Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Section 1 - Product and Company Identification
Hazard Label CAUTION
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: JM EPDM Pourable Sealer-Part A; JM PVC Pourable Sealer - Part A
Use: JM EPDM/PVC Pourable Sealer is a two-part polyurethane sealant. It is used as a penetration pocket filler.
Section 2 - Hazards Identification
Emergency Overview
HMIS Ratings: Health = 1 Fire = 0 Reactivity = 0
Inhalation
Not expected under normal conditions of use. However, irritation of the upper respiratory tract (scratchy throat), coughing, and
congestion may occur in extreme exposures.
Skin
Temporary irritation (itching) or redness may occur.
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Nose (nasal passages), throat, lungs, skin, eyes
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 3 - Composition/Information on Ingredients
CAS # Component Percent
1317-65-3 Calcium carbonate 47
9016-87-9 Polymethylene polyphenylene isocyanate 5.5
7631-86-9 Silica, amorphous 2
1344-28-1 Aluminum oxide 1
1333-86-4 Carbon black 0.1
14808-60-7 Crystalline silica 0.1
General Product Description
Black, liquid. Slight aromatic odor.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water. If irritation develops or persists, seek medical
attention. Launder contaminated clothing before reuse.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention
immediately.
First Aid: Eyes
Flush eyes with large amounts of water until irritation subsides. If irritation persists, seek medical attention.
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Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Section 5 - Fire Fighting Measures
Flash Point: 450潞F Method Used:
Upper Flammable Limit (UFL): Not determined Lower Flammable Limit (LFL): Not determined
Auto Ignition: Not determined Flammability Classification:
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Hazardous Combustion Products
Carbon monoxide, carbon dioxide, halogenated hydrocarbons, nitrogen oxides, and various hydrocarbons.
Extinguishing Media
Carbon dioxide (CO2), water, water fog, dry chemical.
Fire Fighting Equipment/Instructions
Use NIOSH-approved self-contained breathing apparatus operating in the pressure demand mode and full fire fighting
protective clothing. Avoid inhalation of vapors.
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
Place in closable container for disposal.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Product should be kept in a cool and dry area in
original packaging. Do not freeze.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent inhalation of vapors, prolonged skin contact, and to keep
exposure levels below the applicable exposure limits.
B: Component Exposure Limits
Calcium carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Silica, amorphous (7631-86-9)
OSHA: 20 mppcf TWA; ((80)/(% SiO2) mg/m3 TWA)
Aluminum oxide (1344-28-1)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Carbon black (1333-86-4)
OSHA: 3.5 mg/m3 TWA
3.5 mg/m3 TWA
ACGIH: 3.5 mg/m3 TWA
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Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Crystalline silica (14808-60-7)
OSHA: 0.1 mg/m3 TWA (respirable dust)
((250)/(%SiO2 + 5) mppcf TWA (respirable)); ((10)/(%SiO2 + 2) mg/m3 TWA (respirable));
((30)/(%SiO2 + 2) mg/m3 TWA (total dust))
ACGIH: 0.025 mg/m3 TWA (respirable fraction)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields or chemical goggles are recommended.
Personal Protective Equipment: Skin
Impervious gloves such as nitrile rubber should be used to help prevent excessive skin contact.
Personal Protective Equipment: Respiratory
A NIOSH approved respirator must be used if vapor concentrations exceed exposure limits.
Ventilation
Local exhaust or general dilution ventilation may be required to maintain exposures below the applicable exposure limits. The
need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Protective equipment should be provided as necessary to prevent irritation of the throat, eyes, and skin, and to keep
exposures below the applicable exposure limits identified in Section 8.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black Slight aromatic odor
Physical State: pH:
Liquid Not applicable
Vapor Pressure: Vapor Density:
<0.001 @ 20潞C Not available
Boiling Point: Melting Point:
>260潞C/500潞F Not determined
Solubility (H2O): Specific Gravity:
Negligible 1.51
Freezing Point: Evaporation Rate:
Not determined Not applicable
Percent Volatile: VOC:
0.1 0 g/L
Section 10 - Stability & Reactivity Information
Stability
These products are not reactive.
Incompatibility
Strong acids, alkalis, and oxidizing agents
Hazardous Decomposition
May form carbon dioxide, carbon monoxide, halogenated hydrocarbons, nitrogen oxides, various hydrocarbons.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Vapors from this product may cause eye, respiratory and skin irritation,
B: Component Analysis - LD50/LC50
Polymethylene polyphenylene isocyanate (9016-87-9)
Inhalation LC50 Rat: 490 mg/m3/4H; Oral LD50 Rat:49 g/kg; Dermal LD50 Rabbit:>9400 mg/kg
Silica, amorphous (7631-86-9)
Oral LD50 Rat: >5000 mg/kg; Inhalation LC50 Rat:>2.2 mg/L/1H; Dermal LD50 Rabbit:>2000 mg/kg
Aluminum oxide (1344-28-1)
Oral LD50 Rat: >5000 mg/kg
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Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Carbon black (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg
Crystalline silica (14808-60-7)
Oral LD50 Rat: 500 mg/kg
Component Carcinogenicity
Polymethylene polyphenylene isocyanate (9016-87-9)
IARC: Group 3 - Not Classifiable (IARC Supplement 7 [1987], Monograph 19 [1979])
Silica, amorphous (7631-86-9)
IARC: Group 3 - Not Classifiable (IARC Monograph 68 [1997], Supplement 7 [1987])
Carbon black (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph
65 [1996])
Crystalline silica (14808-60-7)
ACGIH: A2 - Suspected Human Carcinogen
NTP: Known Human Carcinogen (Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 68 [1997] (listed under Crystalline silica
inhaled in the form of quartz or cristobalite from occupational sources))
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Silica, amorphous (7631-86-9)
96 Hr LC50 Brachydanio rerio: 5000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 440 mg/L
48 Hr EC50 Ceriodaphnia dubia: 7600 mg/L
Carbon black (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection
Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is
recommended to ensure proper disposal under federal and/or state requirements.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transport Information
Shipping Name: This product is not regulated for transport.
International Transport Regulations
These products are not classified as dangerous goods according to international transport regulations.
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Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Polymethylene polyphenylene isocyanate (9016-87-9)
SARA 313: 1.0 % de minimis concentration (listed under Chemical Category N120, Diisocyanates)
Aluminum oxide (1344-28-1)
SARA 313: 1.0 % de minimis concentration (fibrous forms)
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Calcium carbonate 1317-65-3 No No Yes Yes Yes Yes
Polymethylene polyphenylene isocyanate 9016-87-9 No No No No Yes No
Silica, amorphous 7631-86-9 Yes No Yes Yes No Yes
Aluminum oxide 1344-28-1 Yes No Yes Yes Yes Yes
Carbon black 1333-86-4 Yes No Yes Yes Yes Yes
Crystalline silica 14808-60-7 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Carbon black 1333-86-4
Crystalline silica 14808-60-7
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Calcium carbonate 1317-65-3 Yes No Yes
Polymethylene polyphenylene isocyanate 9016-87-9 Yes Yes No
Silica, amorphous 7631-86-9 Yes Yes Yes
Aluminum oxide 1344-28-1 Yes Yes Yes
Carbon black 1333-86-4 Yes Yes Yes
Crystalline silica 14808-60-7 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Silica, amorphous 7631-86-9 1%
Aluminum oxide 1344-28-1 1%
WHMIS Classification
This is not a WHMIS controlled product. This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations. This SDS contains all the information required by the Controlled Products Regulations.
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Material Name: JM EPDM/PVC Pourable Sealer - Part A Safety Data Sheet
ID: 3129
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 3129-1.0000 New MSDS authoring system.
12/11/00 3129-1.0100 Minor editing and regulatory update.
08/05/03 3129-1.0101 Sect. 1: Update product names "UltraGard EPDM Pourable Sealer
Part A; UltraGard PVC Pourable Sealer Part B. Delete obsolete
trade name SPM. Sect. 2 Update composition for PVC Sealer.
Health and safety statements updated to relate to composition.
03/31/05 3129-1.0102 Moved PVC Pourable Sealer-Part A to new MSDS ID 3225 as TPO
Pourable Sealer-Part A. Updated composition and remaining
sections for supplier and regulatory updates.
12/02/05 3129-1.0103 Re-added JM PVC Pourable Sealer - Part A. Regulatory update.
Minor edits to Section 11 LD50 and Section 15 WHMIS.
08/18/08 3129-1.0104 Updated SDS to GHS format. Updated composition.
End of Sheet 3129
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