MATERIAL SAFETY DATA SHEET
INHALATION:
SECTION 1 - PRODUCT AND COMPANY INFORMATION
Vapor and/or spray mist may be harmful if inhaled. Vapor irritates eyes,
nose, and throat.
PPG Industries, Inc. INGESTION:
One PPG Place Harmful if swallowed.
Pittsburgh, PA 15272 SIGNS & SYMPTOMS OF OVEREXPOSURE:
Repeated exposure to high vapor concentrations may cause irritation of
EMERGENCY PHONE NUMBERS (412) 434-4515 (U.S.) the respiratory system and permanent brain and nervous system
(24 hours/day): damage. Eye watering, headaches, nausea, dizziness and loss of
(514) 645-1320 (Canada) coordination are indications that solvent levels are too high. Intentional
01-800-00-21-400 (Mexico) misuse by deliberately concentrating and inhaling the contents can be
0532-83889090 (China) harmful or fatal. Dryness, itching, cracking, burning, redness, and
swelling are conditions associated with excessive skin contact.
TECHNICAL (724) 274-7900 (SPRINGDALE, PA) 8:00 a.m. -
INFORMATION: 5:00 p.m. EST
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not
PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m.
applicable.
- 4:30 p.m. EST
CHRONIC OVEREXPOSURE EFFECTS
Product ID: UC60400 (0811)
Avoid long-term and repeated contact.
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
Repeated exposure to vapors above recommended exposure limits (see
SYNONYMS: None
Section 8) may cause irritation of the respiratory system and permanent
ISSUE DATE: 03/29/2007
brain and nervous system damage. Intentional misuse by deliberately
EDITION NO.: 2
concentrating and inhaling the contents can be harmful or fatal. This
CHEMICAL Acrylic Fluoropolymer
product contains toluene. Toluene inhalation in animals (greater than
FAMILY:
1500 ppm) and intentional inhalation of toluene-containing products by
EMERGENCY OVERVIEW:
humans (e.g. glue) has caused adverse fetal development effects. There
Flammable. Keep away from heat, sparks, flames, and other sources of
is some evidence that repeated exposure to organic solvent vapors in
ignition. Do not smoke. Extinguish all flames and pilot lights. Turn off
combination with constant loud noise can cause greater hearing loss than
stoves, heaters, electrical motors, and other sources of ignition during
expected from exposure to noise alone.
use and until all vapors/odors are gone.CAUSES EYE IRRITATION.
The effects of long-term, low level exposures to this product have not
MAY CAUSE SLIGHT SKIN IRRITATION. MAY BE ABSORBED
been determined. Safe handling of this material on a long-term basis
THROUGH THE SKIN.VAPOR AND/OR SPRAY MIST MAY BE
should emphasize the prevention of all contact with this material to avoid
HARMFUL IF INHALED. VAPOR IRRITATES EYES, NOSE, AND
any effects from repetitive acute exposures. See Section 11, of this
THROAT.HARMFUL IF SWALLOWED.
MSDS for a detailed list of chronic health effects information available on
individual ingredients in this product.
SECTION 2 - COMPOSITION INFORMATION
SECTION 4 - FIRST AID MEASURES
The following ingredient(s) marked with an "x" are considered
If ingestion, irritation, any type of overexposure or symptoms of
hazardous under applicable U.S. OSHA and/or Canadian WHMIS
overexposure occur during or persists after use of this product, contact a
regulations. If no ingredients are listed, then there are no U.S. OSHA
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
and/or Canadian WHMIS hazardous ingredients in this product.
immediately; have Material Safety Data Sheet information available.
Material/ Percent Hazardous
EYE CONTACT:
CAS Number
1-METHOXY-2-PROPYL 10 - 30 X Remove contact lens and pour a gentle stream of warm water through the
ACETATE affected eye for at least 15 minutes. If irritation persists, contact a poison
108-65-6 control center, emergency room, or physician as further treatment may be
TOLUENE 10 - 30 X
necessary.
108-88-3
SKIN CONTACT:
ETHYL ACETATE 10 - 30 X
Run a gentle stream of water over the affected area for 15 minutes. A
141-78-6
mild soap may be used if available. If any symptoms persist, contact a
TITANIUM DIOXIDE 7 - 13 X
13463-67-7 poison control center, emergency room, or physician as further treatment
ETHYL ALCOHOL 1-5 X may be necessary.
64-17-5 INHALATION:
2-METHOXY-1-PROPYL 0.1-1.0 X
Remove from area to fresh air. If symptomatic, contact a poison control
ACETATE
center, emergency room or physician for treatment information.
70657-70-4
INGESTION:
Gently wipe or rinse the inside of the mouth with water. Sips of water
SECTION 3 - HAZARDS IDENTIFICATION
may be given. Never give anything by mouth to an unconscious person.
ACUTE OVEREXPOSURE EFFECTS Contact a poison control center, emergency room or physician right away
as further treatment may be necessary.
EYE CONTACT:
Causes eye irritation. Redness, itching, burning sensation and visual
SECTION 5 - FIRE FIGHTING MEASURES
disturbances may indicate excessive eye contact.
FLAMMABLE PROPERTIES
SKIN CONTACT:
FLASHPOINT: 35 Degrees F ( 2 Degrees C)
May cause slight skin irritation. Dryness, itching, cracking, burning,
FLASHPOINT TEST METHOD:
redness, and swelling are conditions associated with excessive skin
Pensky-Martens Closed Cup
contact.
UEL: Not Available.
SKIN ABSORPTION:
LEL: 1.9
May be absorbed through the skin.
__________________________________________________________________
Page 1 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
AUTOIGNITION TEMPERATURE: RESPIRATOR:
Not Available. Overexposure to vapors may be prevented by ensuring proper ventilation
EXTINGUISHING MEDIA: controls, vapor exhaust or fresh air entry. A NIOSH- approved air
Use National Fire Protection Association (NFPA) Class B extinguishers purifying respirator with the appropriate chemical cartridges or a positive-
(carbon dioxide, dry chemical, or universal aqueous film forming foam) pressure, air-supplied respirator may also reduce exposure. Read the
designed to extinguish NFPA Class IB flammable liquid fires. Water spray respirator manufacturer's instructions and literature carefully to determine
may be ineffective. Water spray may be used to cool closed containers the type of airborne contaminants against which the respirator is effective,
to prevent pressure build-up and possible autoignition or explosion when its limitations, and how it is to be properly fitted and used. Provide general
exposed to extreme heat. dilution or local exhaust ventilation in volume and pattern to keep the
PROTECTION OF FIREFIGHTERS: concentration of ingredients listed in Section 2 below the lowest
Fire-fighters should wear self-contained breathing apparatus and full suggested exposure limits, the LEL below the stated limit, and to remove
protective clothing. decomposition products during welding or flame cutting.
UNUSUAL FIRE AND EXPLOSION HAZARDS: GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS
Keep this product away from heat, sparks, flame, and other sources of If Threshold Limit Values (TLVs) have been established by ACGIH,
ignition (i.e., pilot lights, electric motors, static electricity). Invisible vapors OSHA, Ontario or PPG, they will be listed below. These limits are
can travel to a source of ignition and flash back. Do not smoke while intended for use in the practice of industrial hygiene as guidelines or
using this product. Keep containers tightly closed when not in use. Closed recommendations in the control of potential workplace health hazards.
containers may explode when overheated. Do not apply to hot surfaces. These limits are not a relative index of toxicity and should not be used by
Toxic gases may form when this product comes in contact with extreme anyone without industrial hygiene training.
heat. May produce hazardous decomposition products when exposed to
extreme heat. Extreme heat includes, but is not limited to, flame cutting,
Material/ Percent ACGIH TLV ACGIH OSHA PEL OSHA
brazing, and welding. CAS Number STEL STEL
TOLUENE 10 - 30 S- 50 ppm Not 100 ppm 150 ppm
108-88-3 established
SECTION 6 - ACCIDENTAL RELEASE MEASURE
ETHYL ACETATE 10 - 30 400 PPM Not 400 ppm Not
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
141-78-6 established established
Provide maximum ventilation. Only personnel equipped with proper 3 3
TITANIUM DIOXIDE 7 - 13 10 mg/m Not 10 mg/m Not
respiratory, skin, and eye protection should be permitted in the area. 13463-67-7 established established
Remove all sources of ignition. Take up spilled material with sand, ETHYL ALCOHOL 1-5 1000 ppm Not 1000 ppm Not
vermiculite, or other noncombustible absorbent material and place in 64-17-5 established established
clean, empty containers for disposal. Only the spilled material and the
absorbant should be placed in this container.
Material/ Percent Ontario Ontario PPG IPEL PPG STEL
CAS Number TWA STEL
SECTION 7 - HANDLING AND STORAGE 1-METHOXY-2- 10 - 30 50 PPM Not 50 PPM Not
PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: PROPYL ACETATE established established
Vapors may collect in low areas. If this material is part of a multiple 108-65-6
TOLUENE 10 - 30 50 PPM Not Not Not
component system, read the Material Safety Data Sheet(s) for the other
108-88-3 established established established
component or components before blending as the resulting mixture may
ETHYL ACETATE 10 - 30 400 ppm Not Not Not
have the hazards of all of its parts. Containers should be grounded when
141-78-6 established established established
pouring. Avoid free fall of liquids in excess of a few inches.
10 MG/m3
TITANIUM DIOXIDE 7 - 13 Not Not Not
STORAGE: 13463-67-7 established established established
Do not store above 120 degrees F.(48 degrees C.). Store large quantities ETHYL ALCOHOL 1-5 1000 ppm Not Not Not
in buildings designed and protected for storage of NFPA Class IB 64-17-5 established established established
flammable liquids.
Key: ACGIH=American Conference of Governmental Industrial
SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION Hygienists; OSHA=Occupational Safety and Health Administration;
ENGINEERING CONTROLS: TLV=Threshold Limit Value; TWA=Time Weighted Average;
Provide general dilution or local exhaust ventilation in volume and pattern PEL=Permissible Exposure Limit (1989 Vacated values); IPEL=Internal
to keep the concentration of ingredients listed in Section 8 below the Permissible Exposure Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV
lowest suggested exposure limits, the LEL below the stated limit, and to or PEL Short-Term Exposure Limit; Skin= Skin Absorption Designation.
remove decomposition products during welding or flame cutting. [C- Ceiling Limit; S-Potential Skin Absorption; R-Respirable Dust]
Additional Information Not applicable.
PERSONAL PROTECTIVE EQUIPMENT
EYES: SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
Wear safety glasses with side shields. (FORMULA VALUES, NOT SALES SPECIFICATIONS)
SKIN/GLOVES: SPECIFIC GRAVITY: 1.112
Wear protective clothing. Gloves should be constructed of: butyl rubber. PHYSICAL STATE: Liquid
No specific permeation/degradation testing have been done on protective Percent Solids: 34.94
clothing for this product. Recommendations for skin protection are based Percent Volatile by Volume: 79.710
on infrequent contact with this product. For frequent contact or total pH: Not available.
immersion, contact a manufacturer of protective clothing for appropriate ODOR THRESHOLD: Not available.
chemical impervious equipment. Clean contaminated clothing and shoes. Vapour Pressure: 30.7 mmHg
ODOR/APPEARANCE: Viscous liquid with an odor
characteristic of the solvents listed in
Section 2.
VAPOR DENSITY: HEAVIER THAN AIR
Evaporation Rate: 250
__________________________________________________________________
Page 2 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
BOILING POINT OR RANGE: 148 - 302Degrees F Ecotoxicity: No Information Available.
Freezing Point or Range: Not Applicable.
Melting Point or Range(掳C): Not Applicable.
ENVIRONMENTAL FATE
Partition coefficient (n- Not Applicable.
Mobility: No information available.
octanol/water):
Biodegradation: No information available.
WEIGHT PER GALLON: 9.27 (U.S.) / 11.1 (IMPERIAL)
Bioaccumulation: No Information Available.
PHYSICAL/CHEMICAL
SECTION 10 - STABILITY AND REACTIVITY
STABILITY: Hydrolysis: No information available.
This product is normally stable and will not undergo hazardous reactions. Photolysis: No information available.
CONDITIONS TO AVOID:
None Known.
SECTION 13 - DISPOSAL CONSIDERATIONS
INCOMPATIBLE MATERIALS:
Provide maximum ventilation, only personnel equipped with proper
Avoid contact with strong alkalies, strong mineral acids, or strong
respiratory and skin and eye protection should be permitted in the area.
oxidizing agents.
Take up spilled material with sawdust, vermiculite, or other absorbent
HAZARDOUS POLYMERIZATION:
material and place in containers for disposal.
None Known.
Waste material must be disposed of in accordance with federal, state,
HAZARDOUS DECOMPOSITION PRODUCTS:
provincial and local environmental control regulations. Empty containers
- Carbon monoxide - Carbon dioxide - Lower molecular weight polymer
should be recycled by an appropriately licensed reconditioner/salvager or
fractions
disposed of through a permitted waste management facility. Additional
disposal information is contained on the Environmental Data Sheet for
this product, which can be obtained from your PPG representative.
SECTION 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY SECTION 14 - TRANSPORTATION INFORMATION
Proper Shipping Name: Paint
Material/ Percent ORAL DERMAL INHALATION NOS Technical Name: None
CAS Number LD50 (g/kg) LD50 (g/kg) LC50 (mg/l) Hazard Class: 3
1-METHOXY-2- 10 - 30 8.53 g/kg 5.00 g/kg Not Available
Subsidiary Class(es): None
PROPYL ACETATE
UN Number: UN1263
108-65-6
Packing Group: II
TOLUENE 10 - 30 .64 g/kg 8.39 g/kg 12.50 g/L. 4 hr.
108-88-3
ETHYL ACETATE 10 - 30 5.62 g/kg 5.00 g/kg 29.30 g/L. 4 hr.
USA - RQ Hazardous Substances: Toluene, Ethyl Acetate
141-78-6
USA-RQ Hazardous Substance Toluene>4712.58 Pounds, Ethyl
TITANIUM DIOXIDE 7 - 13 10.00 g/kg Not Available Not Available
Threshold Ship Weight: Acetate>35385.75 Pounds
13463-67-7
Marine Pollutant Name: None
ETHYL ALCOHOL 1-5 7.06 g/kg Not Available Not Available
USA Shipments Only - RQ Threshold Ship Weight: This is the total
64-17-5
weight of this product that must be shipped to exceed the RQ quantity.
CHRONIC TOXICITY
Ingredient Target Organ/Chronic Effects:
- Carcinogen - Embryotoxin - Reproductive - Teratogen - Ear - Brain -
SECTION 15 - REGULATORY INFORMATION
Central nervous system - Lung
INVENTORY STATUS
U.S. TSCA: This product and/or all of its components are listed on the
Mutagenicity Toxicity: U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory
This has not been tested for this product. reporting requirements.
Reproductive Toxicity: FEDERAL REGULATIONS
This has not been tested for this product. US Regulations
Material/ Percent
CAS Number CERCLA HS - SARA EHS- SARA 313
SUPPLEMENTAL HEALTH INFORMATION:
RQ (LBS) TPQ (LBS)
Material/ Percent
1-METHOXY-2- 10 - 30 Not Listed Not Listed Not Listed
CAS Ingredient Specific Animal Data:
PROPYL ACETATE
Number
108-65-6
TITANIUM 7 - 13 This product contains titanium dioxide. Animals inhaling
TOLUENE 10 - 30 1000 lbs Not Listed Listed
DIOXIDE massive quantities of titanium dioxide dust in a long-term
108-88-3
13463-67-7 study developed lung tumors. Studies with humans
ETHYL ACETATE 10 - 30 5000 lbs Not Listed Not Listed
involved in manufacture of this pigment indicate no
141-78-6
increased risk of cancer from exposure.
TITANIUM DIOXIDE 7 - 13 Not Listed Not Listed Not Listed
2- 0.1-1.0 Possible reproductive hazard. An ingredient(s) in this
13463-67-7
METHOXY- product has adversely affected reproductive tissues and
ETHYL ALCOHOL 1-5 Not Listed Not Listed Not Listed
1-PROPYL fetal development in test animals.
64-17-5
ACETATE
2-METHOXY-1- 0.1-1.0 Not Listed Not Listed Not Listed
70657-70-4
PROPYL ACETATE
70657-70-4
SECTION 12 - ECOLOGICAL INFORMATION
POTENTIAL ENVIRONMENTAL EFFECTS
SARA 311/312
__________________________________________________________________
Page 3 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC60400 (0811)
PRODUCT NAME: DURANAR ADS WHITE "EZ" BA
Health (acute): Yes
Health (chronic): Yes
Fire (flammable): Yes
Pressure: No
Reactivity: No
WHMIS HAZARD CLASS: - Class B, Division 2 - Class D, Division 2,
Subdivision A
STATE/PROVINCIAL REGULATIONS
CALIFORNIA PROP. 65: WARNING: This product contains a chemical
known to the State of California to cause birth defects or other
reproductive harm.
Additional Information
Percent
Material/
CAS Number IARC IARC IARC ACGIH NTP OSHA
Group Group 2B ( Carc. Known Carc.
1(Kno 2A Suspec Carc.
wn (Proba ted
Human ble Carc.)
Carc.) Carc.)
TITANIUM DIOXIDE 7 - 13 N N Y N N N
13463-67-7
Key: IARC- International Agency on the Research of Cancer; ACGIH-
American Conference of Governmental Industrial Hygienists; NTP-
National Toxicology Program *Denotes chemical as NTP Known
Carcinogen; + Denotes NTP Possible Carcinogen; OSHA-
Occupational Safety and Health Administration.
SECTION 16 - OTHER INFORMATION
Hazard Rating Systems
NFPA Rating: 2 30
HMIS Rating: 2*30
Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe,
*=Chronic Effects.
HMIS=Hazardous Materials Identification System; NFPA=National Fire
Protection Association;
Safe handling of this product requires that all of the information on the
MSDS be evaluated for specific work environments and conditions of use.
PREPARED BY: Product Safety Department
REASON FOR REVISION: Section 11 has been updated. Section 1 has
been updated. Section 3 has been updated. Section 8 has been updated.
Section 9 has been updated. Section 16 has been updated. Section 14
has been updated. Date. Edition.
Updated MSDS
format.
This Material Safety Data Sheet has been prepared in accordance with
Canada's Workplace Hazardous Materials Information System (WHMIS)
and the OSHA Hazard Communication Standard (29 CFR 1910.1200),
the supplier notification requirements of SARA Title III, Section 313 and
other applicable right-to-know regulations.
Additional environmental information is contained on the Environmental
Data Sheet for this product, which can be obtained from your PPG
representative.
UC60400 000011 (00454918.001)(03/28/07)
060106, 000, 0811
*** END OF MSDS ***
__________________________________________________________________
Page 4 of 4
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