MATERIAL SAFETY DATA SHEET
INHALATION:
SECTION 1 - PRODUCT AND COMPANY INFORMATION
Vapor and/or spray mist may be harmful if inhaled. Vapor irritates eyes,
nose, and throat.
PPG Industries, Inc. INGESTION:
One PPG Place Harmful if swallowed.
Pittsburgh, PA 15272 SIGNS & SYMPTOMS OF OVEREXPOSURE:
Repeated exposure to high vapor concentrations may cause irritation of
EMERGENCY PHONE NUMBERS (412) 434-4515 (U.S.) the respiratory system and permanent brain and nervous system
(24 hours/day): damage. Eye watering, headaches, nausea, dizziness and loss of
(514) 645-1320 (Canada) coordination are indications that solvent levels are too high. Intentional
01-800-00-21-400 (Mexico) misuse by deliberately concentrating and inhaling the contents can be
0532-3889090 (China) harmful or fatal. Dryness, itching, cracking, burning, redness, and
swelling are conditions associated with excessive skin contact.
TECHNICAL (724) 274-7900 (SPRINGDALE, PA) 8:00 a.m. -
INFORMATION: 5:00 p.m. EST
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not
PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m.
applicable.
- 4:30 p.m. EST
CHRONIC OVEREXPOSURE EFFECTS
Product ID:
Avoid long-term and repeated contact.
PRODUCT NAME: DURANAR ADS
Repeated exposure to vapors above recommended exposure limits (see
SYNONYMS: None
Section 8) may cause irritation of the respiratory system and permanent
ISSUE DATE: 09/29/2004
brain and nervous system damage. Intentional misuse by deliberately
EDITION NO.: 1
concentrating and inhaling the contents can be harmful or fatal. This
CHEMICAL Acrylic Fluoropolymer
product contains toluene. Toluene inhalation in animals (greater than
FAMILY:
1500 ppm) and intentional inhalation of toluene-containing products by
EMERGENCY OVERVIEW:
humans (e.g. glue) has caused adverse fetal development effects.
Flammable. Keep away from heat, sparks, flames, and other sources of
The effects of long-term, low level exposures to this product have not
ignition. Do not smoke. Extinguish all flames and pilot lights. Turn off
been determined. Safe handling of this material on a long-term basis
stoves, heaters, electrical motors, and other sources of ignition during
should emphasize the prevention of all contact with this material to avoid
use and until all vapors/odors are gone.CAUSES EYE IRRITATION.
any effects from repetitive acute exposures. See Section 11, of this
MAY CAUSE SLIGHT SKIN IRRITATION. VAPOR AND/OR SPRAY
MSDS for a detailed list of chronic health effects information available on
MIST MAY BE HARMFUL IF INHALED. VAPOR IRRITATES EYES,
individual ingredients in this product.
NOSE, AND THROAT.HARMFUL IF SWALLOWED.
SECTION 4 - FIRST AID MEASURES
If ingestion, irritation, any type of overexposure or symptoms of
SECTION 2 - COMPOSITION INFORMATION
overexposure occur during or persists after use of this product, contact a
The following ingredient(s) marked with an "x" are considered
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
hazardous under applicable U.S. OSHA and/or Canadian WHMIS
immediately; have Material Safety Data Sheet information available.
regulations. If no ingredients are listed, then there are no U.S.
EYE CONTACT:
OSHA and/or Canadian WHMIS hazardous ingredients in this
Remove contact lens and pour a gentle stream of warm water through
product.
the affected eye for at least 15 minutes. If irritation persists, contact a
Material/ Percent Hazardous
poison control center, emergency room, or physician as further treatment
CAS Number
1-METHOXY-2-PROPYL 10 - 30 X may be necessary.
ACETATE SKIN CONTACT:
108-65-6
Run a gentle stream of water over the affected area for 15 minutes. A
TOLUENE 10 - 30 X
mild soap may be used if available. If any symptoms persist, contact a
108-88-3
poison control center, emergency room, or physician as further treatment
ETHYL ACETATE 10 - 30 X
may be necessary.
141-78-6
INHALATION:
TITANIUM DIOXIDE 7 - 13 X
13463-67-7 Remove from area to fresh air. If symptomatic, contact a poison control
ETHYL ALCOHOL 1-5 X center, emergency room or physician for treatment information.
64-17-5
2-METHOXY-1-PROPYL 0.1-1.0 X
.
ACETATE
INGESTION:
70657-70-4
Gently wipe or rinse the inside of the mouth with water. Sips of water
may be given. Never give anything by mouth to an unconscious person.
SECTION 3 - HAZARDS IDENTIFICATION
Contact a poison control center, emergency room or physician right away
ACUTE OVEREXPOSURE EFFECTS
as further treatment may be necessary.
EYE CONTACT:
SECTION 5 - FIRE FIGHTING MEASURES
Causes eye irritation. Redness, itching, burning sensation and visual
FLAMMABLE PROPERTIES
disturbances may indicate excessive eye contact.
FLASHPOINT: 35 Degrees F ( 2 Degrees C)
SKIN CONTACT:
FLASHPOINT TEST METHOD:
May cause slight skin irritation. Dryness, itching, cracking, burning,
Pensky-Martens Closed Cup
redness, and swelling are conditions associated with excessive skin
UEL: Not Available.
contact.
LEL: 1.9
SKIN ABSORPTION:
AUTOIGNITION TEMPERATURE:
Not Available.
__________________________________________________________________
Page 1 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
EXTINGUISHING MEDIA: RESPIRATOR:
Use National Fire Protection Association (NFPA) Class B extinguishers Overexposure to vapors may be prevented by ensuring proper ventilation
(carbon dioxide, dry chemical, or universal aqueous film forming foam) controls, vapor exhaust or fresh air entry. A NIOSH- approved air
designed to extinguish NFPA Class IB flammable liquid fires. Water purifying respirator with the appropriate chemical cartridges or a positive-
spray may be ineffective. Water spray may be used to cool closed pressure, air-supplied respirator may also reduce exposure. Read the
containers to prevent pressure build-up and possible autoignition or respirator manufacturer's instructions and literature carefully to determine
explosion when exposed to extreme heat. the type of airborne contaminants against which the respirator is
PROTECTION OF FIREFIGHTERS: effective, its limitations, and how it is to be properly fitted and used.
Fire-fighters should wear self-contained breathing apparatus and full Provide general dilution or local exhaust ventilation in volume and pattern
protective clothing. to keep the concentration of ingredients listed in Section 2 below the
UNUSUAL FIRE AND EXPLOSION HAZARDS: lowest suggested exposure limits, the LEL below the stated limit, and to
Keep this product away from heat, sparks, flame, and other sources of remove decomposition products during welding or flame cutting.
ignition (i.e., pilot lights, electric motors, static electricity). Invisible vapors GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS
can travel to a source of ignition and flash back. Do not smoke while If Threshold Limit Values (TLVs) have been established by ACGIH,
using this product. Keep containers tightly closed when not in use. OSHA, Ontario or PPG, they will be listed below. These limits are
Closed containers may explode when overheated. Do not apply to hot intended for use in the practice of industrial hygiene as guidelines or
surfaces. Toxic gases may form when this product comes in contact with recommendations in the control of potential workplace health hazards.
extreme heat. May produce hazardous decomposition products when These limits are not a relative index of toxicity and should not be used by
exposed to extreme heat. Extreme heat includes, but is not limited to, anyone without industrial hygiene training.
flame cutting, brazing, and welding.
Material/ Percent ACGIH TLV ACGIH OSHA PEL OSHA
SECTION 6 - ACCIDENTAL RELEASE MEASURE CAS Number STEL STEL
TOLUENE 10 - 30 S- 50 ppm Not 100 ppm 150 ppm
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
108-88-3 established
Provide maximum ventilation. Only personnel equipped with proper
ETHYL ACETATE 10 - 30 400 ppm Not 400 ppm Not
respiratory, skin, and eye protection should be permitted in the area.
141-78-6 established established
Remove all sources of ignition. Take up spilled material with sand,
10 mg/m3 10 mg/m3
TITANIUM DIOXIDE 7 - 13 Not Not
vermiculite, or other noncombustible absorbent material and place in 13463-67-7 established established
clean, empty containers for disposal. Only the spilled material and the ETHYL ALCOHOL 1-5 1000 ppm Not 1000 ppm Not
absorbant should be placed in this container. 64-17-5 established established
SECTION 7 - HANDLING AND STORAGE Key: OSHA=Occupational Safety and Health Administration;
PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: PEL=Permissable Exposure Limit; Ceiling=PEL Ceiling Limit; STEL=PEL
Vapors may collect in low areas. If this material is part of a multiple Short-Term Exposure Limit; Skin=OSHA Skin Designation.
component system, read the Material Safety Data Sheet(s) for the other Material/ Percent Ontario Ontario PPG IPEL PPG STEL
component or components before blending as the resulting mixture may CAS Number TWA STEL
have the hazards of all of its parts. Containers should be grounded when 1-METHOXY-2- 10 - 30 50 PPM Not 100 ppm Not
pouring. Avoid free fall of liquids in excess of a few inches. PROPYL ACETATE established established
108-65-6
STORAGE:
TOLUENE 10 - 30 R- 50 PPM Not Not Not
Do not store above 120 degrees F.(48 degrees C.). Store large quantities
108-88-3 established established established
in buildings designed and protected for storage of NFPA Class IB
ETHYL ACETATE 10 - 30 R- 400 Not Not Not
flammable liquids.
141-78-6 PPM established established established
3
TITANIUM DIOXIDE 7 - 13 10 mg/m Not Not Not
SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION 13463-67-7 established established established
ETHYL ALCOHOL 1-5 1000 ppm Not Not Not
ENGINEERING CONTROLS:
64-17-5 established established established
Provide general dilution or local exhaust ventilation in volume and pattern
to keep the concentration of ingredients listed in Section 8 below the
lowest suggested exposure limits, the LEL below the stated limit, and to Key: ACGIH=American Conference of Governmental Industrial
remove decomposition products during welding or flame cutting. Hygienists; OSHA=Occupational Safety and Health Administration;
TLV=Threshold Limit Value; TWA=Time Weighted Average;
PEL=Permissible Exposure Limit; IPEL=Internal Permissible Exposure
PERSONAL PROTECTIVE EQUIPMENT
Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV or PEL Short-Term
EYES:
Exposure Limit; Skin= Skin Absorption Designation. [C- Ceiling Limit; S-
Wear chemical-type splash goggles when possibility exists for eye
Potential Skin Aborption; R-Respirable Dust]
contact due to splashing or spraying liquid, airborne particles, or vapors.
Additional Information Not applicable.
SKIN/GLOVES:
Wear protective clothing to prevent skin contact. Apron and gloves
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
should be constructed of: butyl rubber. No specific
permeation/degradation testing have been done on protective clothing for (FORMULA VALUES, NOT SALES SPECIFICATIONS)
this product. Recommendations for skin protection are based on SPECIFIC GRAVITY: 1.112
infrequent contact with this product. For frequent contact or total PHYSICAL STATE: Liquid
immersion, contact a manufacturer of protective clothing for appropriate Percent Solids: 34.94
chemical impervious equipment. Clean contaminated clothing and shoes. Percent Volatile by Volume: 79.710
pH: Not available.
ODOR THRESHOLD: Not available.
Vapour Pressure (mm Hg): 30.7 mmHg
__________________________________________________________________
Page 2 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
ODOR/APPEARANCE: Viscous liquid with an odor Material/ Percent
CAS Ingredient Specific Animal Data:
characteristic of the solvents listed
Number
in Section 2.
TITANIUM 7 - 13 This product contains titanium dioxide. Animals inhaling
VAPOR DENSITY: HEAVIER THAN AIR
DIOXIDE massive quantities of titanium dioxide dust in a long-term
Evaporation Rate: 250 13463-67-7 study developed lung tumors. Studies with humans
BOILING POINT OR RANGE: 149 - 302Degrees F involved in manufacture of this pigment indicate no
Freezing Point or Range: Not Applicable. increased risk of cancer from exposure.
Melting Point or Range: Not Applicable. 2- 0.1-1.0 Possible reproductive hazard. An ingredient(s) in this
METHOXY- product has adversely affected reproductive tissues and
Octanol/Water Partition Not Applicable.
1-PROPYL fetal development in test animals.
Coefficient:
ACETATE
WEIGHT PER GALLON: 9.27 (U.S.) / 11.1 (IMPERIAL)
70657-70-4
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 10 - STABILITY AND REACTIVITY
POTENTIAL ENVIRONMENTAL EFFECTS:
STABILITY:
Ecotoxicity No data available
This product is normally stable and will not undergo hazardous reactions.
CONDITIONS TO AVOID:
None Known. ENVIRONMENTAL FATE
INCOMPATIBLE MATERIALS: Mobility: No Information Available.
Avoid contact with strong alkalies, strong mineral acids, or strong Biodegradation: No Information Available.
oxidizing agents. Bioaccumulation No data available
HAZARDOUS POLYMERIZATION:
None Known.
PHYSICAL/CHEMICAL
HAZARDOUS DECOMPOSITION PRODUCTS:
- Carbon monoxide - Carbon dioxide - Lower molecular weight polymer Hydrolysis: No Information Available.
fractions Photolysis: No Information Available.
SECTION 13 - DISPOSAL CONSIDERATIONS
Provide maximum ventilation, only personnel equipped with proper
SECTION 11 - TOXICOLOGICAL INFORMATION
respiratory and skin and eye protection should be permitted in the area.
ACUTE TOXICITY
Take up spilled material with sawdust, vermiculite, or other absorbent
material and place in containers for disposal.
Material/ Percent ORAL DERMAL INHALATION
Waste material must be disposed of in accordance with federal, state,
CAS Number LD50 (g/kg) LD50 (g/kg) LC50 (mg/l)
provincial and local environmental control regulations. Empty containers
1-METHOXY-2- 10 - 30 8.53 g/kg Not Available Not Available
should be recycled by an appropriately licensed reconditioner/salvager or
PROPYL ACETATE
108-65-6 disposed of through a permitted waste management facility. Additional
TOLUENE 10 - 30 5.00 g/kg 12.12 g/kg Not Available disposal information is contained on the Environmental Data Sheet for
108-88-3
this product, which can be obtained from your PPG representative.
ETHYL ACETATE 10 - 30 5.62 g/kg Not Available 14.41 mg/L. 4 h
141-78-6
SECTION 14 - TRANSPORTATION INFORMATION
ETHYL ALCOHOL 1-5 7.06 g/kg Not Available Not Available
64-17-5 Proper Shipping Name: Paint
NOS Technical Name: None
Hazard Class: 3
CHRONIC TOXICITY
Subsidiary Class(es): None
Target Organs:
UN Number: UN1263
- Carcinogen - Embryotoxin - Reproductive - Teratogen - Brain - Central
Packing Group: II
nervous system - Lung
USA - RQ Hazardous Substances: Toluene, Ethyl Acetate
Mutagenicity:
USA-RQ Hazardous Substance Toluene>4712.58 Pounds, Ethyl
This has not been tested for this product.
Threshold Ship Weight: Acetate>35360.72 Pounds
Reproductive:
Marine Pollutant Name: None
This has not been tested for this product.
USA Shipments Only - RQ Threshold Ship Weight: This is the total
weight of this product that must be shipped to exceed the RQ quantity.
SUPPLEMENTAL HEALTH INFORMATION:
SECTION 15 - REGULATORY INFORMATION
INVENTORY STATUS
U.S. TSCA: This product and/or all of its components are listed on the
U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory
reporting requirements.
FEDERAL REGULATIONS
US Regulations
__________________________________________________________________
Page 3 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
UC60400 000011 (00306154.001)(09/29/04)
Material/ Percent
CAS Number CERCLA HS - SARA EHS- SARA 313 011101, 000, 0811
RQ (LBS) TPQ (LBS)
1-METHOXY-2- 10 - 30 Not Listed Not Listed Not Listed
*** END OF MSDS ***
PROPYL ACETATE
108-65-6
9.2 % 2000 1 0811 UC60400 ,0811,000 UC60400 F 000 01109/29/04
TOLUENE 10 - 30 1000 lbs Not Listed Listed
0
108-88-3
ETHYL ACETATE 10 - 30 5000 lbs Not Listed Not Listed
141-78-6
TITANIUM DIOXIDE 7 - 13 Not Listed Not Listed Not Listed
13463-67-7
ETHYL ALCOHOL 1-5 Not Listed Not Listed Not Listed
64-17-5
2-METHOXY-1- 0.1-1.0 Not Listed Not Listed Not Listed
PROPYL ACETATE
70657-70-4
SARA 311/312
Health (acute): Yes
Health (chronic): Yes
Fire (flammable): Yes
Pressure: No
Reactivity: No
WHMIS HAZARD CLASS: - Class B, Division 2 - Class D, Division 2,
Subdivision A
STATE/PROVINCIAL REGULATIONS
CALIFORNIA PROP. 65: WARNING: This product contains a chemical
known to the State of California to cause birth defects or other
reproductive harm.
Additional Information
Key: IARC- International Agency on the Research of Cancer; ACGIH-
American Conference of Governmental Industrial Hygienists; NTP-
National Toxicology Program *Denotes chemical as NTP Known
Carcinogen; + Denotes NTP Possible Carcinogen; OSHA-
Occupational Safety and Health Administration.
SECTION 16 - OTHER INFORMATION
Hazard Rating Systems
NFPA Rating: 2 30
HMIS Rating: 2 30
Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe,
*=Chronic Effects.
HMIS=Hazardous Materials Identification System; NFPA=National Fire
Protection Association;
Safe handling of this product requires that all of the information on the
MSDS be evaluated for specific work environments and conditions of
use.
PREPARED BY: Product Safety Department
REASON FOR REVISION: Date. Edition.
Updated MSDS
format.
This Material Safety Data Sheet has been prepared in accordance with
Canada's Workplace Hazardous Materials Information System (WHMIS)
and the OSHA Hazard Communication Standard (29 CFR 1910.1200),
the supplier notification requirements of SARA Title III, Section 313 and
other applicable right-to-know regulations.
Additional environmental information is contained on the Environmental
Data Sheet for this product, which can be obtained from your PPG
representative.
__________________________________________________________________
Page 4 of 4
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