Material Safety Data Sheet

                              Page 1 of 7               Issue date: February 2005



                                      CSM-1A DEGREASER

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Davidson Measurement Pty. Ltd

ACN: 005 031 961 ABN: 29 005 031 961

Phone: 03 9580 4366

Fax: 03 9580 6499

Email: info@davidson.com.au

Web: www.davidson.com.au

Address: 1-3 Lakewood Boulevard,

         Braeside, Victoria, 3195.

Product Name: CSM-1A DEGREASER

Manufacturer's Product Code: MGM058E



Use: A powerful chlorinated hydrocarbon. Readily attacks general-purpose lubricating and hydraulic oils.



2. HAZARDS IDENTIFICATION

HAZARDOUS ACCORDING TO EU CRITERIA



Hazard Category: Harmful (Xn)



Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOOD



RISK PHRASES

R40/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.

R52 Harmful to aquatic organisms.

R53 May cause long term adverse effects in the aquatic environment.

R59 Dangerous for the ozone layer.



SAFETY PHRASES

S1/2 Keep locked up and out of reach of children.

S7 Keep container tightly closed.

S24 Avoid contact with skin.

S45 In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately and show

this container or label.



Road Transport

UN Number: 1950

Proper Shipping Name: AEROSOLS

Dangerous Goods Class: 2.2

Packing Group: None allocated



Poison Schedule: S5 [Aust]

This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulations.



Warning Statement:

Avoid breathing vapour and skin contact.



3. COMPOSITION / INFORMATION ON INGREDIENTS

SUBSTANCE NAME                                                  Proportion       CAS Number



1,1-DICHLORO-1-FLUOROETHANE                                     > 95 %           1717-00-6

METHANOL                                                        1 to < 5%        67-56-1

CARBON DIOXIDE                                                  1 to < 5 %       124-38-9



All other ingredients not hazardous according to EU Criteria.

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                                       CSM-1A DEGREASER



4. FIRST AID MEASURES

Swallowed:

Not a likely source of exposure, however, if product is concentrated and if swallowed, DO NOT induce vomiting. If

conscious, give 1 to 2 glasses of water to drink. If sprayed in mouth, rinse and give further water to drink.



Eye:

If contents of cylinder are vented directly into the eyes then blindness may occur due to freeze burns. Keep victim calm

and warm. In case of freeze burns URGENTLY transport to hospital or doctor. In normal use situations, however, if

material is splashed or lightly sprayed into eyes, flush with plenty of water for at least 15 minutes, ensuring eye lids are

held open. If irritation persists transport to hospital or doctor.



Skin:

Remove contaminated clothing and shoes immediately - Clothing frozen to the skin should be thawed before being

removed - In case of frostbite, thaw with lukewarm water. Immediately transport to hospital or doctor. In normal use

situations, however, if product is lightly sprayed onto the skin, immediately remove any contaminated clothing and

wash skin thoroughly with soap and water. If irritation persists transport to hospital or doctor.



Inhaled:

Remove victim to fresh air - Apply resuscitation if victim is not breathing - Administer oxygen if breathing is difficult.



First Aid Facilities:

Eye wash fountain, safety shower and normal wash room facilities.



Advice to Doctor:

Treat symptomatically.

In case of poisoning, contact Poisons Information Centre

In Australia call Tel: 131126

In New Zealand Tel: 034747000



5. FIRE-FIGHTING MEASURES

Fire/Explosion Hazard

If safe to do so, move undamaged containers from fire area. If involved in a fire cans may explode if subjected to heat

greater than 548C.

Hazardous Decomposition Products: Upon heating to high temperatures or burning in Emits oxides of carbon, HCl

and fluorine entities.

Fire Fighting Procedures: Fire fighters to wear Self-contained breathing apparatus (SCBA) in confined spaces, in

oxygen deficient atmospheres or if exposed to products of decomposition. Full protective clothing is also recommended.

Extinguishing Media: Use foam, carbon dioxide or dry chemical powder.



HAZCHEM CODE: None allocated [Aust]



FLAMMABILITY

This product is considered to be non-flammable. Contents under pressure.



6. ACCIDENTAL RELEASE MEASURES

Precautions for Safe Handling:

Keep aerosol containers in a cool, dry place away from direct sunlight. Store away from oxidizing agents. Store away

from sources of heat, ignition, sparks, flames or electrical discharges. Do not store above 508 C. Do not get liquid or

mist in eyes. Provide adequate ventilation.



Conditions for Safe Storage:

Store in original packages as approved by manufacturer. For further information please refer to the Engineering

Controls of this MSDS.

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                                        CSM-1A DEGREASER

7. HANDLING AND STORAGE

Emergency Procedures:

Cauti on! Aerosol container. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

Contents are under pressure. Assess situation, if safe, remove leaking aerosol container to well ventilated area (outside,

away from people and buildings).



Methods and Materials for Containment and Clean Up Procedures:

Isolate area until gas has dispersed. If possible, turn leaking containers so that gas escapes rather than liquid. If fire risk

is possible, use water spray to reduce vapors or divert vapor cloud drift. Do not direct water at spill or source of leak.

Prevent entry into waterways, sewers, basements or confined areas.



Emergency information(Transport):

Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997)

For AEROSOL DISPENSERS Guide No: 49



8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Standards



No exposure standards are available for this product, however, the following exposure standards have been assigned by

[NOHSC] to the following components of the product:



1,1-DICHLORO-1-FLUOROETHANE

(ACGIH)

[TWA] 500 ppm



METHANOL

[NOHSC]

                      3

[TWA]200 ppm 262 mg/m

                      3

[STEL]250 ppm 328 mg/m



Notices: Sk



Sk Notation:

The main route of most hazardous substances into the body is via inhalation, however, certain substances such as

ethylene glycol monoethyl ether can readily penetrate the skin, with resultant toxic effects. The notice 'Sk' indicates that

absorption can occur through the skin.



References: H



CARBON DIOXIDE

[NOHSC]

                                 3

[TWA]5,000 ppm         9,000 mg/m

                             3

[STEL]30,000 ppm 54,000 mg/m



References: H



Engineering Controls

Maintain adequate ventilation at all times. In most circumstances natural ventilation systems are adequate.

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                                       CSM-1A DEGREASER

8. EXPOSURE CONTROLS / PERSONAL PROTECTION (Continued)

Personal Protection Equipment

GLOVES: Not normally required, however, if can is punctured or leaking then use thermally insulated gloves.

EYES: Chemical goggles or spectacles to protect eyes.

RESPIRATORY PROTECTION: Avoid breathing of vapours, mists or spray. Select and use respirators in

accordance with AS/NZS 1715/1716. When mists, sprays or vapours exceed the exposure standards then the use of a

half-face respirator fitted with an organic vapour cartridge is recommended. Filter capacity and respirator type depends

on exposure levels. If entering spaces where the airborne concentration of a contaminant is unknown then the use of a

Self-contained breathing apparatus (SCBA) complying with AS/NZS 1715 / 1716, or any other acceptable International

Standard is recommended.



9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance:                         Clear, colourless liquid, with slight ethereal/alcoholic odour.

Boiling Point:                      32°C

Vapour Pressure:                    4100 mmHg

Specific Gravity:                   1.24

Flash Point:                        Not applicable.

Flammability Limits:                LEL: 6.0 % UEL: 23.0 %

Solubility in Water:                Insoluble (< 4 %)



Other Properties

Vapor Density (Air = 1):            4.1

Evaporation Rate (BuAc = 1):        >1

Volatile Organic Compounds :        1.0 - 3.5%



10. STABILITY AND REACTIVITY

CHEMICAL STABILITY:

Stable under normal conditions of use. Unstable at temperatures exceeding (~978C) or with flame contact.



CONDITIONS TO AVOID:

Ignition sources and mixing with incompatibles.



INCOMPATIBLE MATERIALS:

Strong mineral acids (sulfuric, nitric and hydrochloric), and oxidizing agents.



HAZARDOUS DECOMPOSITION PRODUCTS:

Emits oxides of carbon, HCl and fluorine entities.



HAZARDOUS REACTIONS:

Will not occur.



11. TOXICOLOGICAL INFORMATION

ACUTE HEALTH EFFECTS:

Swallowed:

Harmful if swallowed. May cause irritation to mouth, throat and stomach with effects including pains in the stomach,

which may lead to nausea, vomiting and diarrhoea. Overexposure to methanol has been suggested as a cause of the

following effects in both laboratory animals and humans: Liver abnormalities, kidney damage, eye damage, lung

damage, brain damage and nervous system damage. Methanol has been reported to cause death or serious irreversible

injury such as blindness in humans. Onset of symptoms may be delayed for 18 - 24 hours and are similar in respect to

ethanol poisoning, being staggering gait, euphoria, deliriums, coma and death.



Eye:

May cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision.

                        Material Safety Data Sheet

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                                       CSM-1A DEGREASER

11. TOXICOLOGICAL INFORMATION (Continued)

Skin:

Harmful by skin contact. This product will be absorbed through the skin with resultant toxic effects, similar to those of

swallowed. May cause irritation to the skin, with effects including; Redness and itchiness.



Inhaled:

Harmful if inhaled. May cause central nervous system effects. Effects may be similar to ingestion(swallowing). May

cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache and loss of co-

ordination.



Chronic:

Prolonged or repeated skin contact may lead to dermatitis. Product may also be absorbed through the skin with resultant

toxic effects. Prolonged or repeated exposure may lead to irreversible damage to health.



There is no toxicological information available for this product, however, for;



Methanol:



Swallowing as little as 28 - ~ 130 g of methanol has been reported to cause death or serious irreversible injury such as

blindness in humans. Studies in experimental animals indicate that the metabolism of methanol to formic acid results in

metabolic acidosis and irreversible damage to the optic nerve may occur. Ingestion of this product, can cause blindness

and death. Onset may be delayed for 18 - 24 hours. Symptoms are similar to those of ethanol alcohol stupor.



Rat

Inhalation LC50(rat): 64000 ppm/4H

Oral LD50(rat): 5628 mg/kg



Irritation - Rabbit Draize test skin



Dermal LD50(rabbit): 20 mg/24H

REACTION: Moderate



12. ECOLOGICAL INFORMATION

The 1,1-DICHLORO-1-FLUOROETHANE component of this product is considered to be environmental hazardous

and this component is dangerous to the ozone layer. Avoid release to the environment.



13. DISPOSAL CONSIDERATIONS

Seek expert advice in all cases dealing with leaking or suspicious cylinders. Remove all unnecessary personnel from the

area. If safe to do so, move container to well ventilated area, away from all personnel and allow to naturally vent to

atmosphere.



14. TRANSPORT INFORMATION

Road Transport

UN Number: 1950

Proper Shipping Name: AEROSOLS

Dangerous Goods Class: 2.2

Packing Group: None allocated

Label: Harmful (Xn)



Air Transport

UN Number: 1950

Proper Shipping Name: AEROSOLS

Dangerous Goods Class: 2.2

Packing Group: None allocated

Label: Harmful (Xn)

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                                      CSM-1A DEGREASER

14. TRANSPORT INFORMATION (Continued)

Sea Transport

UN Number: 1950

Proper Shipping Name: AEROSOLS

Dangerous Goods Class: 2.2

Packing Group: None allocated

Label: Harmful (Xn)



15. REGULATORY INFORMATION

Poison Schedule: S5 [Aust]

This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulations.



Inventory Status:

Australia (AICS)                       Y

United States (TSCA)                   Y

Europe (EINECS/ELINCS)                 Y



Y = all ingredients are on the inventory.



16. OTHER INFORMATION

Date of Preparation:



Issue date: February 15, 2005                        Supercedes: August 23, 2003 and March 8, 2000



Reasons for Update:

                       nd

1. Alignment with the 2 Edition of National Code of Practice for the Preparation of Material Safety Data Sheets

   [NOHSC:2001(2003)].

2. Changes and /or addition made to all sections.



Key Legend Information:

NOHSC - National Occupational Health & Safety Commission [Aust]

SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]

ACGIH - American Conference of Governmental Industrial Hygienists [US]

TWA - Time Weighted Average [Int]

STEL - Short Term Exposure Limit [Int]

AICS - Australian Inventory of Chemical Substances

EPA - Environmental Protection Agency [Int]

NIOSH - National Institute for Occupational Safety and Health [US]

AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]

AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]

(SAA/SNZ HB76:1997) - Dangerous Goods - Initial Emergency Response Guide [Aust/NZ]

AS 1940 - The Storage and Handling of Flammable and Combustible Liquids [Aust]

IATA - International Aviation Transport Authority [Int]

ICAO - International Civil Aviation Organization [Int]

IMO - International Maritime Organisation. [Int]

IMDG - International Maritime Dangerous Goods [Int]

United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the

classification and labelling of Chemicals. [Int]

EU - European Union [Int]



[Aust/NZ] = Australian/New Zealand

[Int] = International

[US] = United States of America

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                                    CSM-1A DEGREASER

16. OTHER INFORMATION (Continued)

Principal References:

Information supplied by manufacturer.



Disclaimer

To the best of our knowledge, the information provided above meets the requirements of European Union directives for

hazardous substances which have been tested as a whole. The data provided on this Material Safety Data Sheet is from

manufacturers of the original components. All animal test data has been obtained from the public domain, NO

ANIMAL TESTS have been conducted by Davidson Pty Ltd. Davidson Pty Ltd specifically disclaims any and all form

of liability and/or responsibility for the application of this product.



                                           END of MSDS