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MATERIAL SAFETY DATA SHEET
Section 1 Product & Company Identification
Product Name......................... : RIDGID Synthentic Transmission Grease
Product Catalog No. ............... : 61332
Company Name...................... : Ridge Tool Company
Address .................................. : 400 Clark Street
: Elyria, Ohio 44036-2023
Telephone .............................. : 1-800-519-3456 (USA) (8:00 am 5:00 pm EST, M-F)
Emergency Telephone ........... : 1-440-323-5581 (USA) (24 Hours)
Issue Date .............................. : March 27, 2008
Section 2 Hazards Identification
EMERGENCY OVERVIEW:
This product is a semi-solid that is insoluble in water and, under normal use, does not
pose a health risk. Direct eye contact may cause minor, short term irritation. Short term
skin exposure is not expected to be irritating. Inhalation and ingestion are not
anticipated routes of exposure during normal conditions of use.
POTENTIAL HEALTH EFFECTS AND SYMPTOMS FROM SHORT TERM / ACUTE
EXPOSURE:
Eye
This product is not expected to cause eye irritation under normal conditions of
use. Symptoms of slight eye irritation may result when direct contact occurs.
Skin
Short term skin contact is not expected to cause skin irritation. Prolonged or
repeated direct exposure to the skin may result in symptoms of irritation and
redness.
Inhalation:
This product has low volatility and so is not expected to cause respiratory tract
irritation during normal conditions of use.
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Product Name......................... : RIDGID Synthetic Transmission Grease
Ingestion:
Ingestion may cause slight stomach irritation and discomfort.
Potential Chronic Health Effects
No further data known.
Medical Conditions Aggravated By Exposure:
No further data known.
Carcinogenicity:
See Sections 3 and 11 for carcinogenicity information.
Section 3 Composition / Information On Ingredients
Components listed in this section may contribute to the potential hazards associated
with exposure to the concentrate. The product may contain additional non-hazardous or
trade secret components.
Component: CAS # % By Weight
Naphthalene 91-20-3 92.6
Lithium Hydroxide 1310-65-2 .05
Lithium-Soap Thickener 7620-77-1 5.20
Lithium Salts 68783-36-8 .64
Fatty Acids 64601-11-2 1.47
CARCINOGENIC COMPONENTS:
This warning is given to comply with California Health and Safety Code 25249.6 and
does not constitute an admission or a waiver of rights. This product contains a chemical
known to the State of California to cause cancer.
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Product Name : RIDGID Synthetic Transmission Grease
Section 4 First Aid Measures
EYE CONTACT:
Upon direct eye contact, hold eyelids open and flush with a steady, gentle stream
of water for at least 15 minutes. If irritation persists, flush the eyes with clean
water until the irritation subsides. If symptoms persist, contact a physician.
SKIN CONTACT:
Wash contact areas with soap and water. Remove and clean oil soaked clothing
daily and wash affected area. INJECTION INJURY WARNING: If product is
injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be evaluated
immediately by a physician as a surgical emergency. Even though initial
symptoms from high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the ultimate extent of
injury.
INHALATION:
Remove from further exposure. If respiratory irritation, dizziness, nausea or
unconsciousness occurs, seek immediate medical assistance. If breathing has
stopped, assist ventilation with mechanical device or use mouth-to-mouth
resuscitation.
INGESTION:
Not expected to be a problem. Seek medical attention if discomfort occurs. Do
not induce vomiting.
NOTE TO PHYSICIANS:
No further data known.
Section 5 Fire Fighting Measures
FIRE AND EXPLOSIVE PROPERTIES:
Flashpoint ..........................: 400掳F Cleveland Open Cup
Flammability Limits ............: LEL - N/A
UEL - N/A
NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0
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Product Name......................... : RIDGID Synthetic Transmission Grease
EXTINGUISH MEDIA:
In accordance with NFPA guidance, dry chemical, foam, CO2 or water fog fire
extinguishers are all acceptable.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
No further data known.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT:
Water or foam may cause frothing. Use water to keep fire exposed containers
cool. Water spray may be used to flush spills away from exposure. Prevent
runoff from fire control or dilution from entering streams, sewers or drinking water
supply.
Emergency responders in the danger area should wear bunker gear and self-
contained breathing apparatus for fires beyond the incipient stage. See Section
8 of the MSDS for other PPE to be worn as conditions warranty.
Section 6 Accidental Release Measures
ENVIRONMENTAL:
This material is a water pollutant. Do not let spilled or leaking material enter
waterways.
CLEAN-UP MEASURES:
Important: As with any spill or leak, before responding, ensure that you are
familiar with the potential hazards and recommendations of the MSDS.
Appropriate personal protective equipment must be worn.
If possible, safely contain the spill with dikes or other spill response equipment
appropriate for petroleum or organic material releases. Take measures to
prevent spreading of product. Note that while product will ignite, it will not readily
burn. However, as a precaution, eliminate ignition sources. Prevent from
entering sewers or waterways. Large volumes may be transferred to an
appropriate container for proper disposal. Small volumes or residues may be
soaked up with absorbents. Spill response materials should be collected for
proper disposal.
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Product Name......................... : RIDGID Synthetic Transmission Grease
Section 7 Handling And Storage
HANDLING:
High pressure injection under the skin may occur due to the rupture of
pressurized lines. Always seek medical attention. No special precautions are
necessary beyond normal good hygiene practices. See Section 8 for additional
personal protection advice when handling this product.
Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE
AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container
since residue is difficult to remove. Empty drums should be completely drained,
properly bunged and promptly returned to a drum reconditioner. All containers
should be disposed of in an environmentally safe manner and in accordance with
governmental regulations.
STORAGE:
Keep containers closed when not in use. Do not store in open or unlabelled
containers. Store away from strong oxidizing agents and combustible materials.
Do not store near heat, sparks, flame or strong oxidants.
SPECIAL COMMENTS:
Prevent small spills and leakages to avoid slip hazard.
Section 8 Exposure Controls / Personal Protection
EXPOSURE GUIDELINES:
This product does not contain any components which have recognized exposure
limits.
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Product Name......................... : RIDGID Synthetic Transmission Grease
ENGINEERING CONTROLS:
Normal general ventilation is expected to be adequate.
PERSONAL PROTECTIVE EQUIPMENT:
Selection of personal protective equipment should be based upon the anticipated
exposure and made in accordance with OSHA's Personal Protective Equipment
Standard found in 29 CFR 1910 Subpart I. The following information may be
used to assist in PPE selection.
Eye Protection
Wear eye protection appropriate to prevent eye exposure. Chemical
safety glasses with side shields are recommended.
Skin Protection
Gloves are not normally needed during normal conditions of use. If health
effects are experienced, oil or chemical resistant gloves such as butyl or
nitrile are recommended.
Respiratory Protection
No special requirements under ordinary conditions of use and with
adequate ventilation.
General Hygiene Considerations
Wash thoroughly after handling.
Section 9 Physical And Chemical Properties
Physical Appearance:............. : Grease / Red
Odor. ...................................... : Mild Petroleum
Physical State......................... : Semi-Solid
Water Solubility....................... : Insoluble
Specific Gravity....................... : .866
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Product Name......................... : RIDGID Synthetic Transmission Grease
Section 10 Stability And Reactivity
STABILITY:
This product is stable.
CONDITIONS TO AVOID:
Extreme heat and high energy sources of ignition.
INCOMPATIBLE MATERIALS:
This product is incompatible with strong oxidizing agents.
DECOMPOSITION PRODUCTS MAY INCLUDE:
Thermal decomposition products are dependent on combustion conditions. A complex
mixture of airborne solid, liquid, particulates and gasses may evolve when the material
burns. Combustion by-products may include:
oxides of carbon
oxides of sulfur
aldehydes
incompletely burned hydrocarbons as fumes and smoke
POSSIBILITY OF HAZARDOUS REACTIONS:
This product is not expected to polymerize
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Product Name......................... : RIDGID Synthetic Transmission Grease
Section 11 Toxicological Information
EYE EFFECTS:
(RABBITS) Practically non-irritating. (Draize score: greater than 6 but 15 or
less). Based on testing of similar products and/or the components.
SKIN EFFECTS:
(RABBITS) Practically non-irritating. (Primary Irritation Index: greater than 0.5
but less than 3). Based on testing of similar products and/or the components.
ORAL EFFECTS:
(RATS) Practically non-toxic. (LD50: greater than 2000 mg / kg). Based on
testing of similar products and/or the components.
INHALATION EFFECTS:
(RATS) Practically non-toxic. (LC50: greater than 5 mg / 1). Based on testing of
similar products and/or the components.
OTHER:
Although an acute inhalation study was not performed with this product, a variety
of mineral oils and synthetic base oils, such as those in this product, have been
tested. These samples had virtually no effect other than a non-specific
inflammatory response in the lung to the aerosolized mineral oil. The presence
of additives in other tested formulations (in approximately the same amounts as
in the present formulation) did not alter the observed effects.
SUBCHRONIC TOXICOLOGY (SUMMARY)
No significant adverse effects were found in studies using repeated
dermal applications of similar formulations to the skin of laboratory
animals for 13 weeks at doses significantly higher than those expected
during normal industrial exposure. The animals were evaluated
extensively for effects of exposure (hematology, serum chemistry,
urinalysis, organ weights, microscopic examination of tissues, etc.).
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Product Name......................... : RIDGID Synthetic Transmission Grease
REPRODUCTIVE TOXICOLOGY (SUMMARY)
No teratogenic effects would be expected from dermal exposure, based
on laboratory developmental toxicity studies of major components in this
formulation and/or materials of similar composition.
CHRONIC TOXICOLOGY (SUMMARY)
Repeated and/or prolonged exposure may cause irritation to the skin,
eyes or respiratory tract. For mineral base oils: Base oils in this product
are severely solvent refined and/or severely hydrotreated. Chronic mouse
skin painting studies of severely treated oils showed no evidence of
carcinogenic effects. These results are confirmed on a continuing basis
using various screening methods such as Modified Ames Test, IP-346,
and/or other analytical methods. For synthetic base oil: The base oils in
this product have been tested in the Ames assay and other tests of
mutagenicity with negative results. These base oils are not expected to
be carcinogenic with chronic dermal exposures.
SENSITIZATION (SUMMARY)
Not expected to be sensitizing based on tests of this product, components
or similar products.
Section 12 Ecological Information
ECOTOXICOLOGICAL INFORMATION:
The major components in the formulation show no aquatic toxicity at 1000 mg/L
loading, therefore, long-term adverse effects in the aquatic environment are not
expected.
This product is expected to be inherently biodegradable, as the principal
components have been shown to degrade at slow to moderate rates.
ENVIRONMENTAL FATE:
This environmental assessment was conducted using information on the
individual components as no test data was available for this specific formulation.
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Product Name : RIDGID Synthetic Transmission Grease
Section 13 Disposal Consideration
WASTE DISPOSAL:
Product is suitable for burning in an enclosed, controlled burner for fuel value.
Such burning may be limited pursuant to the Resource Conservation and
Recovery Act. In addition, the product is suitable for processing by an approved
recycling facility or can be disposed of at an appropriate government waste
disposal facility. Use of these methods is subject to user compliance with
applicable laws and regulations and consideration of product characteristics at
time of disposal.
RCRA INFORMATION
The unused product, in our opinion, is not specifically listed by the EPA as a
hazardous waster (40 CFR, Part 261D), nor is it formulated to contain materials
which are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity or reactivity. The unused product is not
formulated with substances covered by the Toxicity Characteristic Leaching
Procedure (TCLP). However, used product may be regulated.
Section 14 Transportation Information
U.S. DOT HAZARDOUS MATERIAL INFORMATION:
Not DOT regulated.
Section 15 Regulatory Information
FEDERAL REGULATIONS:
SARA 313:
This product contains NONE of the substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372.
US OSHA HAZARD COMMUNICATION STANDARD
When used for its intended purposes, this product is not classified as
hazardous in accordance with OSHA 29 CFR 1910.1200.
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Product Name......................... : RIDGID Synthetic Transmission Grease
SARA 311/312 Reportable Hazard Categories:
None
TOXIC SUBSTANCE CONTROL ACT:
The components of this product are listed on the TSCA Inventory.
OZONE DEPLETING SUBSTANCES:
This product contains no ozone depleting substances as defined by the
Clean Air Act.
CANADA
DSL:
The components of this product are listed on DSL Inventory.
Section 16 Other Information
HMIS RATING:
Health Flammability Reactivity PPE
0 1 0 X
Prepared by:. . . . . . . . . . . . Ridge Tool Company
Issue Date: . . . . . . . . . . . . . January 5, 2006
Last Revision Date: . . . . . . . May, 2004
RIDGE TOOL BELIEVES THE STATEMENTS, TECHNICAL INFORMATION AND RECOM-
MENDATIONS CONTAINED HEREIN ARE RELIABLE BUT THEY ARE GIVEN WITHOUT WARRANTY
OR GUARANTEE OF ANY KIND, EXPRESSED OR IMPLIED, AND WE ASSUME NO RESPONSIBILITY
FOR ANY LOSS, DAMAGE OR EXPENSE, DIRECT OR CONSEQUENTIAL, ARISING OUT OF THEIR
USE.
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