Material Name: JM TPO Bonding Adhesives (Water Based) Safety Data Sheet
ID: 3100
Section 1 - Product and Company Identification
Hazard Label CAUTION label
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: JM TPO Bonding Adhesive (Water Based); JM TPO-1 Bonding Adhesive (Water Based)
Section 2 - Hazards Identification
Emergency Overview
HMIS Rating: Health = 1 Fire = 0 Reactivity = 0
Inhalation
Irritation of the upper respiratory tract (scratchy throat), coughing, and congestion may occur in extreme exposures.
Skin
Temporary irritation (itching) or redness may occur.
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, seek medical attention.
Eyes
Irritation, redness, and burning in eyes may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Nose (nasal passages), throat, lungs, skin, eyes
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 3 - Composition/Information on Ingredients
CAS # Component Percent
7732-18-5 Water 20-50
Not Available Acrylic Polymer 40-50
Proprietary Copolymer 10-30
Not Available Copolymer Acrylate-acrylonitrile 10-30
1332-58-7 Kaolin 5-10
108-05-4 Vinyl acetate <1
Proprietary Epoxy Resin <1
General Product Description
Mobile to viscous off-white liquid with slight odor.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water. If irritation develops or persists, seek medical
attention. Launder contaminated clothing before reuse.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention
immediately.
First Aid: Eyes
Flush eyes with large amounts of water until irritation subsides. If irritation persists, seek medical attention.
First Aid: Notes to Physician
Treatment for inhalation, skin contact, or ingestion should be symptomatic. Inhalation of high concentrations of this material, as
could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias.
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Material Name: JM TPO Bonding Adhesives (Water Based) Safety Data Sheet
ID: 3100
Section 5 - Fire Fighting Measures
Flash Point: Non-Flammable Method Used: Not determined
Upper Flammable Limit (UFL): Not determined Lower Flammable Limit (LFL): Not determined
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
NFPA Ratings: Health = 1 Fire = 0 Reactivity = 0
Hazardous Combustion Products
Carbon monoxide, carbon dioxide, halogenated hydrocarbons, nitrogen oxides, and various hydrocarbons.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
Place in closable container for disposal.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Product should be kept in a cool and dry area in
original packaging. Do not freeze.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent inhalation of vapors, prolonged skin contact, and to keep
exposure levels below the applicable exposure limits.
B: Component Exposure Limits
Kaolin (1332-58-7)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and <1% crystalline
silica)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Vinyl acetate (108-05-4)
ACGIH: 10 ppm TWA
15 ppm STEL
OSHA: 20 ppm STEL; 60 mg/m3 STEL
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields or chemical goggles are recommended.
Personal Protective Equipment: Skin
Impervious gloves such as nitrile rubber should be used to help prevent excessive skin contact.
Personal Protective Equipment: Respiratory
A NIOSH approved respirator must be used if vapor concentrations exceed exposure limits.
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Material Name: JM TPO Bonding Adhesives (Water Based) Safety Data Sheet
ID: 3100
Ventilation
Local exhaust or general dilution ventilation may be required to maintain exposures below the applicable exposure limits. The
need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Protective equipment should be provided as necessary to prevent irritation of the throat, eyes, and skin, and to keep
exposures below the applicable exposure limits identified in Section 8.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Off-white mobile to viscous Slight odor
liquid
Physical State: pH:
liquid Not available
Vapor Pressure: Vapor Density:
Not available Heavier than air
Boiling Point: Melting Point:
162潞F-446潞F Not available
Solubility (H2O): Specific Gravity:
Not available Not available
Freezing Point: Evaporation Rate:
Not available 0.20
Bulk Density: Percent Volatile:
8.8 lbs/gal 56%
VOC: 41.7g/L corrected for water
Test Method 24
Section 10 - Stability & Reactivity Information
Stability
These products are not reactive.
Hazardous Decomposition
May form carbon dioxide and carbon monoxide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Vapors from this product may cause eye, respiratory and skin irritation,
B: Component Analysis - LD50/LC50
Water (7732-18-5)
Oral LD50 Rat: >90 mL/kg
Vinyl acetate (108-05-4)
Inhalation LC50 Rat: 11.4 mg/L/4H; Inhalation LC50 Rat:3200 ppm/4H; Oral LD50 Rat:2920 mg/kg; Dermal LD50 Rabbit:2320
mg/kg
Carcinogenicity
A: General Product Information
Vinyl acetate induced tumors of the nasal cavity by inhalation in rats and mice exposed to concentrations up to 600 ppm for
104 weeks. Vinyl acetate vapor has induced tumors of the nasal cavity in rats, but not in mice.
B: Component Carcinogenicity
Kaolin (1332-58-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Vinyl acetate (108-05-4)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
IARC: Group 2B 鈥? Possibly Carcinogenic to Humans (IARC Monograph 63 [1995], Supplement 7
[1987])
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Material Name: JM TPO Bonding Adhesives (Water Based) Safety Data Sheet
ID: 3100
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Vinyl acetate (108-05-4)
96 Hr LC50 Pimephales promelas: 31.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 31.0 mg/L; 96 Hr LC50 Pimephales
promelas: 14-15 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 18 mg/L [static]
5 min EC50 Photobacterium phosphoreum: 2080 mg/L
24 Hr EC50 water flea: 52.0 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection
Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is
recommended to ensure proper disposal under federal and/or state requirements.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transport Information
International Transport Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Vinyl acetate (108-05-4)
SARA 302: 1000 lb TPQ
SARA 313: 0.1 % de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Kaolin 1332-58-7 No No Yes Yes No Yes
Vinyl acetate 108-05-4 Yes No Yes Yes Yes Yes
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
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Material Name: JM TPO Bonding Adhesives (Water Based) Safety Data Sheet
ID: 3100
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Water 7732-18-5 Yes Yes Yes
Kaolin 1332-58-7 Yes Yes Yes
Vinyl acetate 108-05-4 Yes Yes Yes
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
WHMIS Classification
Controlled Product Classification: D2A
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS
contains all the information required by the Controlled Products Regulations.
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
09/19/01 3100-1.0000 New MSDS
02/24/03 3100-1.0001 Corrected product name. Other minor edits.
04/14/03 3100-1.0002 Minor edits.
10/22/03 3100-1.0003 Section 15, TSCA 12b, Acetone is deleted
03/31/05 3100-1.0004 Section 1 new material name & trade name from Low VOC
Adhesive to Bonding Adhesive (Water Based). Section 2 new
compositions for Bonding Adhesive (Water Based) and remaining
sections updated.
12/16/05 3100-1.0104 Regulatory update. Minor edit to Section 11 LD50. UltraGard
name change to JM.
08/03/07 3100-1.0105 Addition of TPO-1 Bonding Adhesive (Water Based) to trade
names. Minor edits throughout.
05/08/08 3100-1.0106 Updated composition. Update SDS to GHS format.
End of Sheet 3100
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