MATERIAL SAFETY DATA SHEET
Material/ Percent Hazardous
SECTION 1 - PRODUCT AND COMPANY INFORMATION
CAS Number
TOLUENE 15 - 40 X
108-88-3
PPG Industries, Inc.
ALUMINUM SILICATE 7 - 13 X
One PPG Place
1332-58-7
Pittsburgh, PA 15272
1-METHOXY-2-PROPYL 5 - 10 X
ACETATE
EMERGENCY PHONE NUMBERS (412) 434-4515 (U.S.) 108-65-6
(24 hours/day): TITANIUM DIOXIDE 5 - 10 X
13463-67-7
(514) 645-1320 (Canada)
METHYL ETHYL KETONE 3-7 X
01-800-00-21-400 (Mexico)
78-93-3
0532-83889090 (China) STRONTIUM CHROMATE 1-5 X
TECHNICAL (724) 274-7900 (SPRINGDALE, PA) 8:00 a.m. - 7789-06-2
INFORMATION: 5:00 p.m. EST BUTYL BENZYL PHTHALATE 1-5 X
85-68-7
PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m.
2-METHOXY-1-PROPYL 0.1-1.0 X
- 4:30 p.m. EST
ACETATE
Product ID: UC51760 (0811)
70657-70-4
PRODUCT NAME: DURACRYL PRIMER LACQUER (As Chromium (VI) Cmpnds) * X See Sections 8
SYNONYMS: None 7789-06-2 and 15 for
ISSUE DATE: 01/25/2007 information.
EDITION NO.: 3 (As Chromium Cmpnds) * X See Sections 8
7789-06-2 and 15 for
CHEMICAL Acrylic
information.
FAMILY:
(As Chromates) * X See Sections 8
EMERGENCY OVERVIEW: 7789-06-2 and 15 for
Flammable. Keep away from heat, sparks, flames, and other sources of information.
ignition. Do not smoke. Extinguish all flames and pilot lights. Turn off (As inorganic Chromium cmpnds) * X See Sections 8
stoves, heaters, electrical motors, and other sources of ignition during 7789-06-2 and 15 for
information.
use and until all vapors/odors are gone.CAUSES SEVERE EYE
IRRITATION. CAUSES PRIMARY SKIN IRRITATION. MAY BE
ABSORBED THROUGH THE SKIN. PROLONGED OR REPEATED SECTION 3 - HAZARDS IDENTIFICATION
CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.VAPOR ACUTE OVEREXPOSURE EFFECTS
AND/OR SPRAY MIST MAY BE HARMFUL IF INHALED. VAPOR
IRRITATES EYES, NOSE, AND THROAT. SANDING AND GRINDING EYE CONTACT:
DUSTS MAY BE HARMFUL IF INHALED. MAY CAUSE IRRITATION Causes severe eye irritation. Redness, itching, burning sensation and
AND/OR ALLERGIC RESPIRATORY REACTION IN LUNGS.HARMFUL visual disturbances may indicate excessive eye contact.
IF SWALLOWED. DRIED FILM OF THIS PRODUCT MAY BE HARMFUL SKIN CONTACT:
IF CHEWED OR SWALLOWED. Causes primary skin irritation. Dryness, itching, cracking, burning,
redness, and swelling are conditions associated with excessive skin
contact.
SKIN ABSORPTION:
SECTION 2 - COMPOSITION INFORMATION
May be absorbed through the skin. Prolonged or repeated contact may
The following ingredient(s) marked with an "x" are considered
cause an allergic skin reaction.
hazardous under applicable U.S. OSHA and/or Canadian WHMIS
INHALATION:
regulations. If no ingredients are listed, then there are no U.S. OSHA
Vapor and/or spray mist may be harmful if inhaled. Vapor irritates eyes,
and/or Canadian WHMIS hazardous ingredients in this product.
nose, and throat. Sanding and grinding dusts may be harmful if inhaled.
May cause irritation and/or allergic respiratory reaction in lungs.
INGESTION:
Harmful if swallowed. Dried film of this product may be harmful if chewed
or swallowed.
SIGNS & SYMPTOMS OF OVEREXPOSURE:
Repeated exposure to high vapor concentrations may cause irritation of
the respiratory system and permanent brain and nervous system
damage. Eye watering, headaches, nausea, dizziness and loss of
coordination are indications that solvent levels are too high. Intentional
misuse by deliberately concentrating and inhaling the contents can be
harmful or fatal. Dryness, itching, cracking, burning, redness, and
swelling are conditions associated with excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not
applicable.
CHRONIC OVEREXPOSURE EFFECTS
Avoid long-term and repeated contact.
__________________________________________________________________
Page 1 of 5
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC51760 (0811)
PRODUCT NAME: DURACRYL PRIMER LACQUER
Repeated exposure to vapors above recommended exposure limits (see UNUSUAL FIRE AND EXPLOSION HAZARDS:
Section 8) may cause irritation of the respiratory system and permanent Keep this product away from heat, sparks, flame, and other sources of
brain and nervous system damage. Intentional misuse by deliberately ignition (i.e., pilot lights, electric motors, static electricity). Invisible vapors
concentrating and inhaling the contents can be harmful or fatal. NTP, can travel to a source of ignition and flash back. Do not smoke while
IARC, and OSHA have classified chromium (+6) compounds as using this product. Keep containers tightly closed when not in use. Closed
carcinogenic. OSHA considers all Cr+6 compounds as potential containers may explode when overheated. Do not apply to hot surfaces.
occupational carcinogens capable of causing lung cancer above the Toxic gases may form when this product comes in contact with extreme
recommended exposure limits. This product contains toluene. Toluene heat. May produce hazardous decomposition products when exposed to
inhalation in animals (greater than 1500 ppm) and intentional inhalation of extreme heat. Extreme heat includes, but is not limited to, flame cutting,
toluene-containing products by humans (e.g. glue) has caused adverse brazing, and welding.
fetal development effects. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud SECTION 6 - ACCIDENTAL RELEASE MEASURE
noise can cause greater hearing loss than expected from exposure to STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
noise alone. Provide maximum ventilation. Only personnel equipped with proper
The effects of long-term, low level exposures to this product have not respiratory, skin, and eye protection should be permitted in the area.
been determined. Safe handling of this material on a long-term basis Remove all sources of ignition. Take up spilled material with sand,
should emphasize the prevention of all contact with this material to avoid vermiculite, or other noncombustible absorbent material and place in
any effects from repetitive acute exposures. See Section 11, of this clean, empty containers for disposal. Only the spilled material and the
MSDS for a detailed list of chronic health effects information available on absorbant should be placed in this container.
individual ingredients in this product.
SECTION 7 - HANDLING AND STORAGE
SECTION 4 - FIRST AID MEASURES PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:
If ingestion, irritation, any type of overexposure or symptoms of Vapors may collect in low areas. If this material is part of a multiple
overexposure occur during or persists after use of this product, contact a component system, read the Material Safety Data Sheet(s) for the other
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN component or components before blending as the resulting mixture may
immediately; have Material Safety Data Sheet information available. have the hazards of all of its parts. Containers should be grounded when
EYE CONTACT: pouring. Avoid free fall of liquids in excess of a few inches.
Remove contact lens and pour a gentle stream of warm water through the STORAGE:
affected eye for at least 15 minutes. If irritation persists, contact a poison Do not store above 120 degrees F.(48 degrees C.). Store large quantities
control center, emergency room, or physician as further treatment may be in buildings designed and protected for storage of NFPA Class IB
necessary. flammable liquids.
SKIN CONTACT:
Run a gentle stream of water over the affected area for 15 minutes. A
SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION
mild soap may be used if available. If any symptoms persist, contact a
ENGINEERING CONTROLS:
poison control center, emergency room, or physician as further treatment
Provide general dilution or local exhaust ventilation in volume and pattern
may be necessary.
to keep the concentration of ingredients listed in Section 8 below the
INHALATION:
lowest suggested exposure limits, the LEL below the stated limit, and to
Remove from area to fresh air. If symptomatic, contact a poison control
remove decomposition products during welding or flame cutting.
center, emergency room or physician for treatment information.
INGESTION:
Gently wipe or rinse the inside of the mouth with water. Sips of water PERSONAL PROTECTIVE EQUIPMENT
may be given if person is fully conscious. Never give anything by mouth EYES:
to an unconscious or convulsing person. Do Not induce vomiting. Wear chemical-type splash goggles when possibility exists for eye
Contact a poison control center, emergency room or physician right away contact due to splashing or spraying liquid, airborne particles, or vapors.
as further treatment will be necessary. SKIN/GLOVES:
Wear protective clothing to prevent skin contact. Apron and gloves
should be constructed of: neoprene rubber. No specific
SECTION 5 - FIRE FIGHTING MEASURES
permeation/degradation testing have been done on protective clothing for
FLAMMABLE PROPERTIES
this product. Recommendations for skin protection are based on
FLASHPOINT: 40 Degrees F ( 4 Degrees C)
infrequent contact with this product. For frequent contact or total
FLASHPOINT TEST METHOD:
immersion, contact a manufacturer of protective clothing for appropriate
Pensky-Martens Closed Cup
chemical impervious equipment. Clean contaminated clothing and shoes.
UEL: Not Available.
RESPIRATOR:
LEL: 1.4
Overexposure to vapors may be prevented by ensuring proper ventilation
AUTOIGNITION TEMPERATURE:
controls, vapor exhaust or fresh air entry. A NIOSH- approved air
Not Available.
purifying respirator with the appropriate chemical cartridges or a positive-
EXTINGUISHING MEDIA:
pressure, air-supplied respirator may also reduce exposure. Read the
Use National Fire Protection Association (NFPA) Class B extinguishers
respirator manufacturer's instructions and literature carefully to determine
(carbon dioxide, dry chemical, or universal aqueous film forming foam)
the type of airborne contaminants against which the respirator is effective,
designed to extinguish NFPA Class IB flammable liquid fires. Water spray
its limitations, and how it is to be properly fitted and used. Provide general
may be ineffective. Water spray may be used to cool closed containers
dilution or local exhaust ventilation in volume and pattern to keep the
to prevent pressure build-up and possible autoignition or explosion when
concentration of ingredients listed in Section 2 below the lowest
exposed to extreme heat.
suggested exposure limits, the LEL below the stated limit, and to remove
PROTECTION OF FIREFIGHTERS:
decomposition products during welding or flame cutting.
Fire-fighters should wear self-contained breathing apparatus and full
GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS
protective clothing.
If Threshold Limit Values (TLVs) have been established by ACGIH,
OSHA, Ontario or PPG, they will be listed below. These limits are
__________________________________________________________________
Page 2 of 5
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC51760 (0811)
PRODUCT NAME: DURACRYL PRIMER LACQUER
intended for use in the practice of industrial hygiene as guidelines or ODOR/APPEARANCE: Viscous liquid with an odor
recommendations in the control of potential workplace health hazards. characteristic of the solvents listed in
These limits are not a relative index of toxicity and should not be used by Section 2.
anyone without industrial hygiene training. VAPOR DENSITY: HEAVIER THAN AIR
Evaporation Rate: 265
BOILING POINT OR RANGE: 148 - 302Degrees F
Material/ Percent ACGIH TLV ACGIH OSHA PEL OSHA
Freezing Point or Range: Not Applicable.
CAS Number STEL STEL
Melting Point or Range(掳C): Not Applicable.
TOLUENE 15 - 40 S- 50 ppm Not 100 ppm 150 ppm
Partition coefficient (n- Not Applicable.
108-88-3 established
octanol/water):
R- 5 mg/m3
ALUMINUM 7 - 13 R- 2 Not Not
MG/m3 WEIGHT PER GALLON: 9.30 (U.S.) / 11.1 (IMPERIAL)
SILICATE established established
1332-58-7
10 mg/m3 10 mg/m3
TITANIUM DIOXIDE 5 - 10 Not Not
13463-67-7 established established
SECTION 10 - STABILITY AND REACTIVITY
METHYL ETHYL 3-7 200 ppm 300 ppm 200 ppm 300 ppm
STABILITY:
KETONE
This product is normally stable and will not undergo hazardous reactions.
78-93-3
STRONTIUM 1-5 0.0005 Not Not Not CONDITIONS TO AVOID:
MG/m3
CHROMATE established established established None Known.
7789-06-2 INCOMPATIBLE MATERIALS:
0.05 mg/m3 5[MU]G/m3
(As Chromium (VI) * Not Not
Avoid contact with strong alkalies, strong mineral acids, or strong
Cmpnds) established established
oxidizing agents.
7789-06-2
HAZARDOUS POLYMERIZATION:
(As Chromates) * Not Not C- 0.1 Not
None Known.
mg/m3
7789-06-2 established established established
HAZARDOUS DECOMPOSITION PRODUCTS:
- Oxides of chromium - Carbon monoxide - Carbon dioxide - Oxides of
Material/ Percent Ontario Ontario PPG IPEL PPG STEL aluminum - Lower molecular weight polymer fractions
CAS Number TWA STEL
TOLUENE 15 - 40 50 PPM Not Not Not
108-88-3 established established established
ALUMINUM 7 - 13 R- 2 Not Not Not
SECTION 11 - TOXICOLOGICAL INFORMATION
MG/m3
SILICATE established established established
ACUTE TOXICITY
1332-58-7
1-METHOXY-2- 5 - 10 50 PPM Not 50 PPM Not
PROPYL ACETATE established established Material/ Percent ORAL DERMAL INHALATION
108-65-6 CAS Number LD50 (g/kg) LD50 (g/kg) LC50 (mg/l)
10 MG/m3
TITANIUM DIOXIDE 5 - 10 Not Not Not TOLUENE 15 - 40 .64 g/kg 8.39 g/kg 12.50 g/L. 4 hr.
13463-67-7 established established established 108-88-3
METHYL ETHYL 3-7 200 ppm 300 ppm Not Not 1-METHOXY-2- 5 - 10 8.53 g/kg 5.00 g/kg Not Available
KETONE established established PROPYL ACETATE
78-93-3 108-65-6
STRONTIUM 1-5 0.0005 Not Not Not TITANIUM DIOXIDE 5 - 10 10.00 g/kg Not Available Not Available
MG/m3
CHROMATE established established established 13463-67-7
7789-06-2 METHYL ETHYL 3-7 2.74 g/kg 13.00 g/kg Not Available
0.05 mg/m3
(As Chromium (VI) * Not Not Not KETONE
Cmpnds) established established established 78-93-3
7789-06-2 STRONTIUM 1-5 3.12 g/kg Not Available Not Available
0.05 mg/m3
(As Chromates) * Not Not Not CHROMATE
7789-06-2 established established established 7789-06-2
BUTYL BENZYL 1-5 2.33 g/kg 10.00 g/kg 6.70 g/L. 4 hr.
PHTHALATE
Key: ACGIH=American Conference of Governmental Industrial 85-68-7
Hygienists; OSHA=Occupational Safety and Health Administration;
TLV=Threshold Limit Value; TWA=Time Weighted Average;
CHRONIC TOXICITY
PEL=Permissible Exposure Limit (1989 Vacated values); IPEL=Internal
Ingredient Target Organ/Chronic Effects:
Permissible Exposure Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV
- Respiratory sensitizer - Carcinogen - Testes - Reproductive - Ear -
or PEL Short-Term Exposure Limit; Skin= Skin Absorption Designation.
Embryotoxin - Teratogen - Brain - Central nervous system - Lung
[C- Ceiling Limit; S-Potential Skin Absorption; R-Respirable Dust]
Additional Information Not applicable.
Mutagenicity Toxicity:
This has not been tested for this product.
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
Reproductive Toxicity:
(FORMULA VALUES, NOT SALES SPECIFICATIONS)
This has not been tested for this product.
SPECIFIC GRAVITY: 1.116
PHYSICAL STATE: Liquid
Percent Solids: 44.42 SUPPLEMENTAL HEALTH INFORMATION:
Percent Volatile by Volume: 71.080
pH: Not available.
ODOR THRESHOLD: Not available.
Vapour Pressure: 27.2 mmHg
__________________________________________________________________
Page 3 of 5
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC51760 (0811)
PRODUCT NAME: DURACRYL PRIMER LACQUER
Marine Pollutant Name: None
Material/ Percent
CAS Ingredient Specific Animal Data: USA Shipments Only - RQ Threshold Ship Weight: This is the total
Number weight of this product that must be shipped to exceed the RQ quantity.
TITANIUM 5 - 10 This product contains titanium dioxide. Animals inhaling
DIOXIDE massive quantities of titanium dioxide dust in a long-term
13463-67-7 study developed lung tumors. Studies with humans
involved in manufacture of this pigment indicate no
increased risk of cancer from exposure. SECTION 15 - REGULATORY INFORMATION
METHYL 3-7 This product contains methyl ethyl ketone (MEK). MEK INVENTORY STATUS
ETHYL has been shown to cause minor embryotoxic/fetotoxic
U.S. TSCA: This product and/or all of its components are listed on the
KETONE effects in laboratory animals exposed for prolonged
U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory
78-93-3 periods at high concentrations via inhalation. The
reporting requirements.
potential for human exposure to high concentrations is
FEDERAL REGULATIONS
expected to be low due to the irritating effects of MEK at
US Regulations
low concentrations.
BUTYL 1-5 Due to limited evidence of carcinogenicity in experimental Material/ Percent
BENZYL animals, Butyl benzyl phthalate (BBP) has been classified CAS Number CERCLA HS - SARA EHS- SARA 313
PHTHALAT as an IARC Group 3 Carcinogen (not classifiable as to its RQ (LBS) TPQ (LBS)
E carcinogenicty to humans). BBP has shown weak TOLUENE 15 - 40 1000 lbs Not Listed Listed
85-68-7 estrogenic activity in several in-vitro assays. BBP has 108-88-3
caused adverse reproductive and development effects in ALUMINUM 7 - 13 Not Listed Not Listed Not Listed
laboratory animals, including negative effects on male SILICATE
reproductive organs; decreases in fertility and fetal 1332-58-7
toxicity. 1-METHOXY-2- 5 - 10 Not Listed Not Listed Not Listed
2- 0.1-1.0 Possible reproductive hazard. An ingredient(s) in this PROPYL ACETATE
METHOXY- product has adversely affected reproductive tissues and 108-65-6
1-PROPYL fetal development in test animals. TITANIUM DIOXIDE 5 - 10 Not Listed Not Listed Not Listed
ACETATE 13463-67-7
70657-70-4 METHYL ETHYL 3-7 5000 lbs Not Listed Not Listed
KETONE
78-93-3
SECTION 12 - ECOLOGICAL INFORMATION
STRONTIUM 1-5 10 lbs Not Listed Not Listed
POTENTIAL ENVIRONMENTAL EFFECTS
CHROMATE
Ecotoxicity: No Information Available. 7789-06-2
BUTYL BENZYL 1-5 100 lbs Not Listed Not Listed
PHTHALATE
ENVIRONMENTAL FATE
85-68-7
Mobility: No information available. 2-METHOXY-1- 0.1-1.0 Not Listed Not Listed Not Listed
Biodegradation: No information available. PROPYL ACETATE
Bioaccumulation: No Information Available. 70657-70-4
(As Chromium (VI) * Not Listed Not Listed Listed
Cmpnds)
PHYSICAL/CHEMICAL 7789-06-2
(As Chromium * 1 lb Not Listed Listed
Hydrolysis: No information available.
Cmpnds)
Photolysis: No information available. 7789-06-2
SECTION 13 - DISPOSAL CONSIDERATIONS
SARA 311/312
Provide maximum ventilation, only personnel equipped with proper
Health (acute): Yes
respiratory and skin and eye protection should be permitted in the area.
Health (chronic): Yes
Take up spilled material with sawdust, vermiculite, or other absorbent
Fire (flammable): Yes
material and place in containers for disposal.
Pressure: No
Waste material must be disposed of in accordance with federal, state,
Reactivity: No
provincial and local environmental control regulations. Empty containers
WHMIS HAZARD CLASS: - Class B, Division 2 - Class D, Division 2,
should be recycled by an appropriately licensed reconditioner/salvager or
Subdivision A - Class D, Division 2, Subdivision B
disposed of through a permitted waste management facility. Additional
disposal information is contained on the Environmental Data Sheet for
this product, which can be obtained from your PPG representative. STATE/PROVINCIAL REGULATIONS
CALIFORNIA PROP. 65: WARNING: This product contains a
chemical(s) known to the State of California to cause cancer and birth
SECTION 14 - TRANSPORTATION INFORMATION
defects or other reproductive harm.
Proper Shipping Name: Paint
Additional Information
NOS Technical Name: None
Hazard Class: 3
Subsidiary Class(es): None
UN Number: UN1263
Packing Group: II
USA - RQ Hazardous Substances: Strontium Chromate, Toluene, Butyl
Benzyl Phthalate
USA-RQ Hazardous Substance Strontium Chromate>258.66
Threshold Ship Weight: Pounds, Toluene>2579.34 Pounds,
Butyl Benzyl Phthalate
__________________________________________________________________
Page 4 of 5
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: UC51760 (0811)
PRODUCT NAME: DURACRYL PRIMER LACQUER
Percent
Material/
CAS Number IARC IARC IARC ACGIH NTP OSHA
Group Group 2B ( Carc. Known Carc.
1(Kno 2A Suspec Carc.
wn (Proba ted
Human ble Carc.)
Carc.) Carc.)
TITANIUM DIOXIDE 5 - 10 N N Y N N N
13463-67-7
1-5
STRONTIUM N N N Y *Y Y
CHROMATE
7789-06-2
Key: IARC- International Agency on the Research of Cancer; ACGIH-
American Conference of Governmental Industrial Hygienists; NTP-
National Toxicology Program *Denotes chemical as NTP Known
Carcinogen; + Denotes NTP Possible Carcinogen; OSHA-
Occupational Safety and Health Administration.
SECTION 16 - OTHER INFORMATION
Hazard Rating Systems
NFPA Rating: 3 30
HMIS Rating: 3*30
Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe,
*=Chronic Effects.
HMIS=Hazardous Materials Identification System; NFPA=National Fire
Protection Association;
Safe handling of this product requires that all of the information on the
MSDS be evaluated for specific work environments and conditions of use.
PREPARED BY: Product Safety Department
REASON FOR REVISION: Section 9 has been updated. Date. Edition.
Updated MSDS
format.
This Material Safety Data Sheet has been prepared in accordance with
Canada's Workplace Hazardous Materials Information System (WHMIS)
and the OSHA Hazard Communication Standard (29 CFR 1910.1200),
the supplier notification requirements of SARA Title III, Section 313 and
other applicable right-to-know regulations.
Additional environmental information is contained on the Environmental
Data Sheet for this product, which can be obtained from your PPG
representative.
UC51760 000012 (00358031.003)(01/24/07)
050412, 000, 0811
*** END OF MSDS ***
__________________________________________________________________
Page 5 of 5
|