MATERIAL SAFETY DATA SHEET
COATINGS AND RESINS GROUP
PPG Industries, Inc.
SECTION 1 - CHEMICAL, PRODUCT, AND COMPANY INFORMATION
PRODUCT CODE/IDENTITY: DP40LF
PRODUCT TRADE NAME: EPOXY PRIMER GRAY GREEN
REVISION DATE: 08/29/02 (000) 0808
CUSTOMER PART #/NAME: Not applicable
CHEMICAL FAMILY: Epoxy
EMERGENCY MEDICAL/SPILL INFO: (304) 843-1300 (U.S.) 01-800-00-21-400 (MEXICO)
TECHNICAL INFORMATION: (440) 572-2800
PRODUCT SAFETY/MSDS INFORMATION: 4325 ROSANNA DRIVE, P.O. BOX 9
DATE OF MSDS PREPARATION: 01/11/03
PRIMARY HAZARD WARNING
Flammable. Keep away from heat, sparks, flames, and other sources of ignition.
Do not smoke. Extinguish all flames and pilot lights. Turn off stoves, heaters,
electrical motors, and other sources of ignition during use and until all
vapors/odors are gone. Harmful or fatal if swallowed. May cause moderate skin
irritation. Causes severe eye irritation. May be harmful if absorbed through the
skin. Prolonged or repeated contact may cause an allergic skin reaction. Vapor
and/or spray mist harmful if inhaled. Vapor irritates eyes, nose, and throat.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200), THE SUPPLIER NOTIFICATION
REQUIREMENTS OF SARA TITLE III, SECTION 313, AND OTHER APPLICABLE RIGHT-TO-KNOW
REGULATIONS.
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
REF HAZARDOUS INGREDIENTS PERCENT CAS NUMBER CARCINOGEN*
--- ---------------------------------------- ------- --------------- -----------
01 ETHYL BENZENE 0.1- <1 100-41-4 I
02 METHYL ISOBUTYL KETONE 5 - <10 108-10-1
03 TOLUENE 1 - <5 108-88-3
04 METHYL (N-AMYL) KETONE 10- <20 110-43-0
05 2-BUTOXY ETHANOL 1 - <5 111-76-2
06 AMORPHOUS SILICA 1 - <5 112926-00-8
07 CALCIUM CARBONATE 10- <20 1317-65-3
08 XYLENES 1 - <5 1330-20-7
09 CARBON BLACK 0.1- <1 1333-86-4 I
10 TITANIUM DIOXIDE 1 - <5 13463-67-7
11 TALC 1 - <5 14807-96-6
12 QUARTZ 0.1- <1 14808-60-7 INOA
13 EPOXY RESIN 10- <20 25068-38-6
14 VINYL RESIN 1 - <5 25086-48-0
15 AROMATIC NAPHTHA 1 - <5 64742-95-6
16 BARIUM SULFATE 10- <20 7727-43-7
17 1,2,4-TRIMETHYL BENZENE 1 - <5 95-63-6
* Carcinogens: O=OSHA; A=ACGIH; N=NTP; I=IARC
SARA TITLE III & CERCLA CLASSIFICATIONS
CERCLA HAZARDOUS SARA EXTREMELY HAZ SARA 311/312
REF SUBSTANCE RQ(LBS) SUBSTANCE TPQ(LBS) SARA 313 AC CH FL PR RE
---- ----------------- ------------------ -------- -- -- -- -- --
01 1000 lbs NOT ESTAB Y YY YNN
02 5000 lbs NOT ESTAB Y YN YNN
03 1000 lbs NOT ESTAB Y YN YNN
04 NOT ESTAB NOT ESTAB N YN YNN
05 NOT ESTAB NOT ESTAB N YY YNN
05 NOT ESTAB NOT ESTAB Y (GLYCOLETHR)
05 NOT ESTAB NOT ESTAB N (ONTARIO)
06 NOT ESTAB NOT ESTAB N N N NNN
07 NOT ESTAB NOT ESTAB N N N NNN
08 100 lbs NOT ESTAB Y Y N YNN
09 NOT ESTAB NOT ESTAB N N Y NNN
10 NOT ESTAB NOT ESTAB N N N NNN
10 NOT ESTAB NOT ESTAB N (TI COMPDS)
10 NOT ESTAB NOT ESTAB N (AS TI)
11 NOT ESTAB NOT ESTAB N N N NNN
12 NOT ESTAB NOT ESTAB N N Y NNN
12 NOT ESTAB NOT ESTAB N (AS QUARTZ)
13 NOT ESTAB NOT ESTAB N Y N NNN
14 NOT ESTAB NOT ESTAB N Y N NNN
15 NOT ESTAB NOT ESTAB N Y N YNN
15 NOT ESTAB NOT ESTAB N (ONTARIO)
16 NOT ESTAB NOT ESTAB N N N NNN
17 NOT ESTAB NOT ESTAB Y Y N YNN
SARA 311/312 CATEGORIES FOR THIS PRODUCT: ACUTE= Y, CHRONIC= Y, FLAMMABILITY= Y,
PRESSURE= N, REACTIVITY= N
OCCUPATIONAL EXPOSURE LIMITS HAVE BEEN ESTABLISHED FOR THE FOLLOWING MATERIALS:
ACGIH U.S. OSHA
REF TLV-TWA TLV-STEL PEL-TWA PEL-STEL
---- ---------------- ------------ ---------------- ------------
01 100 ppm 125 ppm 100 ppm 125 ppm
02 50 ppm 75 ppm 50 ppm 75 ppm
03 50 ppm NOT ESTAB 100 ppm 150 ppm
04 50 ppm NOT ESTAB 100 ppm NOT ESTAB
05 20 PPM NOT ESTAB S- 25 ppm NOT ESTAB
05 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (GLYCOLETHR)
05 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (ONTARIO)
06 10 mg/m3 NOT ESTAB 6 mg/m3 NOT ESTAB
07 10 mg/m3 NOT ESTAB R- 5 mg/m3 NOT ESTAB
08 100 ppm 150 ppm 100 ppm 150 ppm
09 3.5 mg/m3 NOT ESTAB 3.5 mg/m3 NOT ESTAB
10 10 mg/m3 NOT ESTAB 10 mg/m3 NOT ESTAB
10 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (TI COMPDS)
10 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (AS TI)
11 2 mg/m3 NOT ESTAB R- 2 mg/m3 NOT ESTAB
12 0.05 MG/M3 NOT ESTAB R- 0.1 mg/m3 NOT ESTAB
12 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (AS QUARTZ)
13 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
14 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
15 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
15 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB (ONTARIO)
16 10 mg/m3 NOT ESTAB R- 5 mg/m3 NOT ESTAB
17 NOT ESTAB NOT ESTAB NOT ESTAB NOT ESTAB
[C- Ceiling Limit; S- Potential Skin Absorption; R- Respirable Dust]
REF ACGIH TLV - BASIS - CRITICAL EFFECT(S)
---- ------------------------------------------------------------
01 irritation; CNS
02 irritation; narcosis; liver; kidney
03 CNS
04 irritation
05 irritation; CNS
05 (GLYCOLETHR)...NOT ESTAB.
05 (ONTARIO) ...NOT ESTAB.
06 irritation
07 irritation
08 irritation
09 lung
10 lung
10 (TI COMPDS) ...NOT ESTAB.
10 (AS TI) ...NOT ESTAB.
11 lung
12 pulmonary fibrosis; silicosis
12 (AS QUARTZ) ...silicosis; pulmonary function;
12 (AS QUARTZ) ...pulmonary fibrosis; cancer
13 NOT ESTAB.
14 NOT ESTAB.
15 NOT ESTAB.
15 (ONTARIO) ...NOT ESTAB.
16 pneumoconiosis(baritosis)
17 NOT ESTAB.
[ACGIH TLV BASIS - CRITICAL EFFECT(S): CNS-CENTRAL NERVOUS SYSTEM;
CVS-CARDIOVASCULAR SYSTEM; CWP-COAL WORKER'S PNEUMOCONIOSIS;
GI-GASTROINTESTINAL] [NOT ESTAB.= NOT ESTABLISHED = NOT APPLICABLE] [NOT ESTAB.
= NOT ESTABLISHED = NOT APPLICABLE]
PRODUCT STATUS RELATIVE TO THE U.S. EPA TOXIC SUBSTANCES CONTROL ACT
All chemical substances in this product are listed on the U.S. TSCA Inventory or
are otherwise exempt from TSCA Inventory reporting requirements.
SECTION 3 - HAZARDS IDENTIFICATION
EFFECTS OF OVEREXPOSURE FROM:
INGESTION: Harmful or fatal if swallowed.
EYE CONTACT: Causes severe eye irritation.
SKIN CONTACT: May cause moderate skin irritation. May be harmful if absorbed
through the skin. Prolonged or repeated contact may cause an allergic skin
reaction.
INHALATION: Vapor and/or spray mist harmful if inhaled. Vapor irritates eyes,
nose, and throat. Repeated exposure to high vapor concentrations may cause
irritation of the respiratory system and permanent brain and nervous system
damage.
CHRONIC OVEREXPOSURE: Avoid long-term and repeated contact. This product
contains crystalline silica which has been classified as a human carcinogen by
IARC. Long-term exposures may also lead to a disabling lung condition known as
silicosis. The risk depends on the duration and level of exposure to dust from
sanding surfaces or mist from spray applications. Use of appropriate personal
protective equipment and/or engineering controls should be employed whenever
these types of operations are being performed. This product contains an ethylene
series glycol ether and/or acetate which has been shown to cause adverse effects
on the kidneys, liver, blood and/or blood-forming tissue. This product contains
titanium dioxide. Animals inhaling massive quantities of titanium dioxide dust
in a long-term study developed lung tumors. Studies with humans involved in
manufacture of this pigment indicate no increased risk of cancer from exposure.
Potential for inhalation of titanium dioxide dusts from coatings is very
limited. Since overexposures are not expected, there is no significant hazard
for man. This product contains toluene. Toluene inhalation in animals (greater
than 1500 ppm) and intentional inhalation of toluene-containing products by
humans (e.g. glue) has caused adverse fetal development effects. This product
contains talc. In a lifetime inhalation study female rats exposed to an elevated
respirable concentration (9 times the Permissible Exposure Limit) of cosmetic
grade talc developed lung cancer. To date, no U.S. regulatory agency has
classified talc as a carcinogen based on this data. This product contains carbon
black which has been rated an IARC 2B carcinogen due to animal data.
Ethylbenzene has been reported by NTP to cause cancer in laboratory animals
following a chronic (2 year) inhalation exposure. Carcinogenicity was found in
the kidneys of rats and the lung and liver of mice at the 750 ppm dose level.
The No Observed Effect Level (NOEL) was 75 ppm. The International Agency for
Research on Cancer (IARC) has evaluated ethylbenzene and classified it as a
possible human carcinogen (Group 2B) based on sufficient evidence for
carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans. High exposures to xylenes in some animal studies have been
reported to cause health effects on the developing embryo and fetus. These
effects were often at levels toxic to the mother. The significance of these
findings to humans has not been determined. In a two-year NTP inhalation study,
there was no significant increase in the incidence of any type of tumor in rats
exposed to 2-butoxy ethanol at concentrations up to 125 ppm except a
questionable trend in the incidence of adrenal gland tumors in female rats. When
mice were exposed to concentrations of 62.5, 125, and 250 ppm, there was some
evidence of carcinogenicity found in the liver of male mice and the forestomach
of female mice at 250 ppm. The relevance of these findings to humans is unclear.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye watering, headaches, nausea, dizziness,
and loss of coordination are indications that solvent levels are too high.
Intentional misuse by deliberately concentrating and inhaling the contents can
be harmful or fatal. Redness, itching, burning sensation and visual disturbances
may indicate excessive eye contact. Dryness, itching, cracking, burning,
redness, and swelling are conditions associated with excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not applicable.
WARNING: This product contains a chemical(s) known to the State of California to
cause cancer and birth defects or other reproductive harm.
SECTION 4 - FIRST AID MEASURES
IMPORTANT FIRST AID INFORMATION: If ingestion, irritation, any type of
overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
immediately; have Material Safety Data Sheet information available.
INGESTION: Gently wipe or rinse the inside of the mouth with water. Sips of
water may be given. Never give anything by mouth to an unconscious person.
Contact a poison control center, emergency room or physician right away as
further treatment may be necessary.
EYE CONTACT: Remove contact lens and pour a gentle stream of warm water through
the affected eye for at least 15 minutes. If irritation persists, contact a
poison control center, emergency room, or physician as further treatment may be
necessary.
SKIN CONTACT: Run a gentle stream of water over the affected area for 15
minutes. A mild soap may be used if available. If any symptoms persist, contact
a poison control center, emergency room, or physician as further treatment may
be necessary.
INHALATION: Remove from area to fresh air. If symptomatic, contact a poison
control center, emergency room or physician for treatment information.
SECTION 5 - FIRE FIGHTING MEASURES
FLASHPOINT: 80 Degrees F ( 26 Degrees C) (PENSKY-MARTENS CLOSED CUP)
FLAMMABLE LIMITS: Lower explosion limit (LEL): 1.2
Upper explosion limit (UEL): Not available
EXTINGUISHING MEDIA: Use National Fire Protection Association (NFPA) Class B
extinguishers (carbon dioxide, dry chemical, or universal aqueous film forming
foam) designed to extinguish NFPA Class IC flammable liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep this product away from heat, sparks,
flame, and other sources of ignition (i.e., pilot lights, electric motors,
static electricity). Invisible vapors can travel to a source of ignition and
flash back. Do not smoke while using this product. Keep containers tightly
closed when not in use. Closed containers may explode when overheated. Do not
apply to hot surfaces. Toxic gases may form when this product comes in contact
with extreme heat.
SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray
may be used to cool closed containers to prevent pressure build-up and possible
autoignition or explosion when exposed to extreme heat. If water is used, fog
nozzles are preferable. Fire-fighters should wear self-contained breathing
apparatus and full protective clothing.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Provide maximum
ventilation. Only personnel equipped with proper respiratory, skin, and eye
protection should be permitted in the area. Remove all sources of ignition. Take
up spilled material with sand, vermiculite, or other noncombustible absorbent
material and place in clean, empty containers for disposal. Only the spilled
material and the absorbant should be placed in this container.
WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with
federal, state, provincial, and local environmental control regulations. Empty
containers should be recycled or disposed of through an approved waste
management facility.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: Do not store above 120 degrees F.(48 degrees
C.). Store large quantities in buildings designed and protected for storage of
NFPA Class IC flammable liquids.
OTHER PRECAUTIONS: Vapors may collect in low areas. If this material is part of
a multiple component system, read the Material Safety Data Sheet(s) for the
other component or components before blending as the resulting mixture may have
the hazards of all of its parts. Containers should be grounded when pouring.
Avoid free fall of liquids in excess of a few inches.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: Wear chemical-type splash goggles when possibility exists for
eye contact due to splashing or spraying liquid, airborne particles, or vapors.
SKIN PROTECTION: Wear protective clothing to prevent skin contact. Apron and
gloves should be constructed of: nitrile rubber. No specific
permeation/degradation testing have been done on protective clothing for this
product. Recommendations for skin protection are based on infrequent contact
with this product. For frequent contact or total immersion, contact a
manufacturer of protective clothing for appropriate chemical impervious
equipment.
RESPIRATORY PROTECTION: Overexposure to vapors may be prevented by ensuring
proper ventilation controls, vapor exhaust or fresh air entry. A NIOSH- approved
air purifying respirator with the appropriate chemical cartridges or a
positive-pressure, air-supplied respirator may also reduce exposure. Read the
respirator manufacturer's instructions and literature carefully to determine the
type of airborne contaminants against which the respirator is effective, its
limitations, and how it is to be properly fitted and used.
OTHER EQUIPMENT: Clean contaminated clothing and shoes.
VENTILATION REQUIREMENTS: Provide general dilution or local exhaust ventilation
in volume and pattern to keep the concentration of ingredients listed in Section
2 below the lowest suggested exposure limits, the LEL below the stated limit,
and to remove decomposition products during welding or flame cutting.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
[FORMULA VALUES, NOT SALES SPECIFICATIONS]
BOILING RANGE: 212- 381Degrees F
SOLUBILITY IN WATER: 5.0 %
VAPOR PRESSURE: 7.5 mmHg
WEIGHT/GALLON (LBS): 11.54 (U.S.)
VAPOR DENSITY: Heavier than air
pH: Not determined
% VOLATILE/VOLUME: 59.190
% SOLIDS BY WEIGHT: 63.82
SPECIFIC GRAVITY: 1.385
EVAPORATION RATE(BuOAc=100): 78
ODOR/APPEARANCE: Viscous liquid with an odor characteristic of the solvents
listed in Section 2.
SECTION 10 - STABILITY AND REACTIVITY
This product is normally stable and will not undergo hazardous reactions.
INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): Avoid contact with strong
alkalies, strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous
decomposition products when exposed to extreme heat: carbon monoxide ; carbon
dioxide ; silicon oxides ; lower molecular weight polymer fractions; oxides of
barium ; oxides of sulfur ; oxides of phosphorus ; Extreme heat includes, but is
not limited to, flame cutting, brazing, and welding.
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) Ratings:
HMIS Rating NFPA Rating
----------------------- -----------------------
HEALTH 2* HEALTH 2
FLAMMABILITY 3 FLAMMABILITY 3
REACTIVITY 0 INSTABILITY 0
Rating System:0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic
Effects.
Safe handling of this product requires that all of the information on the MSDS
be evaluated for specific work environments and conditions of use.
TRANSPORTATION OF DANGEROUS GOODS
PROPER SHIPPING NAME: Paint
NOS TECHNICAL NAME: None
HAZARD CLASS: 3
SUBSIDIARY CLASS: None
UN NUMBER: UN1263
PACKING GROUP: III
MARINE POLLUTANT: None
USA-RQ, HAZARDOUS SUBSTANCE: Xylenes, Toluene
USA-RQ, HAZARDOUS SUBSTANCE THRESHOLD SHIP WEIGHT: Xylenes>2638.26 Pounds,
Toluene>22371.59 Pounds
USA Shipments Only - RQ Threshold Ship Weight: This is the total weight of this
product that must be shipped to exceed the RQ quantity.
THIS IS THE END OF THE MSDS FOR: DP40LF (00246829.004DP40LF )
Manufactured and Supplied by:
REFINISH PRODUCTS
19699 PROGRESS DRIVE
STRONGSVILLE, OH 44149
陋\
|