Material Name: Aluminum Emulsion Roof Coating Material Safety Data
Sheet ID: 3114
Section 1 - Chemical Product and Company Identification
Product Name Aluminum Roof Coating
CAS# Mixture/None Assigned
Generic Name Aluminum Coating
Formula Hydrocarbon Mixture
Chemical Name: Inorganic/Organic Mixture
Hazard Label L3114
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: Topgard庐 Type A Roof Coating
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
7732-18-5 Water 30-60
8052-42-4 Petroleum Asphalt 15-30
7429-90-5 Aluminum flake 2-10
14807-96-6 Talc 2-10
1302-78-9 Clay 1-5
Proprietary Biocide <0.1
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Silver gray, moderately thick liquid. Slight asphalt odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Potential Health Effects
Summary
Asphalt and its fumes can irritate skin, eyes, and upper respiratory tract.
Inhalation
Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts
of this material may be harmful.
Skin
Prolonged contact may result in mild skin irritation.
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Temporary irritation (itching) or redness may occur.
Ears
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Upper respiratory passages, skin, and eyes.
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
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Material Name: Aluminum Emulsion Roof Coating Material Safety Data
Sheet ID: 3114
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention
immediately.
First Aid: Eyes
Gently flush irritated eye with water for 10-15 minutes or until irritation subsides. Hold eyelid open while flushing. If irritation
cannot be relieved through flushing, seek medical attention.
First Aid: Ears
Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.
First Aid: Notes to Physician
This product is basically a water emulsion and is not expected to produce any long term health effects. Treatment for
inhalation, skin contact, or ingestion should be symptomatic.
Section 5 - Fire Fighting Measures
Flash Point: >212掳F Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not applicable Flammability Classification: Not applicable
Rate of Burning: Not applicable
General Fire Hazards
This material will not burn. When dried: Burning may produce thick, irritating smoke.
Extinguishing Media
Use methods for the surrounding fire.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
Dam, mop, absorb onto sawdust or other absorbent, and place in suitable container.
Clean-Up Procedures
Dispose of spilled material in approved landfill or incinerate in compliance with federal, state and local regulations. If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the Environmental Protection
Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Storage Procedures
No additional information available.
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Petroleum Asphalt (8052-42-4)
ACGIH: 0.5 mg/m3 TWA (inhalable fraction, as benzene-soluble aerosol)
Talc (14807-96-6)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 2 mg/m3 TWA (respirable dust, less than 1% crystalline silica)
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Material Name: Aluminum Emulsion Roof Coating Material Safety Data
Sheet ID: 3114
Aluminum flake (7429-90-5)
ACGIH: 10 mg/m3 TWA (metal dust)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, or a face shield is recommended.
Personal Protective Equipment: Ears
Ear protection (earplugs, hood, or earmuffs), if necessary.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to prevent skin contact and irritation. Normal work clothing (long sleeved shirts and
long pants) is recommended.
Personal Protective Equipment: Respiratory
When applying with a brush or broom: Respiratory protection is not required if mechanical or dilution ventilation is sufficient to
keep the exposure levels below the applicable exposure limits.
When applying with a sprayer: A respirator should be used if ventilation is inadequate or unavailable. Use a NIOSH-approved
organic vapor respirator to protect against inhalation of vapors.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
Normal work clothing (long sleeved shirts and long pants) is recommended.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Silver gray mild asphalt odor
Physical State: pH:
moderately thick liquid Not determined
Vapor Pressure: Vapor Density:
N/A >1
Boiling Point: Melting Point:
>100潞C/212潞F Not applicable
Solubility (H2O): Specific Gravity:
dispersible 9.3 lb./Gal
Evaporation Rate: Percent Volatile:
>1 75% (incl water)
VOC: 120 g/L
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Incompatibility
Oxidizers. Avoid heat and open flame.
Hazardous Decomposition
Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Excessive exposure to this product is irritating to the eyes, skin, and upper respiratory tract.
B: Component Analysis - LD50/LC50
Petroleum Asphalt (8052-42-4)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Clay (1302-78-9)
Oral LD50 Rat: >5000 mg/kg
Carcinogenicity
A: General Product Information
No data for this product as a whole.
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Material Name: Aluminum Emulsion Roof Coating Material Safety Data
Sheet ID: 3114
B: Component Carcinogenicity
Petroleum Asphalt (8052-42-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (as benzene soluble aerosol)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 35, 1985)
Talc (14807-96-6)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers); A1 - Confirmed
Human Carcinogen (containing asbestos fibers)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 42, 1987)
Chronic Toxicity
Asphalt fumes arise from hot asphalt. When this "cold application" product is used as directed, it is not likely to create
hazardous levels of asphalt fumes.
Asphalt (asphalt CAS # 8052-42-4 and oxidized asphalt 64742-93-4; bitumens): In 1985/87, IARC (International Agency for
Research on Cancer) concluded the following: (a) Bitumens are not classifiable as to their carcinogenicity to humans (Group
3). (b) Extracts of steam- and air-refined bitumens are possibly carcinogenic to humans (Group 2B). IARC found that evidence
for carcinogenicity from animal studies was: inadequate for undiluted air-refined bitumens; limited for steam-refined and
cracking-residue bitumens; sufficient for extracts of steam-refined and air-refined bitumen. IARC found that human evidence
for carcinogenicity of asphalt fumes was inadequate. Studies of roofers indicated an excess of cancers; however, IARC
concluded that, since roofers may be exposed also to coal-tar pitches and other materials, "the excess cancer risk cannot be
attributed specifically to bitumens." In 1994, a published review of 20 epidemiology studies of asphalt workers and roofers
agreed with IARC, that current human evidence is inadequate for the carcinogenicity of asphalt fumes in humans. Trace
amounts of polynuclear aromatic hydrocarbons (PAHs) may be present in some asphalts and can be released upon excessive
heating, which results in thermal cracking of the asphalt compounds. Some of these PAHs have been identified as having the
potential to induce carcinogenic and reproductive health effects.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product's components.
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource
Conservation and Recovery Act (RCRA) regulations.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Aluminum flake (7429-90-5)
SARA 313: 1.0 % de minimis concentration (dust or fume only)
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Page 4 of 5 Issue Date: 12/22/2005 Revision: 1.0202
Material Name: Aluminum Emulsion Roof Coating Material Safety Data
Sheet ID: 3114
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Petroleum Asphalt 8052-42-4 Yes No Yes Yes Yes Yes
Talc 14807-96-6 Yes No Yes Yes Yes Yes
Aluminum flake 7429-90-5 Yes No Yes Yes Yes Yes
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Water 7732-18-5 Yes Yes Yes
Petroleum Asphalt 8052-42-4 Yes Yes Yes
Talc 14807-96-6 Yes Yes Yes
Aluminum flake 7429-90-5 Yes Yes Yes
Clay 1302-78-9 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Aluminum flake 7429-90-5 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 3114-1.0000 New MSDS authoring system.
10/01/00 3114-1.0001 Sect. 2: added diethylaminoethanol.
10/22/02 3114-1.0002 Sect. 2 Updated composition. Sect. 3, 8, 11, 15 updated to agree
with current composition. Sect. 11, updated for IARC Group 3 for
asphalt.
05/10/04 3114-1.0003 Regulatory update. Minor edits.
12/22/05 3114-1.0004 Regulatory update. Minor edits in Section 11 LD50 and Section 15
SARA, CERCLA, & WHMIS. Section 5 update for flash point.
This is the end of MSDS # 3114
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