Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
Section 1 - Chemical Product and Company Identification
Product Name JM EPDM Lap Caulking
CAS# Mixture/None Assigned
Generic Name Adhesive (Solvent- Based)
Formula Mixture
Chemical Name: Mixture
Hazard Label SL1128U, SL1167C
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: JM EPDM Lap Caulking (Black and White)
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
8052-41-3 Stoddard solvent (mineral spirits) 20-50
1317-65-3 Calcium carbonate 10-20
1332-58-7 Kaolin (treated clay) 0-10
7631-86-9 Silica, amorphous 0-10
25038-36-2 Ethylene-propylene rubber >3
64742-01-4 Oil (paraffinic) >3
9003-29-6 Polybutene >3
Not Available Coal (ground) >3
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Black or white viscous paste; strong hydrocarbon odor.
Irritating to skin, eyes, and respiratory system. Inhalation of excessive amounts of dust from the product may cause temporary
upper respiratory irritation and/or congestion--remove individual to fresh air.
Potential Health Effects
Summary
Exposure to vapors from this product may be irritating to eyes, respiratory passages, and mucous membranes. Excessive skin
contact may cause irritation, and dryness.
Inhalation
Irritation of the upper respiratory tract. Dizziness, vomiting, light-headedness, watery eyes, dry throat, headache, mental
depression, or narcosis and difficulty in breathing may occur.
Skin
Drying of skin, irritation, redness, and possibly sensitization may occur following prolonged exposures.
Absorption
Not applicable
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Irritation, redness, tearing (watery eyes) and burning in eyes may occur.
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Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Skin, eye, lungs, central nervous system (CNS), respiratory system, kidney, liver.
Medical Conditions Aggravated by Exposure
Pre-existing eye, skin, respiratory, central nervous system (CNS), liver and kidney diseases or conditions.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove individual to fresh air and administer artificial respiration or oxygen as necessary.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention
immediately.
First Aid: Eyes
Flush eyes with large amounts of water for 5-20 minutes. Contact a medical professional.
First Aid: Notes to Physician
Treatment for inhalation, skin contact, or ingestion should be symptomatic.
Section 5 - Fire Fighting Measures
Flash Point: 4.4潞C/40潞F Method Used: TCC
Upper Flammable Limit (UFL): 7% Lower Flammable Limit (LFL): 0.9%
Auto Ignition: 249潞C/480潞F Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
Vapor may form flammable atmosphere in confined spaces or low areas. Pressure build-up may also occur in closed, heated
containers. Water spray or fog should be used to keep containers cool.
Extinguishing Media
Dry chemical, foam, carbon dioxide. Do not use a solid stream of water because it can scatter and spread fire.
Fire Fighting Equipment/Instructions
Use NIOSH-approved self-contained breathing apparatus operating in the pressure demand mode and full fire fighting
protective clothing. Avoid inhalation of vapors.
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
Product waste is hazardous. Refer to Section 13 of this material safety data sheet for information on disposal of waste or
empty containers.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Materials should be kept in a cool, dry area. Keep away from ignition sources, such as heat, sparks, pilot lights, static
electricity, and open flames. Containers exposed to elevated temperatures (such as heat or flames) may develop pressure
build-up and rupture.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from
moisture.
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Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent inhalation of vapors, prolonged skin contact, and to keep
exposure levels below the applicable exposure limits. Wash hands thoroughly before eating or using the bathroom.
B: Component Exposure Limits
Stoddard solvent (mineral spirits) (8052-41-3)
ACGIH: 100 ppm TWA
OSHA: 100 ppm TWA; 525 mg/m3 TWA
Calcium carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Silica, amorphous (7631-86-9)
ACGIH: 10 mg/m3 TWA (inhalable particles, recommended); 3 mg/m3 TWA (respirable particles,
recommended) (related to Particulates (insoluble or poorly soluble) not otherwise specified
(PNOS))
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (related to Particulates not
otherwise regulated)
Kaolin (treated clay) (1332-58-7)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, or a face shield is recommended.
Personal Protective Equipment: Skin
Solvent-resistant gloves are recommended.
Personal Protective Equipment: Respiratory
If vapor levels are above the applicable exposure limits, a NIOSH-approved organic vapor respirator must be provided and
worn.
Ventilation
Local exhaust or general dilution ventilation may be required to maintain exposures below the applicable exposure limits. The
need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Wear long sleeves, long trousers, and industrial shoes to protect skin from contact with product.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black or white viscous paste Strong hydrocarbon odor
Physical State: pH:
Semi-liquid Not applicable
Vapor Pressure: Vapor Density:
45mm Hg 25潞C/77潞F 3.9
Boiling Point: Melting Point:
113潞-207潞C/235潞-405潞F -18潞C/-0.4潞F
Solubility (H2O): Specific Gravity:
Negligible 1.025-1.055
Freezing Point: Solids Content
Not determined Not determined
Evaporation Rate: Viscosity:
1.6 Not determined
Percent Volatile: VOC:
36-37 by weight 381-391
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Keep away from heat, ignition sources and incompatible materials.
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Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
Incompatibility
Strong oxidizers, reducing agents, strong acids and alkalis.
Hazardous Decomposition
Toxic gases or vapors, such as carbon dioxide, oxides of nitrogen and low molecular weight hydrocarbons.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Excessive exposure to the vapors from this product is irritating to the eyes, skin, and respiratory tract. It may cause pulmonary
edema, anorexia, vomiting, headache, dizziness, gastric discomfort, dry throat, watery eyes, light-headedness. Very high
concentrations may have other central nervous system effects, including death.
B: Component Analysis - LD50/LC50
Silica, amorphous (7631-86-9)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Oil (paraffinic) (64742-01-4)
Inhalation LC50 Rat: 2.18 mg/L/4H; Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Carcinogenicity
A: General Product Information
The Occupational Safety and Health Administration (OSHA), National Toxicology Program (NTP), International Agency for
Research on Cancer (IARC), and American Conference of Governmental Industrial Hygienists (ACGIH) have not classified
this product as a carcinogen.
B: Component Carcinogenicity
Silica, amorphous (7631-86-9)
IARC: Group 3 - Not Classifiable (IARC Monograph 68 [1997], Supplement 7 [1987])
Kaolin (treated clay) (1332-58-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Chronic Toxicity
Prolonged, excessive exposure may cause central nervous system (CNS), kidney and liver injury. Repeated, prolonged skin
contact will defat the skin, causing drying, cracking, dermatitis, even sensitization.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Silica, amorphous (7631-86-9)
96 Hr LC50 Brachydanio rerio: 5000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 440 mg/L
48 Hr EC50 Ceriodaphnia dubia: 7600 mg/L
Oil (paraffinic) (64742-01-4)
96 Hr LC50 Pimephales promelas: >5000 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Product waste is classified as hazardous under Resource Conservation and Recovery Act (RCRA) regulations at 40 CFR 261.
Dispose of material in accordance with federal, state, and local regulations in a hazardous waste facility. If you are unsure of
the regulations, contact your local Public Health Department, or the local office of the Environmental Protection Agency (EPA).
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Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of contents and/or container in accordance with Federal, State, and Local Regulations.
Section 14 - Transportation Information
International Transportation Regulations
DOT: Consumer Commodity, ORM-D
Package must not exceed 5 L (1.3 gal) inner; 30 kg (66 lb) outer
JM EPDM Lap Caulking, Black 5 gal can only:
UN1133, Adhesives, 3, PG II
FLAMMABLE LIQUID label required
IATA: ID 8000, Consumer Commodity, 9
Inner packagings must not exceed 500 mL each and the outer package may not exceed 30 kg (66 lb) gross weight.
JM EPDM Lap Caulking, Black 5 gal can only:
UN1133, Adhesives, 3, PG II
CARGO AIRCRAFT ONLY
FLAMMABLE LIQUID label required
The single package may not exceed 60 L (15.8 gal).
IMDG: UN1133, Adhesives, 3, PG II
Inner packagings must not exceed 5 L (1.3 gal) and outer packagings must not exceed 30 kg (66 lb).
JM EPDM Lap Caulking, Black 5 gal can only:
UN1133, Adhesives, 3, PG II
FLAMMABLE LIQUID label required
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard. Fire hazard.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR
372.65), or CERCLA (40 CFR 302.4).
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Stoddard solvent (mineral spirits) 8052-41-3 Yes No Yes Yes Yes Yes
Calcium carbonate 1317-65-3 No No Yes Yes No Yes
Silica, amorphous 7631-86-9 Yes No Yes Yes Yes Yes
Kaolin (treated clay) 1332-58-7 No No Yes Yes No Yes
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
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Material Name: JM EPDM Lap Caulking Material Safety Data
Sheet ID: 3105
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Stoddard solvent (mineral spirits) 8052-41-3 Yes Yes Yes
Calcium carbonate 1317-65-3 Yes No Yes
Silica, amorphous 7631-86-9 Yes Yes Yes
Kaolin (treated clay) 1332-58-7 Yes Yes No
Ethylene-propylene rubber 25038-36-2 Yes Yes No
Oil (paraffinic) 64742-01-4 Yes Yes Yes
Polybutene 9003-29-6 Yes Yes No
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Stoddard solvent (mineral spirits) 8052-41-3 1%
Silica, amorphous 7631-86-9 1%
WHMIS Classification
Controlled Product Class B, Division 2: Flammable liquids having flashpoint below 37.8掳C (100掳F).
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 3105-1.0000 New MSDS authoring system.
05/07/01 3105-1.0001 Update Transportation Section
12/08/03 3105-1.0002 Regulatory review. Minor edits.
05/06/04 3105-1.0003 Regulatory review. Minor edits.
12/20/05 3105-1.0004 Regulatory update. Minor edits in Section 15 WHMIS. Section 14
Transportation addition of IATA and IMDG info.
This is the end of MSDS # 3105
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