Material Safety Data Sheet
Page 1 of 6 Issue date: July 2006
H-CEMENT
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: H-CEMENT
Manufacturer's Product Code: MGM063A
Use: Speciality cement for transducers.
DAVIDSON MEASUREMENT PTY LTD
1-3 Lakewood Blvd.
BRAESIDE 3195 VIC
Tel: 61 3 9580 4366
Fax: 61 3 9580 6499
2. HAZARDS IDENTIFICATION
HAZARDOUS ACCORDING TO ASCC/NOHSC/EU CRITERIA
Hazard Category: Toxic (T), Irritant (Xi)
Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOOD
RISK PHRASES
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R49 May cause cancer by inhalation.
SAFETY PHRASES
S22 Do not breathe dust.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information
Centre.
S38 In case of insufficient ventilation, wear suitable respiratory protection.
S61 Avoid release to the environment. Refer to special instructions/safety data sheet.
Road Transport
UN Number: 1760
Proper Shipping Name: CORROSIVE LIQUID, N.O.S.
Dangerous Goods Class: 8
Packing Group: II
Poison Schedule: S6 [Aust]
This material is a Scheduled S6 Poison and must be stored, handled and used according to the appropriate regulations.
Warning Statement:
The slurry will cause irritation to the eyes and skin. Prolonged skin contact may cause allergic skin reactions with some
susceptible individuals. Breathing the mist or dusts (of the dried) product may lead to cancer.
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME Proportion CAS Number
CRYSTALLINE SILICA - QUARTZ 10 to < 30 % 14808-60-7
PHOSPHORIC ACID 1 to < 10 % 7664-38-2
ALUMINIUM OXIDE 1 to < 10 % 1344-28-1
CHROMIUM (III) OXIDE 1 to < 5 % 1308-38-9
CHROMIC ACID SOLUTION 1 to < 5 % 1333-82-0
All other ingredients not hazardous according to ASCC/NOHSC/EU Criteria.
Material Safety Data Sheet
Page 2 of 6 Issue date: July 2006
H-CEMENT
4. FIRST AID MEASURES
Swallowed:
If swallowed, DO NOT induce vomiting. If victim is conscious, give 1 to 2 glasses of water to drink. Urgently transport
to hospital or doctor.
Eye:
If material is splashed into eyes, flush with plenty of water for at least 15 minutes, ensuring eye lids are held open.
Immediately transport to hospital or doctor.
Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with water and soap.
Immediately transport to hospital or doctor.
Inhaled:
Remove victim to fresh air.Administer oxygen if breathing is difficult. If condition respiratory problems continue,
transport to doctor or hospital immediately.
First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
Fire/Explosion Hazard
SUITABLE EXTINGUISHING MEDIA: Water fog, foam, dry chemical or carbon dioxide.
HAZARDS FROM COMBUSTION PRODUCTS: Thermal decomposition will generally release water vapour and
some phosphorus and chromium compounds.
PRECAUTIONS FOR FIRE FIGHTERS AND SPECIAL PROTECTIVE EQUIPMENT: Self-contained
breathing apparatus (SCBA) required for fire-fighting personnel.
HAZCHEM CODE: 2X [Aust]
FLAMMABILITY
This material is not a flammable or combustible liquid. The phosphoric acid component reacts violently with
magnesium, liberating hydrogen gas.
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
Corrosive Liquid. Avoid all incompatibles. Keep unnecessary people away; Isolate hazard area and deny entry.
Ventilate area. Wear suitable protective equipment as outlined under personal protection in this MSDS.
Methods and Materials for Containment and Clean Up Procedures:
Throw diatomaceous earth onto spill. DO NOT use sawdust. ALLOW TO ABSORB. Use non-sparking tools or
HEPA vacuum system to pick up. Place into labelled drum for later disposal. If risk of fire, blanket the spill with foam
or use water fog to disperse vapour clouds. Consult an expert regarding disposal of this product.
Emergency information(Transport):
Dangerous Goods - Initial Emergency Response Guide (IERG) (SAA/SNZ HB76:2004)
For TOXIC AND/OR CORROSIVE SUBSTANCES Non-Combustible Guide No: 37
Material Safety Data Sheet
Page 3 of 6 Issue date: July 2006
H-CEMENT
7. HANDLING AND STORAGE
Precautions for Safe Handling:
Provide adequate ventilation. Corrosive liquid. Avoid mixing with incompatibles. Do not get in eyes. Avoid direct or
prolonged contact with skin. DO NOT BREATH MIST OR DUST FROM DRIED PRODUCT.
Conditions for Safe Storage:
Keep containers tightly closed, when not using the product. Store in original packages as approved by manufacturer.
Store in an area that is dry and well-ventilation away from ignition sources. Store at ambient temperatures. Store away
from strong alkalis and oxidizing agents. For further information please refer to the Engineering Controls of this MSDS.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by
[ASCC/NOHSC] to the following components of the product:
CRYSTALLINE SILICA - QUARTZ
[ASCC/NOHSC]
[TWA] 0.2 mg/m3
PHOSPHORIC ACID
[ASCC/NOHSC]
[TWA] 1 mg/m3
[STEL] 3 mg/m3
References: H
ALUMINIUM OXIDE
[ASCC/NOHSC]
[TWA] 10 mg/m3
References: H
CHROMIUM (III) OXIDE
[ASCC/NOHSC]
[TWA] 0.5 mg/m3
CHROMIC ACID SOLUTION
[ASCC/NOHSC]
[TWA] 0.5 mg/m3
Engineering Controls
Corrosive liquid. Maintain adequate ventilation at all times. In most circumstances natural ventilation systems are
adequate.
Personal Protection Equipment
GLOVES: Neoprene or nitrile.
EYES: Chemical goggles or spectacles with side shields to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of mists. Select and use respirators in accordance with AS/NZS
1715/1716. The use of a half-face respirator fitted with an acid vapour cartridge is recommended. Filter capacity and
respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne concentration
of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air
supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
Material Safety Data Sheet
Page 4 of 6 Issue date: July 2006
H-CEMENT
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Green slurry with no odour.
Boiling Point: 104.4掳C
Vapour Pressure: 23.7 mmHg @ 20掳C
Specific Gravity: 1.6
Flash Point: Not applicable, water content interferes with flash point.
Flammability Limits: Not applicable.
Solubility in Water: Miscible.
Other Properties
Evaporation Rate (BuAc = 1): 1
Volatile Organic Compounds: 0%
Vapour Density (Air=1): <1
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable under normal conditions of use.
CONDITIONS TO AVOID:
Mixing with alkalis (caustics), oxidizing and reducing agents.
INCOMPATIBLE MATERIALS:
Alkalis (caustics), oxidizing and reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition will generally release water vapour and some phosphorus and chromium compounds.
HAZARDOUS REACTIONS:
Will not occur.
11. TOXICOLOGICAL INFORMATION
No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and
the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE HEALTH EFFECTS:
Swallowed:
May cause irritation to mouth, throat and stomach with effects including pains in the stomach, which may lead to
nausea, vomiting and diarrhoea.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision.
Skin:
Will cause irritation to the skin, with effects including; Redness, itchiness, and possible rashes.
Inhaled:
Mists or vapours may cause irritation to the nose, throat and respiratory system.
Chronic:
Prolonged or repeated skin contact may lead to dermatitis. Prolonged contact may cause severe eye irritation and some
form of permanent eye damage may occur. Prolonged or repeated inhalation exposure may lead to cancer. Prolonged or
repeated contact with this substance will cause sensitisation by skin contact.
Material Safety Data Sheet
Page 5 of 6 Issue date: July 2006
H-CEMENT
11. TOXICOLOGICAL INFORMATION (Continued)
Crystalline Silica:
Exposure to respirable crystalline silica may cause delayed (chronic) lung disease known as silicosis; Acute or rapidly
developing silicosis may occur in a period of time in heavy exposure in certain occupations such as sandblasting,
quarrying or mining. The onset may increase with heavy smoking or poor hygiene.
The International Agency for the Research of Cancer (IARC) enabled a Working Group who reported that there is
sufficient evidence for the classification of crystalline silica as a Confirmed Human Carcinogen (Group I) (IARC,
1997,V.68).
In line with the IARC decision, ASCC/NOHSC has classified ALL forms of crystalline silica as CONFIRMED
HUMAN CARCINOGEN (CATEGORY 1). Established human carcinogens are those substances known to be
carcinogenic to humans. There is sufficient evidence to establish a casual association between human exposure to these
substances and the development of cancer.
Phosphoric acid:
Oral LD50(rat): 1,530 mg/kg
Inhalation LC50(rat): > 850 mg/m_/1 Hr
Dermal LD50(rabbit): 2,740 mg/kg
CHROMIC ACID SOLUTION has been classified as a CATEGORY 1 CARCINOGEN (WORKSAFE).
Established human carcinogens are those substances known to be carcinogenic to humans. There is sufficient evidence
to establish a casual association between human exposure to these substances and the development of cancer.
12. ECOLOGICAL INFORMATION
No information is available for this product, it must be considered to be an environmental hazard, because of the heavy
metal content, and large quantities should not be discharged to waterways, sewers or drains.
13. DISPOSAL CONSIDERATIONS
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise corrosive
nature. If large amounts of the product enter waterways, sewers or streams, immediately contact the Environmental
Protection Agency or your Local Waste Management Authority.
14. TRANSPORT INFORMATION
Road Transport
UN Number: 1760
Proper Shipping Name: CORROSIVE LIQUID, N.O.S.
Dangerous Goods Class: 8
Packing Group: II
Label: Toxic (T), Irritant (Xi)
Air Transport
UN Number: 1760
Proper Shipping Name: CORROSIVE LIQUID, N.O.S.
Dangerous Goods Class: 8
Packing Group: II
Label: Toxic (T), Irritant (Xi)
Sea Transport
UN Number: 1760
Proper Shipping Name: CORROSIVE LIQUID, N.O.S.
Dangerous Goods Class: 8
Packing Group: II
Label: Toxic (T), Irritant (Xi)
Material Safety Data Sheet
Page 6 of 6 Issue date: July 2006
H-CEMENT
15. REGULATORY INFORMATION
Poison Schedule: S6 [Aust]
This material is a Scheduled S6 Poison and must be stored, handled and used according to the appropriate regulations.
Inventory Status:
Australia (AICS) Y
Europe (EINECS/ELINCS) Y
Y = all ingredients are on the inventory.
16. OTHER INFORMATION
Date of Preparation:
Issue date: July 12, 2006
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission {Formerly Worksafe}[Aust]
ASCC - Australian Safety and Compensation Council [Aust]
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997) [Aust]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
Hazchem Code - Fire fighters designation [Aust]
IATA - International Aviation Transport Authority [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the
classification and labelling of Chemicals. [Int]
EINECS - European Inventory of Existing Commercial Chemical Substances. [Int]
ELINCS - European List of Notified Chemical Substances. [Int]
EU - European Union [Int]
EU Directives: The classification criteria used, are adopted from the European Community's (EC) legislation for
classifying dangerous substances. The criteria are taken from:
EC Council Directive 67/548/EEC
EC Council Directive 1999/45/EC
[Aust/NZ] = Australian New Zealand
[Int] = International
[US] = United States of America
Principal References:
Information supplied by manufacturer.
Disclaimer
To the best of our knowledge, the information provided above meets the requirements of European Union directives for
hazardous substances which have been tested as a whole. The data provided on this Material Safety Data Sheet is from
manufacturers of the original components. All animal test data has been obtained from the public domain, NO
ANIMAL TESTS have been conducted by Davidson Pty Ltd. Davidson Pty Ltd specifically disclaims any and all form
of liability and/or responsibility for the application of this product.
END of MSDS
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