SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 03/18/2005
Date Updated: 05/17/2004
Version 1.3
Section 1 - Product and Company Information
Product Name ALUMINUM NITRATE NONAHYDRATE,
98+%, A.C.S. REAGENT
Product Number 237973
Brand ALDRICH
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ALUMINUM NITRATE NONAHYDRATE 7784-27-2 No
Formula Al(NO3)3.9H2O
Synonyms Aluminum nitrate nonahydrate * Aluminum
trinitrate nonahydrate * Nitric acid, aluminum
salt, nonahydrate (8CI,9CI)
RTECS Number: BD1050000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Oxidizing. Irritant.
Contact with combustible material may cause fire. Irritating to
eyes and skin.
HMIS RATING
HEALTH: 2
FLAMMABILITY: 0
REACTIVITY: 3
SPECIAL HAZARD(S): Oxidizer
NFPA RATING
HEALTH: 2
FLAMMABILITY: 0
REACTIVITY: 3
SPECIAL HAZARD(S): Oxidizer
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
DERMAL EXPOSURE
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Contact with other material may cause fire. May accelerate
combustion.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Do not breathe vapor. Do not get in eyes, on
skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed. Keep away from combustible
materials, heat, sparks, and open flame.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
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Use only in a chemical fume hood. Safety shower and eye bath.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Government approved respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Remove and wash contaminated
clothing promptly.
EXPOSURE LIMITS, RTECS
Country Source Type Value
USA ACGIH TWA 2 MG(AL)/M3
New Zealand OEL
Remarks: check ACGIH TLV
Section 9 - Physical/Chemical Properties
Appearance Physical State: Solid
Color: Colorless
Property Value At Temperature or Pressure
Molecular Weight 375.14 AMU
pH 2.5 - 3.5
BP/BP Range N/A
MP/MP Range 73 藲C
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Conditions to Avoid: Moisture.
Materials to Avoid: Strong reducing agents, Finely powdered
metals, Strong acids.
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HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nitrogen oxides, Aluminum oxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
TOXICITY DATA
Oral
Rat
3671 mg/kg
LD50
Remarks: Behavioral:Somnolence (general depressed activity).
Gastrointestinal:Changes in structure or function of salivary
glands.
Intraperitoneal
Rat
901 MG/KG
LD50
Remarks: Behavioral:Somnolence (general depressed activity).
Skin and Appendages: Other: Hair. Nutritional and Gross
Metabolic:Weight loss or decreased weight gain.
Oral
Mouse
3980 mg/kg
LD50
Remarks: Behavioral:Somnolence (general depressed activity).
Skin and Appendages: Other: Hair. Nutritional and Gross
Metabolic:Weight loss or decreased weight gain.
Intraperitoneal
Mouse
1587 MG/KG
LD50
Remarks: Behavioral:Somnolence (general depressed activity).
Skin and Appendages: Other: Hair. Nutritional and Gross
Metabolic:Weight loss or decreased weight gain.
CHRONIC EXPOSURE - TERATOGEN
Species: Rat
Dose: 1620 MG/KG
Route of Application: Oral
Exposure Time: (6-14D PREG)
Result: Effects on Embryo or Fetus: Fetotoxicity (except death,
e.g., stunted fetus). Effects on Embryo or Fetus: Fetal death.
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Specific Developmental Abnormalities: Craniofacial (including
nose and tongue).
Species: Rat
Dose: 1620 MG/KG
Route of Application: Oral
Exposure Time: (6-14D PREG)
Result: Specific Developmental Abnormalities: Musculoskeletal
system.
Species: Rat
Dose: 6480 MG/KG
Route of Application: Oral
Exposure Time: (6-14D PREG)
Result: Specific Developmental Abnormalities: Cardiovascular
(circulatory) system.
CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
Species: Rat
Dose: 7740 MG/KG
Route of Application: Oral
Exposure Time: (1-22D PREG/21D POST)
Result: Effects on Newborn: Physical.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: Aluminum nitrate
UN#: 1438
Class: 5.1
Packing Group: Packing Group III
Hazard Label: Oxidizer
PIH: Not PIH
IATA
Proper Shipping Name: Aluminium nitrate
IATA UN Number: 1438
Hazard Class: 5.1
Packing Group: III
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: O Xi
Indication of Danger: Oxidizing. Irritant.
R: 8 36/38
Risk Statements: Contact with combustible material may cause
fire. Irritating to eyes and skin.
S: 17 26 36
Safety Statements: Keep away from combustible material. In case
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of contact with eyes, rinse immediately with plenty of water and
seek medical advice. Wear suitable protective clothing.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Oxidizing. Irritant.
Risk Statements: Contact with combustible material may cause
fire. Irritating to eyes and skin.
Safety Statements: Keep away from combustible material. In case
of contact with eyes, rinse immediately with plenty of water and
seek medical advice. Wear suitable protective clothing.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: No
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
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