Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
Section 1 - Chemical Product and Company Identification
Product Name JM EPDM Sheets
CAS# Mixture/None Assigned
Generic Name Single Ply Membrane Sheets
Formula Mixture
Chemical Name: Mixture
Hazard Label None necessary.
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names:
JM Reinforced and Nonreinforced EPDM Roofing Membranes (0.045, 0.060 FR, 0.060 FR XT, 0.045 R XT, 0.060 R XT);
JM 0.060 White EPDM Roofing Membrane;
JM Flashing
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
1333-86-4 Carbon black 5-40*
14807-96-6 Magnesium silicate (asbestos-free talc) 0-20*
Not Available Decabromodiphenyl oxide 4-10**
1332-58-7 Kaolin 0-10*
13463-67-7 Titanium dioxide 0-10*
25038-36-2 EPDM polymer >3
8042-47-5 Petroleum hydrocarbon >3
1309-64-4 Antimony trioxide 0-5*
63231-67-4 Silica gel 0-5*
Not Available Ground coal 0-3
1314-13-2 Zinc oxide 0-2*
Additional Component Information
* Note: Due to the product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given
for reference only.
** Present in JM Reinforced and Nonreinforced EPDM Roofing Membranes and JM 0.060 White EPDM Roofing Membrane
only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Black, gray, or white rubber sheet of varying shapes and sizes. Sight rubber odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Potential Health Effects
Summary
Prolonged skin contact with uncured rubber products may cause skin sensitization (allergy). No other health effects are
expected under normal conditions of use for this product.
Inhalation
Not applicable
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
Skin
Irritation, dermatitis (skin rash or redness) may occur.
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause temporary
irritation to the gastrointestinal (GI) tract, especially the stomach.
Eyes
Not applicable
Primary Routes of Entry (Exposure)
Skin contact.
Target Organs
Skin.
Medical Conditions Aggravated by Exposure
Prior sensitization to rubber products.
Section 4 - First Aid Measures
First Aid: Inhalation
Not applicable
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, irritation of the gastrointestinal (GI) tract may occur,
and should be treated symptomatically.
First Aid: Eyes
Not applicable
First Aid: Notes to Physician
Treatment for skin sensitization should be symptomatic, with removal of patient from further exposures.
Section 5 - Fire Fighting Measures
Flash Point: >260潞C/500潞F Method Used: Open Cup
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
No special procedures necessary
Clean-Up Procedures
No additional information available.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from
moisture.
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Carbon black (1333-86-4)
ACGIH: 3.5 mg/m3 TWA
OSHA: 3.5 mg/m3 TWA
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
Magnesium silicate (asbestos-free talc) (14807-96-6)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 2 mg/m3 TWA (respirable dust, less than 1% crystalline silica)
Titanium dioxide (13463-67-7)
ACGIH: 10 mg/m3 TWA
OSHA: 10 mg/m3 TWA (total dust)
Kaolin (1332-58-7)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Zinc oxide (1314-13-2)
ACGIH: 2 mg/m3 TWA (respirable fraction)
10 mg/m3 STEL (respirable fraction)
OSHA: 5 mg/m3 TWA (fume); 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
10 mg/m3 STEL (fume)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses.
Personal Protective Equipment: Skin
Leather or cotton gloves may be used to prevent excessive, prolonged skin contact.
Personal Protective Equipment: Respiratory
Not required
Ventilation
No special ventilation systems are required under normal conditions of use. The need for ventilation systems should be
evaluated by a professional industrial hygienist, while the design of specific ventilation systems should be conducted by a
professional engineer.
Personal Protective Equipment: General
No additional information available.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black, gray or white rubber sheet Slight rubber odor
of varying shapes and sizes.
Physical State: pH:
Solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not applicable Not determined
Solubility (H2O): Specific Gravity:
Nil 1.10-1.30
Freezing Point: Evaporation Rate:
Not applicable Not applicable
Viscosity: Percent Volatile:
Not applicable 0
VOC: Not determined
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material. This product is not reactive.
Hazardous Decomposition
The decomposition products from this material are those that would be expected from any organic (carbon-containing)
material. These decomposition products may include carbon dioxide, carbon monoxide, carbon particles, traces of hydrogen
cyanide, and oxides of nitrogen.
Hazardous Polymerization
Will not occur.
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
This product is not expected to present any acute toxicologic effects in that under normal conditions of use.
B: Component Analysis - LD50/LC50
Carbon black (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit: >3 g/kg
Titanium dioxide (13463-67-7)
Oral LD50 Rat: >10000 mg/kg
Petroleum hydrocarbon (8042-47-5)
Oral LD50 Rat: >5000 mg/kg
Antimony trioxide (1309-64-4)
Oral LD50 Rat: >34600 mg/kg
Zinc oxide (1314-13-2)
Oral LD50 Rat: >5000 mg/kg
Carcinogenicity
A: General Product Information
No data for this product as a whole.
B: Component Carcinogenicity
Carbon black (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 65
[1996])
Magnesium silicate (asbestos-free talc) (14807-96-6)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers); A1 - Confirmed
Human Carcinogen (containing asbestos fibers)
IARC: Group 3 - Not Classifiable (IARC Monograph 93 posted (inhaled), Supplement 7 [1987],
Monograph 42 [1987])
Titanium dioxide (13463-67-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 47
[1989])
Kaolin (1332-58-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Antimony trioxide (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])
Chronic Toxicity
Prolonged skin contact may result in skin sensitization, with possible irritation, redness, rash, or allergic type reactions upon
subsequent exposures.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Carbon black (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L
Magnesium silicate (asbestos-free talc) (14807-96-6)
96 Hr LC50 Brachydanio rerio: >100 g/L [semi-static]
Petroleum hydrocarbon (8042-47-5)
96 Hr LC50 Lepomis macrochirus: >10000 mg/L
Antimony trioxide (1309-64-4)
96 Hr LC50 Pimephales promelas: 833.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 530 mg/L; 96 Hr LC50 Brachydanio rerio:
>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
7 Hr EC50 Pseudomonas putida: >3.5 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Wastes are not hazardous as defined by the Resource Conservation and Recovery Act (RCRA; 40 CFR 261). Comply with
state and local regulations for disposal of solid wastes. If you are unsure of the regulations, contact your local Public Health
Department, or the local offices of the Environmental Protection Agency (EPA).
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Antimony trioxide (1309-64-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Carbon black 1333-86-4 Yes No Yes Yes Yes Yes
Magnesium silicate (asbestos-free talc) 14807-96-6 Yes No Yes Yes Yes Yes
Titanium dioxide 13463-67-7 No No Yes Yes Yes Yes
Kaolin 1332-58-7 No No Yes Yes No Yes
Silica gel 63231-67-4 No No Yes Yes No Yes
Antimony trioxide 1309-64-4 Yes No Yes Yes Yes Yes
Zinc oxide 1314-13-2 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Carbon black 1333-86-4
Antimony trioxide 1309-64-4
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Carbon black 1333-86-4 Yes Yes Yes
Magnesium silicate (asbestos-free talc) 14807-96-6 Yes Yes Yes
Titanium dioxide 13463-67-7 Yes Yes Yes
Kaolin 1332-58-7 Yes Yes No
EPDM polymer 25038-36-2 Yes Yes No
Petroleum hydrocarbon 8042-47-5 Yes Yes Yes
Silica gel 63231-67-4 Yes Yes No
Antimony trioxide 1309-64-4 Yes Yes Yes
Zinc oxide 1314-13-2 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Carbon black 1333-86-4 1%
Antimony trioxide 1309-64-4 1%
Zinc oxide 1314-13-2 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
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Material Name: JM EPDM Sheets Material Safety Data
Sheet ID: 3009
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 3009-1.0000 New MSDS authoring system.
10/14/02 3009-1.0101 Updated Sect. 15 for TSCA 12B: Decabromodiphenyl oxide has
been delisted.
10/22/03 3009-1.0200 Section 15, TSCA 12b, Decabromodiphenyl oxide added
07/20/05 3009-1.0300 Regulatory update: Sections 8, 11, & 15
12/15/05 3009-1.0301 Section 2, minor update to composition amounts and addition of
DBDO footnote.
07/03/06 3009-1.0302 Replaced UltraGard庐 with JM
01/15/07 3009-1.0303 Section 15 TSCA 12b info was edited and DBDO removed. This
product is an article under TSCA. DBDO does not need to be
reported under TSCA 12b per 40CFR 搂707.60(b).
This is the end of MSDS # 3009
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