Material Safety Data Sheet
Page 1 of 6 Issue date: September 2004
M-BOND 300 RESIN
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Davidson Measurement Pty. Ltd
ACN: 005 031 961 ABN: 29 005 031 961
Phone: 03 9580 4366
Fax: 03 9580 6499
Email: info@davidson.com.au
Web: www.davidson.com.au
Address: 1-3 Lakewood Boulevard,
Braeside, Victoria, 3195.
Product Name: M -BOND 300 RESIN
Manufacturer's Product Code: MGM010E
Use: Special-purpose, two-component polyester adhesive, useful when a low temperature-curing adhesive is required.
2. HAZARDS IDENTIFICATION
HAZARDOUS ACCORDING TO EU CRITERIA
Hazard Category: Harmful (Xn), Irritant (Xi), Flammable (F)
Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOODS.
RISK PHRASES
R10 Flammable
R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
SAFETY PHRASES
S23 Do not breathe fumes/vapour.
S24/25 Avoid contact with skin and eyes.
S45 In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately and show
this container or label.
Poison Schedule: S5 [Aust]
This product is a Scheduled (S5) Poison and must be stored, handled and used according to the appropriate regulations.
Warning Statement:
Harmful by inhalation. Will cause irritation to skin and eyes. Flammable, keep away from sources of ignition.
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME Proportion CAS Number
POLYESTER RESIN - NON HAZARDOUS > 60% Mixture
STYRENE MONOMER 30 to 60 % 100-42-5
STYRENE OXIDE Trace 96-09-3
All other ingredients determined not to be hazardous according to the EU criteria.
4. FIRST AID MEASURES
Swallowed:
If swallowed, DO NOT induce vomiting. Give a glass of water to drink. If vomiting occurs spontaneously, keep head
below hips to prevent aspiration of liquid into the lungs. Seek urgent medical assistance.
Eye:
If material is splashed into eyes, flush with plenty of water for at least 15 minutes, ensuring eye lids are held open.
Immediately transport to hospital or doctor.
Material Safety Data Sheet
Page 2 of 6 Issue date: September 2004
M-BOND 300 RESIN
4. FIRST AID MEASURES (Continued)
Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with soap and water.
If irritation persists immediately transport to hospital or doctor
Inhaled:
Remove victim to fresh air. Apply resuscitation if victim is not breathing - Administer oxygen if breathing is difficult.
First Aid Facilities:
Eye wash fountain, safety s hower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide or foam.
HAZARDS FROM COMBUSTION PRODUCTS: Under fire conditions, toxic and corrosive fumes are emitted. On
combustion or on thermal decomposition (pyrolysis), there will be a release of oxides of carbon
PRECAUTIONS FOR FIRE FIGHTERS AND SPECIAL PROTECTIVE EQUIPMENT: Self-contained
breathing apparatus (SCBA) required for fire -fighting personnel. If possible to do so safely, shut off fuel to fire. Use
water spray to spray to cool fire-exposed surfaces and to protect personnel.
Hazchem Code: 3[Y] [Aust]
Flammability:
This material is a FLAMMABLE liquid.
Flash Point: 32掳C
Flammability Limits (vol / vol %): Lower: 1.8 Upper: Not available.
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
Flammable liquid. Avoid all sources of ignition. Keep unnecessary people away; Isolate hazard area and deny entry.
Ventilate area. Wear suitable protective equipment as outlined under personal protection in this MSDS.
Methods and Materials for Containment and Clean Up Procedures:
Throw vermiculite or diatomaceous earth onto spill. DO NOT use sawdust. Use non-sparking tools or HEPA vacuum
system to pick up. Place into labelled drum(s) for later disposal.
Emergency information(Transport):
Dangerous Goods - Initial Emergency Response Guide (IERG) (SAA/SNZ HB76:1997)
For LIQUIDS - Flammable, Guide No: 15
7. HANDLING AND STORAGE
Precautions for Safe Handling:
Flammable liquid. Avoid ignition sources. Do not get in eyes. Avoid direct or prolonged contact with skin. Provide
adequate ventilation.
Conditions for Safe Storage:
Keep containers tightly closed, when not using the product. Store in original packages as approved by manufacturer.
Store in an area that is dry and well-ventilation away from ignition sources. Store below 388 C. The floor of the depot
should be impermeable. Store away from strong alkalis, acids and oxidizing agents. For further information please refer
to the Engineering Controls of this MSDS.
Material Safety Data Sheet
Page 3 of 6 Issue date: September 2004
M-BOND 300 RESIN
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by
the [NOHSC] to the following components of the product:
STYRENE MONOMER
[NOHSC]
3
[TWA]50 ppm 213 mg/m
3
[STEL]100 ppm 426 mg/m
Notices: H
Engineering Controls
Flammable liquid. Maintain adequate ventilation at all times. Prevent accumulation of vapours in hollows or sumps.
Eliminate any sources of ignition. Elevated temperature or mechanical action may form vapours, mists or fumes which
may require local exhaust ventilation systems.
Personal Protection Equipment
GLOVES: If product has spilt, or package is broken, then the use of rubber or PVC gloves is recommended.
EYES : Chemical goggles or spectacles with side shields to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of vapours/gases. Select and use respirators in accordance with
AS/NZS 1715/1716. When vapours/gases exceed the exposure standards then the use of a half-face respirator with
organic vapour cartridge is recommended. For high concentration use an atmosphere-supplied, positive pressure
demand self-contained or airline breathing apparatus, complying with the requirements of AS/NZS 1715. Filter
capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive
pressure air supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is
recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pink, clear liquid; pungent odor.
Boiling Point: 146掳C
Vapour Pressure: Not available.
Specific Gravity: 1.12 - 1.14
Flash Point: 32掳C
Flammability Limits: LEL: 1.1 UEL: Not available.
Solubility in Water: Insoluble.
Other Properties
Vapor Density (Air = 1): >1
Evaporation Rate (BuAc = 1): <1
Volatile Organic Compounds : 33-37 %
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable under normal conditions of use.
CONDITIONS TO AVOID:
Direct sunlight, heat, flames, ignition sources and incompatibles.
HAZARDOUS DECOMPOSITION PRODUCTS:
Emits oxides of carbon when heated to decomposition
Material Safety Data Sheet
Page 4 of 6 Issue date: September 2004
M-BOND 300 RESIN
10. STABILITY AND REACTIVITY (Continued)
HAZARDOUS POLYMERIZATION:
Will occur. Styrene monomer may polymerize under a wide variety of conditions, initiation and ultimate "run-away"
reactions are dependant upon conditions.
INCOMPATIBLE MATERIALS:
Transition metals or complexes, strong acids, oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
Swallowed:
May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and
lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea. There is some indication that if this
product is vomited, that it may be aspirated into the lungs leading to potential chemical pneumonitis, lung damage and
death.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon
duration of exposure, eye damage may occur.
Skin:
Will cause irritation to the skin, with effects including; Redness, itchiness, and rash.
Inhaled:
Harmful if inhaled. May cause central nervous system depression. May cause irritation to the nose, throat and
respiratory system with effects including: Dizziness, headache and loss of co-ordination.
Chronic:
Prolonged or repeated skin contact may lead to dermatitis.
Prolonged contact may cause severe eye irritation and some form of permanent eye damage may occur.
Prolonged or repeated inhalation will lead to liver and kidney damage.
STYRENE OXIDE has been classified as a CATEGORY 2 CARCINOGEN (WORKSAFE).
Probable human carcinogens are those substances for which there is sufficient evidence to provide a strong presumption
that human exposure might result in the development of cancer. This evidence is generally based upon appropriate long
term animal studies, limited epidemiological evidence or other relevant information.
There is no toxicological information available for this product, however, for the ingredient:
STYRENE MONOMER:
3
Inhalation LC50(rat): 120 mg/m /4H
Oral LD50(rat): 2650 mg/kg
IRRITATION (SKIN & EYE STANDARD DRAIZE TEST):
Irritant to eyes and skin.
12. ECOLOGICAL INFORMATION
No information is available for this product, however, large quantities should not be discharged to waterways, sewers or
drains.
13. DISPOSAL CONSIDERATIONS
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise flammable
nature.
Material Safety Data Sheet
Page 5 of 6 Issue date: September 2004
M-BOND 300 RESIN
14. TRANSPORT INFORMATION
Road Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains STYRENE MONOMER)
Dangerous Goods Class: 3
Packing Group: III
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
Air Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains STYRENE MONOMER)
Dangerous Goods Class: 3
Packing Group: III
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
Marine Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains STYRENE MONOMER)
Dangerous Goods Class: 3
Packing Group: III
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
15. REGULATORY INFORMATION
Poison Schedule: S5 [Aust]
This product is a Scheduled (S5) Poison and must be stored, handled and used according to the appropriate regulations.
Inventory Status:
Australia (AICS) Y
United States (TSCA) Y
Canada (DSL) Y
Europe (EINECS/ELINCS) Y
Japan (MITI) Y
South Korea (KECL) Y
Y = all ingredients are on the inventory.
16. OTHER INFORMATION
Date of Preparation:
Issue date: September 13, 2004 Supercedes: July 22, 2004 and Dec 22, 2001
Reasons for Update:
nd
1. Alignment with the 2 Edition of National Code of Practice for the Preparation of Material Safety Data Sheets
[NOHSC:2001(2003)].
2. Changes and /or addition made to all sections.
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission [Aust]
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
Material Safety Data Sheet
Page 6 of 6 Issue date: September 2004
M-BOND 300 RESIN
16. OTHER INFORMATION (Continued)
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
(SAA/SNZ HB76:1997) - Dangerous Goods - Initial Emergency Response Guide [Aust/NZ]
AS 1940 - The Storage and Handling of Flammable and Combustible Liquids [Aust]
IATA - International Aviation Transport Authority [Int]
ICAO - International Civil Aviation Organization [Int]
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the
classification and labelling of Chemicals. [Int]
EU - European Union [Int]
[Aust/NZ] = Australian/New Zealand
[Int] = International
[US] = United States of America
Principal References:
Information supplied by manufacturer.
Disclaimer
To the best of our knowledge, the information provided above meets the requirements of European Union directives for
hazardous substances which have been tested as a whole. The data provided on this Material Safety Data Sheet is from
manufacturers of the original components. All animal test data has been obtained from the public domain, NO
ANIMAL TESTS have been conducted by Davidson Pty Ltd. Davidson Pty Ltd specifically disclaims any and all form
of liability and/or responsibility for the application of this product.
End of MSDS
|