 765-5000 Chemtrec (800) 424-9300
Outside USA & Canada 703 527 3887
COMPOSITION/
HAZARDOUS COMPONENTS HAZARD CAS NO. %WT TLV CHIP R & S Phrases
Linoleic Acid 60-33-3 >99% --- R:36/37/38 Irritating to eyes,
respiratory system and skin.
S:24/25 Avoid contact with skin
and eyes.
S:36/37 Wear suitable protective
clothing and gloves.
HAZARDS IDENTIFICATION CHIP
Irritant
HCS
Irritant
FIRST-AID MEASURES EYES: Flush with water for 15 minutes. Seek medical advice if irritation persists.
SKIN: Flush with water, then wash thoroughly with soap and water. Remove contaminated clothing and wash
before reuse. Seek medical attention if irritation persists.
INHALATION: Remove the victim from exposure and move to fresh air. If breathing is difficult, give oxygen. If
not breathing, give artificial respiration. Keep victim quiet and warm. Seek immediate medical attention.
INGESTION: Drink water and seek immediate medical attention. Avoid alcoholic beverages. Never give
anything by mouth to an unconscious person.
FIRE-FIGHTING INFORMATION Use media suitable to extinguish the supporting or surrounding fire. Wear NIOSH (or equivalent) approved self
contained breathing apparatus. For small fires only: use carbon dioxide, dry powder or foam. Emits toxic fumes
under fire conditions. NFPA Rating: H=2 F=1 R=0.
Flash Point = 235掳F (112.77掳C).
ACCIDENTAL RELEASE MEASURES Wear appropriate personal protective equipment and clothing including lab coat, safety glasses, gloves and
NIOSH-approved (or equivalent) respirator and appropriate to the hazard. Linoleic acid can be saponified
(converted to a soap) with sodium carbonate which solubilizes the material in water. It may then be flushed or
hosed off surfaces. Contain the spill with an inert absorbent and place in a suitable waste container. Avoid
contact of material with skin or eyes. Use adequate ventilation.
HANDLING AND STORAGE Wear suitable protective clothing including lab coat, chemical resistant safety glasses, gloves and NIOSH-
approved (or equivalent) respirator and gloves. A qualified industrial hygienist should evaluate the need for
respiratory protection. Use adequate ventilation. Protect from exposure to air. Do not store near excessive heat
or open flame. Store at -20掳C, in vacuum sealed ampules under inert gas, away from incompatible material.
PERSONAL PROTECTION Wear appropriate personal protective equipment and clothing including lab coat, safety glasses, gloves and
NIOSH-approved respirator. A qualified industrial hygienist should evaluate the need for respiratory protection.
Use respiratory protection approved by NIOSH (or equivalent) and appropriate to the hazard. Avoid contact of
material with skin or eyes. Mechanical ventilation or local exhaust as needed to control exposure to dust,
vapors or mists. Access to a safety shower and eye-wash. HMIS Rating: H= 2 F=1 R=0.
This data sheet is based upon information believed to be reliable. The Company makes no statement or warranty as to the accuracy or completeness of the information
contained herein which is offered for your consideration, investigation and verification. Any use of the information contained in this data sheet must be determined by the user
to be in accordance with appropriate applicable regulations.
For Further Asia Pacific Canada Former Soviet Union Japan Norway Spain USA
Information, +852 2811 8693 1 800 463 5800 +7 (095) 232 0250 81 3 5331 9337 63 89 23 10 935 944 950 USB Corporation
contact your (216) 765-5000
local USB Australia Central and East Europe France Latin America Portugal Sweden If purchased from
authorized +61 2 9894 5188 +43 1 982 3826 0169 18 28 00 +55 11 3667 5700 01 417 70 35 018 164000 Amersham Pharmacia
distributor, Biotech use
Amersham Austria Denmark Germany Middle East and Africa South East Asia Switzerland 1 800 526 3593
Pharmacia 01 576 0616 10 +45 4516 2400 0 7 61 49 03 0 +30 (1) 96 00 687 60 3 724 2080 01 802 81 50
Biotech
Belgium Finland Italy Netherlands South East Europe UK
0800 73888 358 (9) 512 3940 02 27322 1 0165 580 410 +43 (1) 982 3826 0800 515313
MSDS information may be continued on back of page.
PHYSICAL AND CHEMICAL Appearance: Yellow, clear liquid; fatty odor Boiling Point: 650掳F (decomposes)
PROPERTIES Vapor Pressure: 1 mmHg @ 180掳C Vapor Density: 9.7
Solubility (Water): Insoluble Specific Gravity: 0.902
Percent Volatile: No data available Evaporation Rate: No data available
Chemical Formula: C18-H32-O2 Melting Point: -5掳C
STABILITY AND REACTIVITY Product is stable. Protect from exposure to air. May discolor upon exposure to air or light. Heat-sensitive.
Linoleic acid, when overheated, will decompose into shorter chain length oxidation fragments which are not
known to be hazardous. Hazardous decomposition products include oxides of carbon. Incompatible with strong
oxidizing agents, bases and reducing agents. Hazardous polymerization will not occur.
TOXICOLOGICAL INFORMATION EFFECTS OF OVEREXPOSURE:
EYES: Contact may cause irritation and slight corneal injury.
SKIN: Contact may cause irritation and/or allergic reaction.
INHALATION: May cause irritation to mucous membranes and upper respiratory tract.
INGESTION: Chronic ingestion or excessive dosage may cause irritation of the mouth, throat, esophagus and
gastrointestinal tract.
ADDITIONAL INFORMATION:
May be harmful by inhalation, ingestion or skin absorption. Linoleic acid is non-volatile. Inhalation hazard should
not be a factor. Mild irritant to some individuals and may cause nausea and vomiting.
Irritation and toxicity data listed in RTECS under RF9990000.
Irritation data: Skin Human 75 mg/3D (Intermittent) = Moderate (1977).
Toxicity data: Intraperitoneal Rat LD50 = >50 gm/kg (1967). Details of toxic effects not reported other
than lethal dose value.
Definition(s): RTECS = Registry of Toxic Effects of Chemical Substances.
ECOLOGICAL INFORMATION No information available.
DISPOSAL CONSIDERATIONS The water-soluble soaps of Linoleic acid (Sodium and Potassium) are biodegradable and waste disposal is
generally not a problem. Dispose of material in accordance with applicable local, state, and federal regulations.
TRANSPORTATION INFORMATION US DOT / IATA: No applicable information.
REGULATORY INFORMATION RCRA - No applicable information.
SARA 302 -This material does not have an RQ or TPQ.
SARA 313 -This material is not reportable under 313.
EPA TSCA Section 8(b) - Chemical Inventory.
8(d) - unpublished health/safety studies.
Exposure Limits - Not established.
California Proposition 65 - No applicable information.
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