Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
Section 1 - Chemical Product and Company Identification
Product Name PermaFlash Primer
CAS# Mixture/None Assigned
Generic Name Primer Solution
Formula Mixture
Chemical Name: Mixture
Hazard Label CAUTION Flammable liquid
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: PermaFlash Primer
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
67-63-0 Isopropyl alcohol >99
Additional Component Information
Product is an organosilane adhesion promoter in isopropyl alcohol solution.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Clear liquid with rubbing alcohol odor.
Flammable mixture. Use water spray or fog to cool materials in or near fire. If possible, move burning material outside. Fire is
difficult to extinguish. Vapors may travel, and can be ignited by a remote source.
Inhalation of vapors may cause temporary upper respiratory irritation or central nervous system depression-remove affected
individuals to fresh air. This product may be a pulmonary aspiration hazard.
Potential Health Effects
Summary
Vapors from this product may cause eye and upper respiratory irritation, nausea, headache, dizziness, drowsiness, possible
unconsciousness, and even death.
Inhalation
Inhalation of vapors may cause irritation of the respiratory tract. Other symptoms may include signs of CNS depression
involving weakness, dizziness, fatigue, and headache. Severe overexposure may cause coma and death due to respiratory
failure.
Skin
May cause minor skin irritation and dryness following prolonged or frequent contact..
Absorption
No additional information available.
Ingestion
Harmful or fatal if swallowed. Ingestion can cause gastrointestinal irritation, nausea, vomiting, and diarrhea. This product may
be an aspiration hazard.
Eyes
May cause severe eye irritation. Symptoms include redness, swelling, tearing, and blurred vision.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
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Page 1 of 6 Issue Date: 01/05/2006 Revision: 1.0100
Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
Target Organs
Nose, throat, upper respiratory passages, skin, and eyes.
Medical Conditions Aggravated by Exposure
Pre-existing lung disorders and skin allergies.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove individual to fresh air and administer artificial respiration or oxygen as necessary. Seek medical attention.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention
immediately.
First Aid: Eyes
Flush eyes with large amounts of water for 5-15 minutes. If irritation develops, or persists, seek medical attention.
First Aid: Notes to Physician
Treatment should be directed toward removing the source of irritation, with symptomatic treatment as necessary.
Section 5 - Fire Fighting Measures
Flash Point: 53潞F Method Used: TCC
Upper Flammable Limit (UFL): 12% Lower Flammable Limit (LFL): 2%
Auto Ignition: 750潞F Flammability Classification: Flammable
Rate of Burning: Not determined
General Fire Hazards
Flammable liquid. Material is highly volatile and readily gives off vapors, which may travel along the ground or be moved by
ventilation and be ignited by heat sources (such as pilot lights or other flames, sparks, heaters, smoking, electric motors, or
static discharge) at locations distant from material handling point.
Vapor may form flammable atmosphere in confined spaces or low areas. Pressure build-up may also occur in closed, heated
containers. Water spray or fog should be used to keep containers cool.
NFPA Ratings: Health = 1 Fire = 3 Reactivity = 0; Special = 0, Class IB
Hazardous Combustion Products
May form carbon monoxide, carbon dioxide, and water.
Extinguishing Media
Dry chemical, foam, carbon dioxide. Do not use a solid stream of water because it can scatter and spread fire.
Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self contained breathing apparatus (SCBA).
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
No additional information available.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Keep this material and vapors from this material away from ignition sources, such as heat, sparks, pilot lights, static electricity,
and open flames. Containers exposed to elevated temperatures (such as heat or flames) may develop pressure build-up and
rupture. Keep containers sealed when not in use and clean spills promptly to reduce air concentrations and floor hazards.
Storage Procedures
Eliminate all sources of ignition. Keep the container tightly closed.
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Page 2 of 6 Issue Date: 01/05/2006 Revision: 1.0100
Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent inhalation of vapors, prolonged skin contact, and to keep
exposure levels below the applicable exposure limits. Wash hands thoroughly before eating or using the bathroom.
B: Component Exposure Limits
Isopropyl alcohol (67-63-0)
ACGIH: 200 ppm TWA
400 ppm STEL
OSHA: 400 ppm TWA; 980 mg/m3 TWA
500 ppm STEL; 1225 mg/m3 STEL
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields or chemical goggles are recommended.
Personal Protective Equipment: Skin
Solvent-resistant gloves, protective coveralls, and long sleeves are recommended.
Personal Protective Equipment: Respiratory
Use in well ventilated areas only. Wear an OSHA approved type C air supplied respirator if ventilation is inadequate to keep
solvent inhalation vapors below the TLV.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
Wear long sleeves, long trousers, and industrial shoes to protect skin from contact with product. Use personal protective
equipment as discussed above.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Clear liquid Rubbing alcohol odor
Physical State: pH:
liquid Not determined
Vapor Pressure: Vapor Density:
4 mm Hg @ 77潞F (25潞C) 2
Boiling Point: Melting Point:
180潞F (82潞C) Not available
Solubility (H2O): Specific Gravity:
Miscible in water, alcohols, ketones, and 0.78
aromatic hydrocarbons. Insoluble in
aliphatic hydrocarbons.
Freezing Point: Evaporation Rate:
Not determined 7.70
Viscosity: Percent Volatile:
Not determined >99
VOC: 990 g/L
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Keep away from heat, sparks, or open flame.
Incompatibility
May react with strong oxidizing materials.
Hazardous Decomposition
May form carbon monoxide, carbon dioxide, and water.
Hazardous Polymerization
Will not occur.
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Page 3 of 6 Issue Date: 01/05/2006 Revision: 1.0100
Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Vapors from this product may cause irritation of the eyes, and upper respiratory tract including the nose, mouth, and throat.
Inhalation of vapors may cause headache, numbness of the fingers and arms, incoordination, weakness, slowed respiration
(breathing), and narcosis (drowsiness). Prolonged skin contact may produce irritation, and dermatitis. Eye contact may result
in irritation of the eyes, and lacrimation (watering).
B: Component Analysis - LD50/LC50
Isopropyl alcohol (67-63-0)
Inhalation LC50 Rat: 72.6 mg/L/4H; Oral LD50 Rat: 4396 mg/kg; Dermal LD50 Rat: 12800 mg/kg; Dermal LD50 Rabbit: 12800
mg/kg
Carcinogenicity
A: General Product Information
The Occupational Safety and Health Administration (OSHA), National Toxicology Program (NTP), International Agency for
Research on Cancer (IARC), and American Conference of Governmental Industrial Hygienists (ACGIH) have not classified
this product as a carcinogen.
B: Component Carcinogenicity
Isopropyl alcohol (67-63-0)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Monograph 71, 1999; Supplement 7, 1987; Monograph 15,
1977)
Chronic Toxicity
Prolonged, excessive exposures to vapors may cause nervous system, kidney and liver damage, possible unconsciousness,
and even death. LC50: 12,000 ppm (8 hr)
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product. Product may produce significant toxicity to aquatic organisms and ecosystems.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Isopropyl alcohol (67-63-0)
96 Hr LC50 fathead minnow (29 days old):94900 mg/L (flow-through);96 Hr LC50 fathead minnow (31 days old):61200 mg/L
(flow-through)
5 min EC50 Photobacterium phosphoreum: 35390 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
International Transportation Regulations
DOT: UN1219, Isopropanol, 3, PGII
Flammable Liquid label required
Packaging must not exceed 1L inner; 30 kg outer)
IATA: UN1219, Isopropanol, 3, PGII
Flammable Liquid label required
Cargo Aircraft Only
Inner packagings must not exceed 10 L (2.6 gal) each (depending on the type of inner packaging used) and the outer package
may not exceed 60 L (15.8 gal)
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Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
IMDG: UN1219, Isopropanol, 3, PGII
No label required
Inner packagings must not exceed 5 L (1.3 gal) and outer packagings must not exceed 30 kg (66 lb)
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard. Fire hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Isopropyl alcohol (67-63-0)
SARA 313: 1.0 % de minimis concentration (only if manufactured by the strong acid process, no supplier
notification)
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Isopropyl alcohol 67-63-0 Yes No Yes Yes Yes Yes
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Isopropyl alcohol 67-63-0 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Isopropyl alcohol 67-63-0 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
07/07/05 3017-1.0000 New MSDS authoring system.
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Page 5 of 6 Issue Date: 01/05/2006 Revision: 1.0100
Material Name: PermaFlash Primer Material Safety Data
Sheet ID: 3017
01/05/06 3017-1.0001 Regulatory update. Minor edits in Section 11 LD50 and Section 15
WHMIS. Section 14 Transportation update to include IATA and
IMDG.
This is the end of MSDS # 3017
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