Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
Section 1 - Chemical Product and Company Identification
Product Name JM EPDM Sheets
CAS# Mixture/None Assigned
Generic Name Single Ply Membrane Sheets
Formula Mixture
Chemical Name: Mixture
Hazard Label None necessary.
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names:
JM EPDM 0.045 R XT; JM EPDM 0.060 R XT; JM EPDM 90 FR;
JM EPDM 0.045; JM EPDM 45 FR;
JM EPDM 0.060 FR; JM EPDM 60 FR;
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
1332-58-7 Kaolin 10-40
1333-86-4 Carbon black (bound in product matrix) 10-40
25038-36-2 EPDM polymer 10-40
Not Available Decabromodiphenyl oxide 3-12
21645-51-2 Aluminum trihydrate 3-12
1309-64-4 Antimony trioxide 3-10
57-11-4 Stearic acid 0-2
1314-13-2 Zinc oxide 0-2
Additional Component Information
Note: Due to the product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given
for reference only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Black rubber sheet of varying shapes and sizes. Sight rubber odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Potential Health Effects
Summary
May cause skin or eye irritation upon prolonged or repeated contact.
Inhalation
Not applicable
Skin
Irritation, dermatitis (skin rash or redness) may occur.
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause temporary
irritation to the gastrointestinal (GI) tract, especially the stomach.
Eyes
Not applicable
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Page 1 of 6 Issue Date: 01/17/2007 Revision: 1.0001
Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
Primary Routes of Entry (Exposure)
Skin contact.
Target Organs
Skin.
Medical Conditions Aggravated by Exposure
Prior sensitization to rubber products.
Section 4 - First Aid Measures
First Aid: Inhalation
Not applicable
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, irritation of the gastrointestinal (GI) tract may occur,
and should be treated symptomatically.
First Aid: Eyes
Not applicable
First Aid: Notes to Physician
Treatment for skin sensitization should be symptomatic, with removal of patient from further exposures.
Section 5 - Fire Fighting Measures
Flash Point: Not determined Method Used:
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
No special procedures necessary
Clean-Up Procedures
No additional information available.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from
moisture.
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Kaolin (1332-58-7)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Carbon black (bound in product matrix) (1333-86-4)
ACGIH: 3.5 mg/m3 TWA
OSHA: 3.5 mg/m3 TWA
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Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
Zinc oxide (1314-13-2)
ACGIH: 2 mg/m3 TWA (respirable fraction)
10 mg/m3 STEL (respirable fraction)
OSHA: 5 mg/m3 TWA (fume); 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
10 mg/m3 STEL (fume)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses.
Personal Protective Equipment: Skin
Leather or cotton gloves may be used to prevent excessive, prolonged skin contact.
Personal Protective Equipment: Respiratory
Not required
Ventilation
No special ventilation systems are required under normal conditions of use. The need for ventilation systems should be
evaluated by a professional industrial hygienist, while the design of specific ventilation systems should be conducted by a
professional engineer.
Personal Protective Equipment: General
No additional information available.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black rubber sheets of varying Slight rubber odor
shapes and sizes.
Physical State: pH:
Solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not applicable Not determined
Solubility (H2O): Specific Gravity:
Nil
Freezing Point: Evaporation Rate:
Not applicable Not applicable
Viscosity: VOC:
Not applicable Not determined
Section 10 - Chemical Stability & Reactivity Information
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
This product is not expected to present any acute toxicologic effects in that under normal conditions of use.
B: Component Analysis - LD50/LC50
Carbon black (bound in product matrix) (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit: >3 g/kg
Aluminum trihydrate (21645-51-2)
Oral LD50 Rat: >5000 mg/kg
Antimony trioxide (1309-64-4)
Oral LD50 Rat: >34600 mg/kg
Zinc oxide (1314-13-2)
Oral LD50 Rat: >5000 mg/kg
Stearic acid (57-11-4)
Dermal LD50 Rabbit: >5 g/kg
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Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
Carcinogenicity
A: General Product Information
No data for this product as a whole.
B: Component Carcinogenicity
Kaolin (1332-58-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Carbon black (bound in product matrix) (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 65
[1996])
Antimony trioxide (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])
Chronic Toxicity
Prolonged skin contact may result in skin sensitization, with possible irritation, redness, rash, or allergic type reactions upon
subsequent exposures.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Carbon black (bound in product matrix) (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L
Antimony trioxide (1309-64-4)
96 Hr LC50 Pimephales promelas: 833.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 530 mg/L; 96 Hr LC50 Brachydanio rerio:
>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
7 Hr EC50 Pseudomonas putida: >3.5 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health
Department, or the local office of the EPA.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
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Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Antimony trioxide (1309-64-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Kaolin 1332-58-7 No No Yes Yes No Yes
Carbon black (bound in product matrix) 1333-86-4 Yes No Yes Yes Yes Yes
Antimony trioxide 1309-64-4 Yes No Yes Yes Yes Yes
Zinc oxide 1314-13-2 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Carbon black (bound in product matrix) 1333-86-4
Antimony trioxide 1309-64-4
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Kaolin 1332-58-7 Yes Yes No
Carbon black (bound in product matrix) 1333-86-4 Yes Yes Yes
EPDM polymer 25038-36-2 Yes Yes No
Aluminum trihydrate 21645-51-2 Yes Yes Yes
Antimony trioxide 1309-64-4 Yes Yes Yes
Zinc oxide 1314-13-2 Yes Yes Yes
Stearic acid 57-11-4 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Carbon black (bound in product matrix) 1333-86-4 1%
Antimony trioxide 1309-64-4 1%
Zinc oxide 1314-13-2 1%
Stearic acid 57-11-4 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
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Page 5 of 6 Issue Date: 01/17/2007 Revision: 1.0001
Material Name: JM Nonreinforced EPDM Roofing Membranes Material Safety Data
Sheet ID: 3009B
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
12/13/06 3009B-1.0000 New MSDS Authoring System new EPDM nonreinforced products
from new vendor, including new JM EPDM Walkway Pads. This
MSDS will replace 3009 when the existing EPDM membrane
inventory is obsolete.
01/15/07 3009B-1.0001 Section 15 TSCA 12b info was edited and DBDO removed. This
product is an article under TSCA. DBDO does not need to be
reported under TSCA 12b per 40CFR 搂707.60(b).
This is the end of MSDS # 3009B
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