Material Name: MBR庐 Roof Insulation Adhesive Material Safety Data
Sheet ID: 3119
Section 1 - Chemical Product and Company Identification
Product Name MBR Roof Insulation Adhesive
CAS# Mixture/None Assigned
Generic Name latex emulsion
Formula Mixture
Chemical Name: Mixture
Hazard Label L3119
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: MBR庐 Insulation Adhesive
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
8052-42-4 Petroleum Asphalt 45-55
7732-18-5 Water 15-25
9003-55-8 Styrene-butadiene polymer 10-20
1302-78-9 Clay 3-8
8012-95-1 Oil mist, mineral 3-6
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Black fluid. May have a slight asphalt odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
HMIS Ratings: Health = 1 Fire = 0 Reactivity = 0 PPE = A
Potential Health Effects
Summary
Asphalt and its fumes can irritate skin, eyes, and upper respiratory tract.
Inhalation
Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts
of this material may be harmful.
Skin
Prolonged contact may result in mild skin irritation.
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Temporary irritation (itching) or redness may occur.
Ears
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Upper respiratory passages, skin, and eyes.
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Material Name: MBR庐 Roof Insulation Adhesive Material Safety Data
Sheet ID: 3119
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If the material is swallowed, get immediate medical attention or advice -- Do
not induce vomiting.
First Aid: Eyes
Gently flush irritated eye with water for 10-15 minutes or until irritation subsides. Hold eyelid open while flushing. If irritation
cannot be relieved through flushing, seek medical attention.
First Aid: Ears
Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.
First Aid: Notes to Physician
This product is basically a water emulsion and is not expected to produce any long term health effects. Treatment for
inhalation, skin contact, or ingestion should be symptomatic.
Section 5 - Fire Fighting Measures
Flash Point: >212F Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not applicable. Flammability Classification: Non-Combustible
Rate of Burning: Not determined
General Fire Hazards
This material will not burn. After drying: Burning of this material will produce thick black smoke
Extinguishing Media
Use methods for the surrounding fire.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
Dam, mop, absorb onto sawdust or other absorbent, and place in suitable container.
Clean-Up Procedures
Dispose of spilled material in approved landfill or incinerate in compliance with federal, state and local regulations. If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the Environmental Protection
Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Storage Procedures
Keep from freezing
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Petroleum Asphalt (8052-42-4)
ACGIH: 0.5 mg/m3 TWA (inhalable fraction, as benzene-soluble aerosol)
Oil mist, mineral (8012-95-1)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor)
10 mg/m3 STEL
OSHA: 5 mg/m3 TWA
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Material Name: MBR庐 Roof Insulation Adhesive Material Safety Data
Sheet ID: 3119
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, or a face shield is recommended.
Personal Protective Equipment: Ears
Use ear protection (earplugs, hood, or earmuffs) to prevent liquid from entering the ear, if necessary.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to prevent skin contact and irritation.
Personal Protective Equipment: Respiratory
If vapor levels are above the applicable exposure limits, a NIOSH-approved organic vapor respirator must be provided and
worn.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
Normal work clothing (long sleeved shirts and long pants) is recommended.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black May have a slight asphalt odor.
Physical State: pH:
Fluid 10.2-11.1
Vapor Pressure: Vapor Density:
N/A >1
Boiling Point: Melting Point:
212-250F Not applicable
Solubility (H2O): Specific Gravity:
Not soluble 1.03
Evaporation Rate: Percent Volatile:
<1 31
VOC: 2 g/L
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Avoid freezing
Incompatibility
Strong oxidants
Hazardous Decomposition
Smoke, carbon monoxide if combustion is incomplete
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Excessive exposure to this product is irritating to the skin, eyes, and upper respiratory tract.
B: Component Analysis - LD50/LC50
Petroleum Asphalt (8052-42-4)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Clay (1302-78-9)
Oral LD50 Rat: >5000 mg/kg
Oil mist, mineral (8012-95-1)
Oral LD50 Mouse: 22 g/kg
Carcinogenicity
A: General Product Information
No additional information available.
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Material Name: MBR庐 Roof Insulation Adhesive Material Safety Data
Sheet ID: 3119
B: Component Carcinogenicity
Petroleum Asphalt (8052-42-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (as benzene soluble aerosol)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Supplement 7, 1987; Monograph 35, 1985,
extracts of steam and air refined bitumens)
Styrene-butadiene polymer (9003-55-8)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 19, 1979)
Oil mist, mineral (8012-95-1)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 33, 1984)
Chronic Toxicity
When this "cold application" product is used as directed, it is not likely to create hazardous levels of asphalt fumes.
Asphalt (asphalt CAS # 8052-42-4 and oxidized asphalt 64742-93-4; bitumens): In 1985/87, IARC (International Agency for
Research on Cancer) concluded the following: (a) Bitumens are not classifiable as to their carcinogenicity to humans (Group
3). (b) Extracts of steam- and air-refined bitumens are possibly carcinogenic to humans (Group 2B). IARC found that evidence
for carcinogenicity from animal studies was: inadequate for undiluted air-refined bitumens; limited for steam-refined and
cracking-residue bitumens; sufficient for extracts of steam-refined and air-refined bitumen. IARC found that human evidence
for carcinogenicity of asphalt fumes was inadequate. Studies of roofers indicated an excess of cancers; however, IARC
concluded that, since roofers may be exposed also to coal-tar pitches and other materials, "the excess cancer risk cannot be
attributed specifically to bitumens." In 1994, a published review of 20 epidemiology studies of asphalt workers and roofers
agreed with IARC, that current human evidence is inadequate for the carcinogenicity of asphalt fumes in humans. Trace
amounts of polynuclear aromatic hydrocarbons (PAHs) may be present in some asphalts and can be released upon excessive
heating, which results in thermal cracking of the asphalt compounds. Some of these PAHs have been identified as having the
potential to induce carcinogenic and reproductive health effects.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product's components.
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource
Conservation and Recovery Act (RCRA) regulations.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR
372.65), or CERCLA (40 CFR 302.4).
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Material Name: MBR庐 Roof Insulation Adhesive Material Safety Data
Sheet ID: 3119
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Petroleum Asphalt 8052-42-4 Yes No Yes Yes Yes Yes
Oil mist, mineral 8012-95-1 Yes No Yes Yes No Yes
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Petroleum Asphalt 8052-42-4 Yes Yes Yes
Water 7732-18-5 Yes Yes Yes
Styrene-butadiene polymer 9003-55-8 Yes Yes No
Clay 1302-78-9 Yes Yes Yes
Oil mist, mineral 8012-95-1 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Oil mist, mineral 8012-95-1 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
11/07/02 3119-1.0000 Transferred "MBR Insulation Adhesive" from MSDS 3117 to new
MSDS 3119 because product is non-combustible.
04/06/04 3119-1.0001 Minor edits.
05/10/04 3119-1.0002 Sect. 11 Asphalt-IARC edit. Regulatory update. Minor edits.
10/06/05 3119-1.0003 Section 2 composition amount update; Section 5 update, & Section
9 update.
This is the end of MSDS # 3119
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