SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 03/15/2005
Date Updated: 09/15/2004
Version 1.4
Section 1 - Product and Company Information
Product Name ALUMINUM,REAGENTPLUS(TM), 99 %,
POWDER, PARTICLE SIZE -200 MESH
Product Number 214752
Brand ALDRICH
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ALUMINUM POWDER 7429-90-5 Yes
Formula Al
Synonyms A 00 * A 95 * A 995 * A 999 * AA 1099 * AA1199 *
AD 1 * AD1M * ADO * AE * Aisin Metal Fiber *
Alaun (German) * Allbri aluminum paste and powder
* Alumina fibre * Aluminium * Aluminium bronze *
Aluminium flake * Aluminum (ACGIH) * Aluminum 27
* Aluminum A00 * Aluminum dehydrated * Aluminum
metal (OSHA) * Aluminum powder * AO A1 * AR2 *
AV00 * AV000 * C.I. 77000 * Emanay atomized
aluminum powder * JISC 3108 * JISC 3110 * L16 *
Metana * Metana aluminum paste * Noral aluminum *
Noral Extra Fine Lining Grade * Noral Ink Grade
Aluminum * Noral non-leafing grade * PAP-1 *
aluminum
RTECS Number: BD0330000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Pyrophoric (USA) Highly Flammable (EU). Irritant.
Spontaneously flammable in air. Irritating to eyes and respiratory
system.
HMIS RATING
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 4
NFPA RATING
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 4
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
Section 5 - Fire Fighting Measures
FLAMMABLE HAZARDS
Flammable Hazards: Yes
Pyrophoric/Autoignition: Yes
EXPLOSION DATA
Dust Potential: This material, like most materials in powder
form, is capable of creating a dust explosion.
FLASH POINT
N/A
AUTOIGNITION TEMP
760 掳C
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Dry chemical powder.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Flammable solid. Emits toxic fumes under
fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Avoid raising dust. Sweep up, place in a bag and hold for waste
disposal. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
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HANDLING
User Exposure: Avoid breathing dust. Avoid contact with eyes,
skin, and clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep container closed. Keep away from heat, sparks,
and open flame. Store in a cool dry place. Store under nitrogen.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Mechanical
exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Government approved respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
EXPOSURE LIMITS, RTECS
Country Source Type Value
USA ACGIH TWA 10 MG(AL)/M3
Remarks: metal dust
USA OSHA. PEL 8H TWA 15 MG(AL)/M3, TOTAL DUS
New Zealand OEL
Remarks: check ACGIH TLV
USA NIOSH TWA 2 MG/M3
Section 9 - Physical/Chemical Properties
Appearance Physical State: Solid
Form: Powder
Property Value At Temperature or Pressure
Molecular Weight 26.98 AMU
pH N/A
BP/BP Range N/A
MP/MP Range 660.37 掳C
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density 2.702 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
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Flammability N/A
Autoignition Temp 760 掳C
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Conditions of Instability: Air and moisture sensitive.
Materials to Avoid: Acids, Acid chlorides, Halogens, Oxidizing
agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Aluminum oxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Burn in a chemical incinerator equipped with an
afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Observe all federal, state, and
local environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: Aluminum powder, uncoated
UN#: 1396
Class: 4.3
Packing Group: Packing Group II
Hazard Label: Dangerous when wet.
PIH: Not PIH
IATA
Proper Shipping Name: Aluminium powder, uncoated
IATA UN Number: 1396
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Hazard Class: 4.3
Packing Group: II
Section 15 - Regulatory Information
EU DIRECTIVES CLASSIFICATION
Symbol of Danger: F
Indication of Danger: Highly Flammable.
R: 15 17
Risk Statements: Contact with water liberates extremely
flammable gases. Spontaneously flammable in air.
S: 7/8 43
Safety Statements: Keep container tightly closed and dry. In
case of fire, use special powder for metal fire. Never use water.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Pyrophoric (USA) Highly Flammable (EU).
Irritant.
Risk Statements: Spontaneously flammable in air. Irritating to
eyes and respiratory system.
Safety Statements: Keep away from sources of ignition - no
smoking. In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Take precautionary
measures against static discharges. Wear suitable protective
clothing.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: Yes
DEMINIMIS: 1 %
NOTES: This product is subject to SARA section 313 reporting
requirements.
TSCA INVENTORY ITEM: Yes
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
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