MATERIAL SAFETY DATA SHEET
COATINGS AND RESINS GROUP
PPG Industries, Inc.
SECTION 1 - CHEMICAL, PRODUCT, AND COMPANY INFORMATION
PRODUCT CODE/IDENTITY: UC51760
PRODUCT TRADE NAME: DURACRYL PRIMER LACQUER
REVISION DATE: 12/23/03 (000) 0811
CUSTOMER PART #/NAME: Not applicable
CHEMICAL FAMILY: Acrylic
EMERGENCY MEDICAL/SPILL INFO: (304) 843-1300 (U.S.) 01-800-00-21-400 (MEXICO)
TECHNICAL INFORMATION: (724) 274-7900
PRODUCT SAFETY/MSDS INFORMATION: 4325 ROSANNA DRIVE ALLISON PARK, PA 15101 (412)
492-5555
DATE OF MSDS PREPARATION: 06/23/04
PRIMARY HAZARD WARNING
Flammable. Keep away from heat, sparks, flames, and other sources of ignition.
Do not smoke. Extinguish all flames and pilot lights. Turn off stoves, heaters,
electrical motors, and other sources of ignition during use and until all
vapors/odors are gone. Harmful if swallowed. Dried film of this product may be
harmful if chewed or swallowed. Causes primary skin irritation. Causes severe
eye irritation. Prolonged or repeated contact may cause an allergic skin
reaction. Vapor and/or spray mist may be harmful if inhaled. Vapor irritates
eyes, nose, and throat. Sanding and grinding dusts may be harmful if inhaled.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200), THE SUPPLIER NOTIFICATION
REQUIREMENTS OF SARA TITLE III, SECTION 313, AND OTHER APPLICABLE RIGHT-TO-KNOW
REGULATIONS.
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
REF HAZARDOUS INGREDIENTS PERCENT CAS NUMBER CARCINOGEN*
--- ---------------------------------------- ------- --------------- -----------
01 1-METHOXY-2-PROPYL ACETATE 5 - <10 108-65-6
02 TOLUENE 30- <40 108-88-3
03 ALUMINUM SILICATE 10- <20 1332-58-7
04 TITANIUM DIOXIDE 5 - <10 13463-67-7
05 2-METHOXY-1-PROPYL ACETATE 0.1- <1 70657-70-4
06 STRONTIUM CHROMATE 1 - <5 7789-06-2 NOA
07 METHYL ETHYL KETONE 5 - <10 78-93-3
* Carcinogens: O=OSHA; A=ACGIH; N=NTP; I=IARC
SARA TITLE III & CERCLA CLASSIFICATIONS
CERCLA HAZARDOUS SARA EXTREMELY HAZ SARA 311/312
REF SUBSTANCE RQ(LBS) SUBSTANCE TPQ(LBS) SARA 313 AC CH FL PR RE
---- ----------------- ------------------ -------- -- -- -- -- --
01 NOT ESTAB NOT ESTAB N YN YNN
01 NOT ESTAB NOT ESTAB N (ONTARIO)
02 1000 lbs NOT ESTAB Y YN YNN
03 NOT ESTAB NOT ESTAB N NN NNN
03 NOT ESTAB NOT ESTAB N (NUSANCDUST)
04 NOT ESTAB NOT ESTAB N N N N NN
04 NOT ESTAB NOT ESTAB N (TI COMPDS)
04 NOT ESTAB NOT ESTAB N (AS TI)
05 NOT ESTAB NOT ESTAB N N Y YNN
06 10 lbs NOT ESTAB N Y Y NNN
06 NOT ESTAB NOT ESTAB Y (CR6 CMPD)
06 1 lb NOT ESTAB Y (CHROMIUM)
06 NOT ESTAB NOT ESTAB N (CHROMATES)
06 NOT ESTAB NOT ESTAB N (INORG CR)
06 NOT ESTAB NOT ESTAB Y (AS CR)
06 NOT ESTAB NOT ESTAB N (AS CR6)
07 5000 lbs NOT ESTAB Y Y N YNN
SARA 311/312 CATEGORIES FOR THIS PRODUCT: ACUTE= Y, CHRONIC= Y, FLAMMABILITY= Y,
PRESSURE= N, REACTIVITY= N
OCCUPATIONAL EXPOSURE LIMITS HAVE BEEN ESTABLISHED FOR THE FOLLOWING MATERIALS:
ACGIH U.S. OSHA
REF TLV-TWA TLV-STEL PEL-TWA PEL-STEL
---- ---------------- ------------ ---------------- ------------
01 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
01 IPEL-TWA: 100 ppm IPEL-STEL: NOT ESTAB
01 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (ONTARIO)
02 50 ppm NOT ESTAB 100 ppm 150 ppm
03 2 mg/m3 NOT ESTAB R- 5 mg/m3 NOT ESTAB
03 R- 10 MG/M3 NOT ESTAB R- 5 mg/m3 NOT ESTAB (NUSANCDUST)
04 10 mg/m3 NOT ESTAB 10 mg/m3 NOT ESTAB
04 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (TI COMPDS)
04 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (AS TI)
05 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
06 0.0005 mg/m3 NOT ESTAB NOT ESTAB NOT ESTAB
06 0.05 mg/m3 NOT ESTAB NOT ESTAB NOT ESTAB (CR6 CMPD)
06 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (CHROMIUM)
06 NOT ESTAB NOT ESTAB C- 0.1 mg/m3 NOT ESTAB (CHROMATES)
06 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (INORG CR)
06 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (AS CR)
06 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (AS CR6)
07 200 ppm 300 ppm 200 ppm 300 ppm
07 IPEL-TWA: NOT ESTAB IPEL-STEL: 250 PPM
[C- Ceiling Limit; S- Potential Skin Absorption; R- Respirable Dust]
REF ACGIH TLV - BASIS - CRITICAL EFFECT(S)
---- ------------------------------------------------------------
01 NOT ESTAB.
01 (ONTARIO) ...NOT ESTAB.
02 CNS
03 pneumoconiosis
03 (NUSANCDUST)...lung
04 lung
04 (TI COMPDS) ...NOT ESTAB.
04 (AS TI) ...NOT ESTAB.
05 NOT ESTAB.
06 cancer(lung) (as Cr)
06 (CR6 CMPD) ...cancer; irritation
06 (CHROMIUM) ...NOT ESTAB.
06 (CHROMATES) ...NOT ESTAB.
06 (INORG CR) ...irritation; dermatitis
06 (AS CR) ...NOT ESTAB.
06 (AS CR6) ...NOT ESTAB.
07 irritation; CNS
[ACGIH TLV BASIS - CRITICAL EFFECT(S): CNS-CENTRAL NERVOUS SYSTEM;
CVS-CARDIOVASCULAR SYSTEM; CWP-COAL WORKER'S PNEUMOCONIOSIS;
GI-GASTROINTESTINAL] [NOT ESTAB.= NOT ESTABLISHED = NOT APPLICABLE] [NOT ESTAB.
= NOT ESTABLISHED = NOT APPLICABLE]
PRODUCT STATUS RELATIVE TO THE U.S. EPA TOXIC SUBSTANCES CONTROL ACT
All chemical substances in this product are listed on the U.S. TSCA Inventory or
are otherwise exempt from TSCA Inventory reporting requirements.
SECTION 3 - HAZARDS IDENTIFICATION
EFFECTS OF OVEREXPOSURE FROM:
INGESTION: Harmful if swallowed. Dried film of this product may be harmful if
chewed or swallowed.
EYE CONTACT: Causes severe eye irritation.
SKIN CONTACT: Causes primary skin irritation. Prolonged or repeated contact may
cause an allergic skin reaction.
INHALATION: Vapor and/or spray mist may be harmful if inhaled. Vapor irritates
eyes, nose, and throat. Sanding and grinding dusts may be harmful if inhaled.
Repeated exposure to high vapor concentrations may cause irritation of the
respiratory system and permanent brain and nervous system damage.
CHRONIC OVEREXPOSURE: Avoid long-term and repeated contact. Possible
reproductive hazard. An ingredient(s) in this product has adversely affected
reproductive tissues and fetal development in test animals. NTP and IARC have
classified chromium (+6) compounds as carcinogenic. This product contains
titanium dioxide. Animals inhaling massive quantities of titanium dioxide dust
in a long-term study developed lung tumors. Studies with humans involved in
manufacture of this pigment indicate no increased risk of cancer from exposure.
This product contains butyl benzyl phthalate (BBP). BBP has caused testicular
atrophy in laboratory animals. This product contains methyl ethyl ketone (MEK).
MEK has been shown to cause minor embryotoxic/fetotoxic effects in laboratory
animals exposed for prolonged periods at high concentrations via inhalation. The
potential for human exposure to high concentrations is expected to be low due to
the irritating effects of MEK at low concentrations. This product contains
toluene. Toluene inhalation in animals (greater than 1500 ppm) and intentional
inhalation of toluene-containing products by humans (e.g. glue) has caused
adverse fetal development effects.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Dried film of this product may be harmful if
chewed or swallowed. Eye watering, headaches, nausea, dizziness, and loss of
coordination are indications that solvent levels are too high. Intentional
misuse by deliberately concentrating and inhaling the contents can be harmful or
fatal. Redness, itching, burning sensation and visual disturbances may indicate
excessive eye contact. Dryness, itching, cracking, burning, redness, and
swelling are conditions associated with excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not applicable.
WARNING: This product contains a chemical(s) known to the State of California to
cause cancer and birth defects or other reproductive harm.
SECTION 4 - FIRST AID MEASURES
IMPORTANT FIRST AID INFORMATION: If ingestion, irritation, any type of
overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
immediately; have Material Safety Data Sheet information available.
INGESTION: Gently wipe or rinse the inside of the mouth with water. Sips of
water may be given if person is fully conscious. Never give anything by mouth to
an unconscious or convulsing person. Do Not induce vomiting. Contact a poison
control center, emergency room or physician right away as further treatment will
be necessary.
EYE CONTACT: Remove contact lens and pour a gentle stream of warm water through
the affected eye for at least 15 minutes. If irritation persists, contact a
poison control center, emergency room, or physician as further treatment may be
necessary.
SKIN CONTACT: Run a gentle stream of water over the affected area for 15
minutes. A mild soap may be used if available. If any symptoms persist, contact
a poison control center, emergency room, or physician as further treatment may
be necessary.
INHALATION: Remove from area to fresh air. If symptomatic, contact a poison
control center, emergency room or physician for treatment information.
SECTION 5 - FIRE FIGHTING MEASURES
FLASHPOINT: 40 Degrees F ( 4 Degrees C) (PENSKY-MARTENS CLOSED CUP)
FLAMMABLE LIMITS: Lower explosion limit (LEL): 1.4
Upper explosion limit (UEL): Not available
EXTINGUISHING MEDIA: Use National Fire Protection Association (NFPA) Class B
extinguishers (carbon dioxide, dry chemical, or universal aqueous film forming
foam) designed to extinguish NFPA Class IB flammable liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep this product away from heat, sparks,
flame, and other sources of ignition (i.e., pilot lights, electric motors,
static electricity). Invisible vapors can travel to a source of ignition and
flash back. Do not smoke while using this product. Keep containers tightly
closed when not in use. Closed containers may explode when overheated. Do not
apply to hot surfaces. Toxic gases may form when this product comes in contact
with extreme heat.
SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray
may be used to cool closed containers to prevent pressure build-up and possible
autoignition or explosion when exposed to extreme heat. If water is used, fog
nozzles are preferable. Fire-fighters should wear self-contained breathing
apparatus and full protective clothing.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Provide maximum
ventilation. Only personnel equipped with proper respiratory, skin, and eye
protection should be permitted in the area. Remove all sources of ignition. Take
up spilled material with sand, vermiculite, or other noncombustible absorbent
material and place in clean, empty containers for disposal. Only the spilled
material and the absorbant should be placed in this container.
WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with
federal, state, provincial, and local environmental control regulations. Empty
containers should be recycled or disposed of through an approved waste
management facility.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: Do not store above 120 degrees F.(48 degrees
C.). Store large quantities in buildings designed and protected for storage of
NFPA Class IB flammable liquids.
OTHER PRECAUTIONS: Vapors may collect in low areas. If this material is part of
a multiple component system, read the Material Safety Data Sheet(s) for the
other component or components before blending as the resulting mixture may have
the hazards of all of its parts. Containers should be grounded when pouring.
Avoid free fall of liquids in excess of a few inches.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: Wear chemical-type splash goggles when possibility exists for
eye contact due to splashing or spraying liquid, airborne particles, or vapors.
SKIN PROTECTION: Wear protective clothing to prevent skin contact. Apron and
gloves should be constructed of: neoprene rubber. No specific
permeation/degradation testing have been done on protective clothing for this
product. Recommendations for skin protection are based on infrequent contact
with this product. For frequent contact or total immersion, contact a
manufacturer of protective clothing for appropriate chemical impervious
equipment.
RESPIRATORY PROTECTION: Overexposure to vapors may be prevented by ensuring
proper ventilation controls, vapor exhaust or fresh air entry. A NIOSH- approved
air purifying respirator with the appropriate chemical cartridges or a
positive-pressure, air-supplied respirator may also reduce exposure. Read the
respirator manufacturer's instructions and literature carefully to determine the
type of airborne contaminants against which the respirator is effective, its
limitations, and how it is to be properly fitted and used.
OTHER EQUIPMENT: Clean contaminated clothing and shoes.
VENTILATION REQUIREMENTS: Provide general dilution or local exhaust ventilation
in volume and pattern to keep the concentration of ingredients listed in Section
2 below the lowest suggested exposure limits, the LEL below the stated limit,
and to remove decomposition products during welding or flame cutting.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
[FORMULA VALUES, NOT SALES SPECIFICATIONS]
BOILING RANGE: 149- 302Degrees F
SOLUBILITY IN WATER: 3.8 %
VAPOR PRESSURE: 27.2 mmHg
WEIGHT/GALLON (LBS): 9.30 (U.S.)
VAPOR DENSITY: Heavier than air
pH: Not determined
% VOLATILE/VOLUME: 71.080
% SOLIDS BY WEIGHT: 44.42
SPECIFIC GRAVITY: 1.116
EVAPORATION RATE(BuOAc=100): 265
ODOR/APPEARANCE: Viscous liquid with an odor characteristic of the solvents
listed in Section 2.
SECTION 10 - STABILITY AND REACTIVITY
This product is normally stable and will not undergo hazardous reactions.
INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): Avoid contact with strong
alkalies, strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous
decomposition products when exposed to extreme heat: carbon monoxide ; carbon
dioxide ; oxides of chromium ; oxides of aluminum ; lower molecular weight
polymer fractions; Extreme heat includes, but is not limited to, flame cutting,
brazing, and welding.
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) Ratings:
HMIS Rating NFPA Rating
----------------------- -----------------------
HEALTH 2* HEALTH 2
FLAMMABILITY 3 FLAMMABILITY 3
REACTIVITY 0 INSTABILITY 0
Rating System:0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic
Effects.
Safe handling of this product requires that all of the information on the MSDS
be evaluated for specific work environments and conditions of use.
TRANSPORTATION OF DANGEROUS GOODS
PROPER SHIPPING NAME: Paint
NOS TECHNICAL NAME: None
HAZARD CLASS: 3
SUBSIDIARY CLASS: None
UN NUMBER: UN1263
PACKING GROUP: II
MARINE POLLUTANT: None
USA-RQ, HAZARDOUS SUBSTANCE: Strontium Chromate, Toluene, Butyl Benzyl Phthalate
USA-RQ, HAZARDOUS SUBSTANCE THRESHOLD SHIP WEIGHT: Strontium Chromate>258.66
Pounds, Toluene>2579.34 Pounds, Butyl Benzyl Phthalate
USA Shipments Only - RQ Threshold Ship Weight: This is the total weight of this
product that must be shipped to exceed the RQ quantity.
THIS IS THE END OF THE MSDS FOR: UC51760 (00292523.001UC51760 )
Manufactured and Supplied by:
PPG INDUSTRIES, SPRINGDALE
125 COLFAX STREET
SPRINGDALE, PA 15144
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